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Agenda 10/13/2020 Item #16C 1 (ITB #20-7744 - Hulett Environmental Services, Inc.)10/13/2020 EXECUTIVE SUMMARY Recommendation to award Invitation to Bid (“ITB”) No. 20-7744, “Pest Control - County Facilities,” to Hulett Environmental Services, Inc., and authorize the Chairman to sign the attached agreement. OBJECTIVE: To retain a vendor to perform pest control services for County facilities. CONSIDERATIONS: Collier County Facilities Management is responsible for maintaining pest control services in approximately one hundred and forty-seven (147) designated locations for which service shall be provided monthly. To maintain the integrity and an insect/rodent-free environment at those buildings, the company that is awarded an agreement will perform monthly pest control services, control processes, and site-specific exterminations, as needed. On April 14, 2020, the Procurement Services Division released ITB No. 20-7744 to five thousand six hundred and sixty-two (5,662) vendors for the “Pest Control - County Facilities” project. Interested vendors viewed sixty-two (62) bid packages and staff received four (4) responsive and responsible bids by the May 15, 2020 deadline. Two additional firms, Tritech Pest Control, Inc. and W.W. Grainger, viewed the ITB but submitted a “No Bid” response. Staff contacted the responsive/responsible bidders to clarify some documents submitted with the bid and deemed the issue a minor irregularity. Respondents: Company Name City County State Bid Amount Responsive/ Responsible Hulett Environmental Services, Inc. West Palm Beach Palm Beach County FL $89,976.00 Yes/Yes Massey Services, Inc. Fort Myers Lee FL $138,960.00 Yes/Yes Truly Nolen of America, Inc. Fort Myers Lee FL $156,240.00 Yes/Yes Empire Pest Solutions Corp. Hialeah Miami-Dade FL $248,178.36 Yes/Yes Tritech Pest Control, Inc. Miami Miami-Dade FL N/A No Bid W.W. Grainger, Inc. Lake Forest Lake IL N/A No Bid Staff recommends this ITB be awarded to Hulett Environmental Services, Inc., the lowest overall responsive and responsible bidder for treating the County’s facilities. Compared to the expiring agreement #16-6698 the County should be saving approximately $55,000 a year for regular services and a 40% lower rate for the additional services. FISCAL IMPACT: The base annual amount of the contract is estimated to be $89,976.00 plus any additional and unanticipated services. Budget for this contract is provided in the General Fund Facilities Management Cost Center (001-122240). Compared to the expiring agreement #16-6698 the County should be saving approximately $55,000 a year for regular services and a 40% lower rate for the additional services. GROWTH MANAGEMENT IMPACT: There is no Growth Management impact associated with this Executive Summary. LEGAL CONSIDERATIONS: This item is approved as to form and legality and requires majority vote for Board approval. -SRT 16.C.1 Packet Pg. 1655 10/13/2020 RECOMMENDATION: To award Invitation to Bid #20-7744, “Pest Control - County Facilities” to Hulett Environmental Services, Inc., as recommended above, and authorize the Chairman to sign the attached agreement. Prepared by: Juan Delgado, Operations Analyst, Facilities Management Division ATTACHMENT(S) 1. 20-7744 Pest Control Solicitation (PDF) 2. 20-7744 Pest Control Bid Tabulation (PDF) 3. 20-7744 Notice of Recommended Award (PDF) 4. 20-7744 HulettEnvironmental_Insurance 9-1-20 (PDF) 5. 20-7744 HulettEnvironmental_VendorSigned (PDF) 6. [Linked] 20-7744 Hulett_Proposal (PDF) 16.C.1 Packet Pg. 1656 10/13/2020 COLLIER COUNTY Board of County Commissioners Item Number: 16.C.1 Doc ID: 12505 Item Summary: Recommendation to award Invitation to Bid (“ITB”) No. 20-7744, “Pest Control – County Facilities,” to Hulett Environmental Services, Inc., and authorize the Chairman to sign the attached agreement. Meeting Date: 10/13/2020 Prepared by: Title: – Facilities Management Name: Kathleen Sibert 09/01/2020 3:24 PM Submitted by: Title: Director - Facilities Management – Facilities Management Name: Damon Grant 09/01/2020 3:24 PM Approved By: Review: Facilities Management Damon Grant Director - Facilities Completed 09/01/2020 3:28 PM Procurement Services Opal Vann Level 1 Purchasing Gatekeeper Completed 09/01/2020 3:35 PM Procurement Services Barbara Lance Additional Reviewer Completed 09/01/2020 4:21 PM Procurement Services Evelyn Colon Additional Reviewer Completed 09/02/2020 9:16 AM Public Utilities Operations Support Joseph Bellone Additional Reviewer Completed 09/02/2020 10:31 AM Public Utilities Department Dan Rodriguez Additional Reviewer Completed 09/02/2020 4:15 PM Procurement Services Sandra Herrera Additional Reviewer Completed 09/10/2020 3:40 PM Procurement Services Drew Cody Additional Reviewer Skipped 09/11/2020 1:40 PM Public Utilities Department Drew Cody Level 1 Division Reviewer Completed 09/11/2020 3:45 PM Public Utilities Department George Yilmaz Level 2 Division Administrator Review Completed 09/15/2020 3:31 PM County Attorney's Office Scott Teach Level 2 Attorney Review Completed 09/16/2020 2:58 PM Office of Management and Budget Debra Windsor Level 3 OMB Gatekeeper Review Completed 09/16/2020 3:11 PM Budget and Management Office Ed Finn Additional Reviewer Completed 09/21/2020 1:45 PM County Attorney's Office Jeffrey A. Klatzkow Level 3 County Attorney's Office Review Completed 09/21/2020 4:16 PM County Manager's Office Nick Casalanguida Level 4 County Manager Review Completed 10/04/2020 12:26 PM Board of County Commissioners MaryJo Brock Meeting Pending 10/13/2020 9:00 AM 16.C.1 Packet Pg. 1657 COLLIER COUNTY BOARD OF COUNTY COMMISSIONERS INVITATION TO BID (ITB) FOR PEST CONTROL – COUNTY FACILITIES SOLICITATION NO.: 20-7744 BARBARA LANCE, PROCUREMENT STRATEGIST PROCUREMENT SERVICES DIVISION 3295 TAMIAMI TRAIL EAST, BLDG C-2 NAPLES, FLORIDA 34112 TELEPHONE: (239) 252-8998 Barbara.Lance@colliercountyfl.gov (Email) This solicitation document is prepared in a Microsoft Word format. Any alterations to this document made by the Consultant may be grounds for rejection of proposal, cancellation of any subsequent award, or any other legal remedies available to the Collier County Government. 16.C.1.a Packet Pg. 1658 Attachment: 20-7744 Pest Control Solicitation (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – County PAGE 1 SOLICITATION PUBLIC NOTICE INVITATION TO BID (ITB) NUMBER: 20-7744 PROJECT TITLE: PEST CONTROL – COUNTY FACILITIES DUE DATE: PLACE OF BID OPENING: PROCUREMENT SERVICES DIVISION 3295 TAMIAMI TRAIL EAST, BLDG C-2 NAPLES, FL 34112 All proposals shall be submitted online via the Collier County Procurement Services Division Online Bidding System: https://www.bidsync.com/bidsync-cas/ INTRODUCTION As requested by the Facilities Management Division (hereinafter, the “Division or Department”), the Collier County Board of C ounty Commissioners Procurement Services Division (hereinafter, “County”) has issued this Invitation to Bid (hereinafter, “ITB”) wi th the intent of obtaining bid submittals from interested and qualified vendors in accordance with the terms, conditions and specifi cations stated or attached. The vendor, at a minimum, must achieve the requirements of the Specifications or Scope of Work stated. The results of this solicitation may be used by other County departments once awarded according to the Board of County Commis sioners Procurement Ordinance. Historically, County departments have spent approximately $150,000; however, this may not be indicative of future buying patterns. BACKGROUND The County is responsible for maintaining Pest Control Services, in various owned and leased buildings throughout Collier Cou nty. In order to maintain the integrity and insect / rodent free environment of these facilities, the County intends to award a contract to perform: 1. Monthly pest control services and control processes; and 2. Site specific exterminations, as needed. TERM OF CONTRACT The contract term, if an award(s) is/are made is intended to be for three (3) years with two (2) one (1) year renewal options. Prices shall remain firm for the initial term of this contract. Surcharges will not be accepted in conjunction with this contract, and such charges should be incorporat ed into the pricing structure. The County Manager, or designee, may, at his discretion, extend the Agreement under all the terms and conditions contained in this Agreement for up to one hundred eighty (180) days. The County Manager, or designee, shall gi ve the Contractor written notice of the County's intention to extend the Agreement term not less than ten (10) days prior to the end of the Agreement term then in ef fect. All goods are FOB destination and must be suitably packed and prepared to secure the lowest transportation rates and to comply with all carrier regulations. Risk of loss of any goods sold hereunder shall transfer to the COUNTY at the time and place of delivery; if risk of loss prior to actual receipt of the goods by the COUNTY nonetheles s remain with VENDOR. AWARD CRITERIA ITB award criteria are as follows: ➢ The County’s Procurement Services Division reserves the right to clarify a vendor’s submittal prior to the award of the solicitation. ➢ It is the intent of Collier County to award to the lowest, responsive and responsible vendor(s) that represents the best value to the County. 16.C.1.a Packet Pg. 1659 Attachment: 20-7744 Pest Control Solicitation (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – County PAGE 2 ➢ For the purposes of determining the winning bidder, the County will select the vendor with the lowest price as outlined below : • Lowest Total Annual Price (in Category 1) ➢ Collier County reserves the right to select one, or more than one supplier, award on a line item basis, establish a pool for quoting, or other options that represents the best value to the County; however, it is the intent to: • Single Awardee ➢ The County reserves the right to issue a formal contract, standard County Purchase Order, or utilize the County Purchasing Card for the award of this solicitation. DETAILED SCOPE OF WORK It is the intent of the County that pest control services are completed monthly (interior and exterior) on County owned and l eased buildings to prevent infestations and address any insect or rodent issues; therefore, the bidder’s response time shall be a f actor in the award of the bid. While the County intends to use the Contractor award as a part of this solicitation, the County reserves the right at any time, to use the awarded Contractors for the services described, however, if pricing seems unreasonable or if services are unavailable, the County reserves the right to request additional quotes (per the Board’s Purchasing Ordinance). A qualified bidder will provide monthly services, call-backs, and specialized services, as needed, to keep all County facilities insect and rodent free, including but not limited to: bees, wasps, hornets, etc. by using an aggressive approach to the application and service, while maintaining and not impeding County business or the individuals who use the facilities. A qualified bidder will provide evidence of three (3) years of primary experience performing pest control services on similar sized projects/accounts in Florida. Locations: Collier County has approximately one hundred and forty-seven (147) designated locations for which service shall be provided monthly. Collier County advises the Contractor to visit each site prior to bidding. Bidder(s) may also be required to use the County’s Work Management procedures, such as utilizing work order form s or future online work order system, at no additional cost to the County or Contractor. The Contractor will be responsible for utilizing any sy stems used by the County for work orders under this Agreement. All bidders must provide requested certifications and licenses necessary to perform the services outlined in the bid specifications. The Contractor shall use qualified technicians to complete all work in accordance with the requirements specified in th is bid. Hourly time will be paid only for actual time at the worksite. Travel time will not be an allowable item. Technician credentials may be requested by the County. MONTHLY REQUIRED SERVICES The awarded Contractor will be responsible for providing the monthly pest control services and additional treatments (as requested with no additional charge), including but not limited to: • Control of common household pests, specifically ants, roaches, silverfish, firebrats, earwigs, millipedes, centipedes, cricke ts, scorpions, spiders, fleas, ticks, bees, wasps, hornets, etc. • Apply interior supplies / chemicals to buildings, including but not limited to: offices, storage rooms, mezzanines, attics, kitchens, basements, labs, kennels, locker rooms, bathrooms, etc. • Special attention shall be paid to problem areas such as kitchens and bathrooms o This requires monitoring and inquiry of building occupants o Additional treatments, as needed. • Apply perimeter supplies / chemicals to the outside of the buildings which shall include but not be limited to: porches, wind ows, window frames, eaves, patios, doorways, refuse areas, decks, under decks, and anywhere pests con gregate. • Control rats and/or mice, under and around the designated structures including the area extending to fifteen (15) feet. Traps must be checked daily until the condition is under control and less service is approved by the County Representative or designee. The County requests the following level of service: o Standard control for rats and/or mice is daily for 7 days from the reported incident then once per week for an additional thr ee weeks (total service four weeks). Daily site visits will be required initially for 7 days, but may be extended, at the discretion of the County Representative or designee. 16.C.1.a Packet Pg. 1660 Attachment: 20-7744 Pest Control Solicitation (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – County PAGE 3 o The Contractor will provide deodorants, when necessary, at no additional charge, and will be utilized to overcome possible odors caused by rats and/or mice. However, even with deodorants, every effort must be made to remove the source of the odor, when / where accessible. Additional Services: From time to time additional services are needed. These services will be provided on a lump sum, based upon quotes requested by the County Representative or designee. Additional services can be contracted by all Departments/Divisions as needed, for work not covered by general scope of services i.e. wildlife removal, spider fumigation or structures/poles specific to the facility. A scope of services will be provided and a Purchase Order (PO) will be given prior to services. These services are considered alternatives (the services are not a requirement of the contract, but may be incorporated if the selected Contractor can provide the services): • Rodent exclusion services • Cleanout of facilities due to Indoor Air Quality (IAQ) issues • Trapping services (above and beyond standard rodent removal) • Termite inspections and treatments, which shall be negotiated on an as needed basis o Any additional terms and conditions for termite services MUST be provided in conjunction with this solicitation o Entering, inspecting, and treating of specified structures must be performed to minimize interference with the daily routine of County employees and individuals using the facilities. The date and time of services must be mutually agreed upon by the County Representative and the awarded Contractor(s) • Spider and web fumigation, as needed • Any and all other extermination services needed Following the monthly pest control services and site inspections, a written report/check list will be provided detailing the results of the inspection, services completed, and making specific recommendations for future remedial actions, etc. Typically, pest control services will be completed during normal business hours; however, the County Representative or designee may request services during off-hours, as deemed necessary by the County Representative or designee. A surcharge calculated at time and a half (1-1/2 per hour) for off-hours, if necessary, and first approved in writing by the County Representative or designee. Request for Additional Service: • Repair Services Work (on-call, routine): The County Representative or designee will provide a scope of work to be performed to the Contractor and request that a “lump sum” quote be provided. The County expects that for on-call repair/removal/exclusion work, the Contractor provides a price quote within a reasonable time (one to two business days) from the point of initial contact, unless the requestor provides a longer deadline to receive the quote. Once a purchase order is issued, the County Representative or designee would expect that the on-call service for pest control related services commence within two (2) business days, unless otherwise directed by the County Representative or designee. If the Contractor does not fulfill these response requirements, the County Representative or designee reserves the right to contact other Contractor to perform the scope of work. • Urgent Services: The County Representative or designee will identify the needed services for the life, health, safety or equipment/facility urgency and request that work be completed as soon as reasonably practicable. The County Representative or designee may direct the Contractor to commence work through a verbal direction, and a purchase order will be issued to the Contractor as soon as possible. In each scope of work, the County Representative or designee reserves the right to specify: the period of completion; collection of deductions / fines or actual costs in the event of late completion and/or non-compliant performance and/or vendor caused damages; and “lump sum” pricing. • “Lump Sum” Quote is requested, the Contractor shall provide: ➢ The breakdown of the cost for supplies, parts, and equipment used for the scope of work; the Contractor must provide itemized documentation and receipts / invoices for any supply, part, or piece of equipment billed in their invoice. ➢ If applicable, a mark-up of subcontractor’s labor, supplies / materials and equipment may be included; the Contractor must provide itemized documentation (including the subcontractor’s invoice) o f any subcontractor’s labor, supplies / materials, and equipment. ➢ The County agrees to pay the Contractor for labor time spent by the Contractor's employees. Subcontractors will be paid by the Contractor according to their submitted invoice(s) then the Contractor will be allowed to charge a ten (10%) percent mark- up accordingly. 16.C.1.a Packet Pg. 1661 Attachment: 20-7744 Pest Control Solicitation (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – County PAGE 4 ➢ As a general business practice, the lump sum invoices would include back-up documentation for costs for supplies/materials, equipment rental, subcontractors, etc. Invoices would include number of hours worked and billing rate by position (and not company (or subcontractor) timekeeping or payroll records), material or equipment invoices, and other reimbursable documentation for the project. ➢ Taxes, related fees, and ancillary charges may be transferred to the County in the actual amount; however, mark -ups will not be allowed. Mark-ups will not be allowed on sales tax, consumer fees or taxes, use and other similar taxes, or fees associated with any work under this Agreement. ➢ Freight and shipping charges will be allowed if included in the quote and only allowed to the amount supported by backup documentation. No mark-up will be allowed for freight or shipping charges. ➢ If applicable, a fifteen (15%) percent mark-up of subcontractor’s labor, subcontractor’s supplies / materials, subcontractor’s equipment, rental equipment, contactor’s equipment, Contractor supplies / materials, etc. will be allowed . • When a “lump sum” quote is requested, the Contractor shall provide: ✓ A not-to-exceed total cost for the entire scope of work including a brief description of the work to be completed; ✓ Lump Sum (fixed price) is a firm fixed total price offering for a project; the risks are transferred from the County to the Contractor; and, as a business practice there are no hourly or material invoices presented, rather, the Contractor must perform to the satisfaction of the County’s project manager or designee before payment for the fixed price contract is authorized. ✓ Only a single lump sum quote is required, no itemized breakdown for the lump sum quote will be required for quoting or payment purposes. No time and material quotes will be accepted or required for quoting or payment. Actual invoices for materials, subcontractors, mark-ups, etc. will not be required for payment purposes, as the lump sum quote does not require a breakdown of the quote or supporting documentation. Timesheets and/or timecards will not be accepted or required for quoting or payment purposes to support l abor hours, as they are not required for a lump sum quote. • Termite Treatment Quote (includes any / all types of Termites): ➢ Terms and Conditions MUST be included with bid. A requested termite quote will be accepted as a lump sum. ➢ Callbacks: If callbacks are necessary, the awarded Contractor(s) shall perform all callbacks within twenty-four (24) hours after receipt of written notice of the problem. If a rodent situation is not under control after two (2) callbacks, another vendor may be substituted, and the performance measures / deductions shall apply. ➢ Additions and Deletions of Locations and Services: The County representative, or designee, shall attempt to provide advanced written notice to the Contractor of all additional and/or new locations. Pricing for additional locations shall be at the unit price specified in the square footage rates provided in the Contractor’s proposal. If removing a location from coverage, the County Representative or designee shall provide written or electronic notice to the Contractor. The removed location shall not be billed for the month of removal. Any prepaid coverage fees will be refunded at a pro-rata amount to the County in the form of a credit on the subsequent billing. All Contractor(s) personnel will have on their shirts the Contractor's business name and Collier County Government issued badge/card available always. Site access will be limited to required company vehicles and delivery vehicles only. Any parking at any of the County buildings or facilities is to be coordinated, in advance of starting a purchase order, with the County designee. Contractor(s) parking shall not interfere with County personnel or general public parking or pedestrian traffic. Violator's will be towed at owner's expense. Proper behavior and language by all Contractor(s) employees will always be enforced while working on County property. Contractor(s) employees shall be prohibited from disturbing items in County offices, and from smoking in any County facility. Records and Documentation: The Contractor(s) is responsible to maintain and update records for each serviced location. The documentation will include, and not be limited to, records of all service calls, services performed, site recommendations , and any additional services, if applicable. The Contractor(s) will maintain a service log for each site. The Contractor(s) will not charge for any call back work. All reports shall be sent to the County Representative, or their designee, noting date, ty pe, 16.C.1.a Packet Pg. 1662 Attachment: 20-7744 Pest Control Solicitation (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – County PAGE 5 service, location, etc. A current material, supplies, and equipment list shall be provided and shall be updated on a quarterly basis with the updated list provided. A Material Safety Data (MSDS), in compliance with the standards set forth in Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (H.C.S.), 29 CFR 1910.1200, shall be provided. This includes but is not limited to: • The chemical name and the common name for the toxic substance; • The hazards or other risks in the use of the toxic substance, inc luding but not limited to: the potential for fire, explosion, corrosively, and reactivity; known acute and chronic health effects of the risks from exposure, including the medical conditions which are generally recognized as being aggravated by exposure to the toxic substance; and the primary routes of entry and symptoms of over-exposure. • The proper precautions, handling practices, necessary personal protective equipment, and other safety precautions in the use or exposure to the toxic substances, including appropriate emergency treatment in the case of over exposure. • The emergency protocol for spills, fire, disposal, blood -borne pathogens, and first aid. • A description in lay terms of the known specific potential health risks posed by the toxic substance int ended to alert any person reading the information. • The year and month, if available, that the information was compiled and the name, address, and emergency telephone number of the manufacturer responsible for preparing the information. • Note: All changes / updates shall be immediately reported to the County Representative or designee VENDOR CHECKLIST ***Vendor should check off each of the following items as the necessary action is completed (please see, Form 2: Vendor Check List)**** 16.C.1.a Packet Pg. 1663 Attachment: 20-7744 Pest Control Solicitation (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – County Procurement Strategist: Barbara Lance 20-7744 Pest Control - County Facilities Notices Sent: 5,662 Project Mgr: Juan Delgado Bid Pkg View: 62 Submittal: 4 No Bids: 2 Rate Category Size of Location (Sq. Ft.)Approximate Number of Sites Monthly Rate Subtotal Monthly Rate Subtotal Monthly Rate Subtotal Monthly Rate Subtotal Monthly Rate Subtotal Monthly Rate Subtotal 1 0 – 1,000 18.0 $ 25.00 $450.00 $ 10.00 $180.00 $ 15.00 $270.00 $ 47.99 $863.82 $ - $0.00 $ - $0.00 2 1,001 – 5,000 46.0 $ 30.00 $1380.00 $ 20.00 $920.00 $ 30.00 $1380.00 $ 68.99 $3173.54 $ - $0.00 $ - $0.00 3 5,001 – 10,000 30.0 $ 36.00 $1080.00 $ 40.00 $1200.00 $ 45.00 $1350.00 $ 79.99 $2399.70 $ - $0.00 $ - $0.00 4 10,001 – 20,000 26.0 $ 42.00 $1092.00 $ 80.00 $2080.00 $ 90.00 $2340.00 $ 99.99 $2599.74 $ - $0.00 $ - $0.00 5 20,001 – 30,000 8.0 $ 75.00 $600.00 $ 120.00 $960.00 $ 135.00 $1080.00 $ 319.99 $2559.92 $ - $0.00 $ - $0.00 6 30,001 – 50,000 11.0 $ 92.00 $1012.00 $ 200.00 $2200.00 $ 215.00 $2365.00 $ 324.99 $3574.89 $ - $0.00 $ - $0.00 7 50,000 – 70,000 2.0 $ 152.00 $304.00 $ 280.00 $560.00 $ 305.00 $610.00 $ 599.99 $1199.98 $ - $0.00 $ - $0.00 8 70,001 – 100,000 2.0 $ 180.00 $360.00 $ 410.00 $820.00 $ 400.00 $800.00 $ 709.99 $1419.98 $ - $0.00 $ - $0.00 9 100,001 – 150,000 3.0 $ 240.00 $720.00 $ 620.00 $1860.00 $ 625.00 $1875.00 $ 709.99 $2129.97 $ - $0.00 $ - $0.00 10 150,001 +1.0 $ 500.00 $500.00 $ 800.00 $800.00 $ 950.00 $950.00 $ 759.99 $759.99 $ - $0.00 $ - $0.00 Total Sites 147.0 MONTHLY BID TOTAL $7,498.00 MONTHLY BID TOTAL $11,580.00 MONTHLY BID TOTAL $13,020.00 MONTHLY BID TOTAL $20,681.53 MONTHLY BID TOTAL $0.00 MONTHLY BID TOTAL $0.00 Total Annual Price 89,976.00$ Total Annual Price 138,960.00$ Total Annual Price 156,240.00$ Total Annual Price 248,178.36$ Total Annual Price -$ Total Annual Price -$ $ 75.00 $ 100.00 $ 125.00 $ - $ - $ - 10%10%10% 15%15%10% Yes/No Yes/No Yes/No Yes/No Yes/No Yes/No Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes*Yes*Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes * Deemed Minor Irregularities Document(s) Received. W.W. Grainger, Inc.Hulett Environmental Services Massey Services Truly Nolen Empire Pest Solutions Corp.Tritech Pest Control * Mark up for any leased equipment, materials, equipment, etc. shall be no more than 10%. * Mark up for Subcontractors shall be no more than 15%. * Documenation of awardees' cost must be provided with actual invoice from the supplier. * Mark-ups will not be allowed for any portion of an actual invoice that is sales tax, fees, freight, etc. * Mark-ups are only allowed for the actual. * "After-hours" will be calculated at 1 and 1/2 time. "Normal Business" hours is defined as County business hours; Monday through Friday 7:00 am to 5:00 pm. "After-hours" rates apply to weekends, County holidays and Monday through Friday after 5:00 pm and before 7:00 am. If a requested service starts during Normal Business hours and extends into the "After-hours" period, the "After-hours" rate shall only be charged for time actually worked during the "After- hours" period. Category 2 - Additional Services Massey Services Pest Control License Termite Treatment Permit Please complete & include all applicable documents. Addenda Form 4: Vendor Submittal – Local Vendor Preference Affidavit Insurance and Bonding Requirements E-Verify Form 1: Vendor Declaration Statement Form 2: Conflict of Interest Certification Affidavit Form 3: Immigration Affidavit Certification NO BID NO BID Bid Tabulation Sunbiz Page Vendor W-9 Truly Nolen Empire Pest Solutions Corp.Tritech Pest Control W.W. Grainger, Inc.Category 1 Hulett Environmental Services Material Markup (Percentage no more than 10%) Subcontractor Mark-up (Percentage no more than 15%) Hourly Rate for any other service that could be performed 16.C.1.b Packet Pg. 1664 Attachment: 20-7744 Pest Control Bid Tabulation (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – County Notice of Recommended Award Solicitation: 20-7744 Title: Pest Control – County Facilities Due Date and Time: May 15, 2020 @ 3:00 pm Respondents: Company Name City County State Bid Amount Responsive/Responsible Hulett Environmental Services, Inc West Palm Beach Palm Beach County FL $89,976.00 Yes/Yes Massey Services, Inc Fort Myers Lee FL $138,960.00 Yes/Yes Truly Nolen of America, Inc Fort Myers Lee FL $156,240.00 Yes/Yes Empire Pest Solutions Corp Hialeah Miami-Dade FL $248,178.36 Yes/Yes Tritech Pest Control, Inc Miami Miami-Dade FL No Bid W.W. Grainger, Inc. Lake Forest Lake IL No Bid Utilized Local Vendor Preference: Yes No Recommended Vendor(s) For Award: On April 14, 2020, the Procurement Services Division released Invitation to Bid 20-7744 to five thousand six hundred and sixty-two (5,662) vendors for the “Pest Control – County Facilities” project. Sixty-two (62) bid packages were viewed, and four (4) Submittals were received by the May 15, 2020 deadline. Tritech Pest Control, Inc. and W.W. Grainger were a “No Bid”. Staff reviewed the bids received and found all four (4) submittals responsive/responsible. The responsive/ responsible bidders were contacted to clarify documents submitted and deemed a minor irregularity. Staff recommends this ITB be awarded to Hulett Environmental Services, the lowest responsive and responsible bidder. Required Signatures Project Manager: Juan Delgado Procurement Strategist: Barbara Lance Procurement Services Director: __________________________________ _________________ Sandra Herrera Date DocuSign Envelope ID: B834727B-4369-4FB2-911E-7F74A6F4F383 5/21/2020 5/21/2020 5/21/2020 16.C.1.c Packet Pg. 1665 Attachment: 20-7744 Notice of Recommended Award (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – CERTIFICATE OF LIABILITY INSURANCE DATE (MM/DD/YYYY) 8/28/2020 THIS CERTIFICATE IS ISSUED AS A MATTER OF INFORMATION ONLY AND CONFERS NO RIGHTS UPON THE CERTIFICATE HOLDER. THIS CERTIFICATE DOES NOT AFFIRMATIVELY OR NEGATIVELY AMEND, EXTEND OR ALTER THE COVERAGE AFFORDED BY THE POLICIES BELOW. THIS CERTIFICATE OF INSURANCE DOES NOT CONSTITUTE A CONTRACT BETWEEN THE ISSUING INSURER(S), AUTHORIZED REPRESENTATIVE OR PRODUCER, AND THE CERTIFICATE HOLDER. IMPORTANT: If the certificate holder is an ADDITIONAL INSURED, the policy(ies) must have ADDITIONAL INSURED provisions or be endorsed. If SUBROGATION IS WAIVED, subject to the terms and conditions of the policy, certain policies may require an endorsement. A statement on this certificate does not confer rights to the certificate holder in lieu of such endorsement(s). PRODUCER Alliant Insurance Services, Inc. 16000 N. Dallas Parkway, Suite 850 Dallas, TX 75248 CONTACT NAME: PESTSURE CERTIFICATES PHONE (A/C, No, Ext): FAX (A/C, No): E-MAIL ADDRESS: PESTSURECERTS@AJG.COM INSURER(S) AFFORDING COVERAGE NAIC # INSURER A: Old Republic Insurance Company 24147 INSURED HULETT ENVIORNMENTAL SERVICES, INC. 7670 OKEECHOBEE BLVD. WEST PALM BEACH, FL 33411-2100 INSURER B: INSURER C: INSURER D: INSURER E: INSURER F: COVERAGES CERTIFICATE NUMBER: REVISION NUMBER: THIS IS TO CERTIFY THAT THE POLICIES OF INSURANCE LISTED BELOW HAVE BEEN ISSUED TO THE INSURED NAMED ABOVE FOR THE POLICY PERIOD INDICATED. NOTWITHSTANDING ANY REQUIREMENT, TERM OR CONDITION OF ANY CONTRACT OR OTHER DOCUMENT WITH RESPECT TO WHICH THIS CERTIFICATE MAY BE ISSUED OR MAY PERTAIN, THE INSURANCE AFFORDED BY THE POLICIES DESCRIBED HEREIN IS SUBJECT TO ALL THE TERMS, EXCLUSIONS AND CONDITIONS OF SUCH POLICIES. LIMITS SHOWN MAY HAVE BEEN REDUCED BY PAID CLAIMS. INSR LTR TYPE OF INSURANCE ADDL INSR SUBR WVD POLICY NUMBER POLICY EFF (MM/DD/YYYY) POLICY EXP (MM/DD/YYYY) LIMITS A X COMMERCIAL GENERAL LIABILITY X MWZY313739-19 10/01/2019 10/01/2020 EACH OCCURRENCE $ 2,000,000 CLAIMS-MADE X OCCUR DAMAGE TO RENTED PREMISES (Ea occurrence) $ 100,000 MED EXP (Any one person) $ 5,000 PERSONAL & ADV INJURY $ 2,000,000 GEN'L AGGREGATE LIMIT APPLIES PER: GENERAL AGGREGATE $ 4,000,000 X POLICY PRO- JECT LOC PRODUCTS-COMP/OP AGG $ 4,000,000 OTHER: $ A AUTOMOBILE LIABILITY X MWTB313759-19 10/01/2019 10/01/2020 COMBINED SINGLE LIMIT (Ea accident) $ 2,000,000 X ANY AUTO BODILY INJURY (Per person) $ OWNED AUTOS ONLY SCHEDULED AUTOS BODILY INJURY (Per accident) $ HIRED AUTOS ONLY NON-OWNED AUTOS PROPERTY DAMAGE (Per accident) $ $ UMBRELLA LIAB OCCUR EACH OCCURRENCE $ EXCESS LIAB CLAIMS-MADE AGGREGATE $ DED RETENTION $ $ WORKERS COMPENSATION Y/N N/A PER STATUTE OTH- ER AND EMPLOYERS' LIABILITY ANY PROPRIETOR/PARTNER/EXECUTIVE OFFICER/MEMBER EXCLUDED? E.L. EACH ACCIDENT $ (Mandatory in NH) If yes, describe under DESCRIPTION OF OPERATIONS below E.L. DISEASE - EA EMPLOYEE $ E.L. DISEASE - POLICY LIMIT $ DESCRIPTION OF OPERATIONS / LOCATIONS / VEHICLES (ACORD 101, Additional Remarks Schedule, may be attached if more space is required) All locations and operations. Add’l Insured coverage is provided by form by CG 20 10 12 19, See Attached. Collier County Board of County Commissioners, OR, Board of County Commissioners in Collier County, OR, Collier County Government, OR, Collier County included as additional insured. Insurance is primary and non-contributory. Pollution Liability is included under the General Liability policy at full policy limits, as respects Pesticide and Herbicide endorsement. CERTIFICATE HOLDER CANCELLATION Collier County Board of County Commissioners 3295 Tamiami Trail E Naples, Fl 34112 SHOULD ANY OF THE ABOVE DESCRIBED POLICIES BE CANCELLED BEFORE THE EXPIRATION DATE THEREOF, NOTICE WILL BE DELIVERED IN ACCORDANCE WITH THE POLICY PROVISIONS. AUTHORIZED REPRESENTATIVE Kristina Phillips © 1988-2015 ACORD CORPORATION. All rights reserved. ACORD 25 (2016/03) The ACORD name and logo are registered marks of ACORD 16.C.1.d Packet Pg. 1666 Attachment: 20-7744 HulettEnvironmental_Insurance 9-1-20 (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control 16.C.1.dPacket Pg. 1667Attachment: 20-7744 HulettEnvironmental_Insurance 9-1-20 (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest 16.C.1.ePacket Pg. 1668Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1669Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1670Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1671Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1672Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1673Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1674Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1675Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1676Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1677Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1678Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1679Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1680Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.e Packet Pg. 1681 Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1682Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1683Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1684Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1685Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1686Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1687Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1688Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1689Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1690Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – 16.C.1.ePacket Pg. 1691Attachment: 20-7744 HulettEnvironmental_VendorSigned (12505 : Recommendation to award Invitation to Bid (“ITB”) #20-7744, “Pest Control – HULETT ENVIRONMENTAL SERVICES PEST CONTROL SERVICES 10550 Collier Blvd. Naples, FL 34117 239-302-4140 __________________________________________________ Prepared For: Collier County Solicitation #20-7744 - Pest Control - County Facilities Hulett Environmental Services May 14, 2020 1 Hello, Thank you for the opportunity to propose pest and rodent control services for the beautiful Collier County. Our goal is to alleviate and maintain pests throughout the various municipality buildings, resulting in the optimal experience for residents, visitors, and employees. Hulett Environmental Services is dedicated to achieve this goal, and is eager for the opportunity to service the respected Collier County. To help you see the value in the investment you will be making, we have provided an overview of our company history and the details of how we will service your property. Hulett Environmental Services has been providing pest and rodent control, lawn and ornamental spraying, termite and other wood destroying organism control, and structural fumigation services for South Florida since 1968, equipped with management and staff with decades of experience. Hulett not only specializes in servicing residences, but also specializes in the service of both small and large municipalities, and commercial accounts with service requirements very similar to those described by Collier County. These include but are not limited to Admirals Cove of Jupiter, Seminole Tribe of Florida, City of Cape Coral, and even several departments within Collier County, such as the school district. As a full service pest control company, Hulett’s reputation is unrivaled and our customer service is superior, which is how Hulett is able to compete with the larger, national or international companies, while still maintaining a family-owned and operated feel. Hulett Environmental Services has eight locations, all across South Florida. Collier County will be serviced by our fully licensed, qualified and established Naples location, which has recently moved into a new, state of the art facility maintaining all of the required materials and personnel to furnish and fulfill the requirements as described in the bid herein. Hulett Environmental Services also has a location in Bonita Springs which would be available as well, to offer additional support to the county. Hulett Environmental Services only uses the most advanced products, all registered and approved by the EPA, local and state governments. Each of our service personnel are trained to practice Integrated Pest Management by our nationally recognized Board Certified Entomologist through the Hulett Environmental Services May 14, 2020 2 Entomological Society of America, and a Masters Entomologist from the University of Florida. Our technicians are able to identify pests, indicators of pests, recognize conducive conditions or structural deficiencies, and communicate the recommendations to relieve pest pressures to the staff of Collier County. Our treatments will be least invasive and most efficient as possible by combining or suggesting multiple IPM approaches. These may include mechanical controls such as sealing cracks and crevices, using air curtains, etc., or cultural controls such as improving the cleaning and trash practices. We are confident that in using these IPM techniques we can achieve our goal to alleviate and maintain pests throughout the properties of Collier County. If at any time during your decision period you have any questions regarding this proposal, or any of our other services, please do not hesitate to contact us at 239-302- 4140, or by visiting our website at http://www.bugs.com/. Thank you for choosing Hulett Environmental Services, and we are excited for the opportunity to service and develop relations with the beautiful Collier County. Thank you! Ben Benjamin Gillenwaters Entomologist, B.C.E. M.S. in Entomology for University of Florida Email: bgillenwaters@bugs.com Procurement Strategist: Barbara Lance Proj Mgr: Juan Delgado Notices Sent: Bid Pkg Viewed: Submittals: Rate Category Size of Location (Sq. Ft.)Approximate Number of Sites Monthly Rate Subtotal 1 0 – 1,000 18.0 $ 25.00 $450.00 2 1,001 – 5,000 46.0 $ 30.00 $1380.00 3 5,001 – 10,000 30.0 $ 36.00 $1080.00 4 10,001 – 20,000 26.0 $ 42.00 $1092.00 5 20,001 – 30,000 8.0 $ 75.00 $600.00 6 30,001 – 50,000 11.0 $ 92.00 $1012.00 7 50,000 – 70,000 2.0 $ 152.00 $304.00 8 70,001 – 100,000 2.0 $ 180.00 $360.00 9 100,001 – 150,000 3.0 $ 240.00 $720.00 10 150,001 +1.0 $ 500.00 $500.00 Total Sites 147.0 MONTHLY BID TOTAL $7,498.00 Total Annual Price 89,976.00$ $ 75.00 10 15 Please complete & include all applicable documents.Yes/No Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes YesTermite Treatment Permit Material Markup (Percentage no more than 10%) Form 1: Vendor Declaration Statement Form 2: Conflict of Interest Certification Affidavit Form 3: Immigration Affidavit Certification Form 4: Vendor Submittal – Local Vendor Preference Affidavit Subcontractor Mark-up (Percentage no more than 15%) E-Verify Form 5: Reference Questionnaire Form 6: Grant Forms (if applicable) Pest Control License Insurance and Bonding Requirements Sunbiz Page Vendor W-9 Hourly Rate for any other service that could be performed 20-7744 Pest Control - County Facilities Bid Schedule Category 1 BID SCHEDULE * Mark up for any leased equipment, materials, equipment, etc. shall be no more than 10%. * Mark up for Subcontractors shall be no more than 15%. * Documenation of awardees' cost must be provided with actual invoice from the supplier. * Mark-ups will not be allowed for any portion of an actual invoice that is sales tax, fees, freight, etc. * Mark-ups are only allowed for the actual. * "After-hours" will be calculated at 1 and 1/2 time. "Normal Business" hours is defined as County business hours; Monday through Friday 7:00 am to 5:00 pm. "After-hours" rates apply to weekends, County holidays and Monday through Friday after 5:00 pm and before 7:00 am. If a requested service starts during Normal Business hours and extends into the "After-hours" period, the "After-hours" rate shall only be charged for time actually worked during the "After-hours" period. Category 2 - Additional Services City of Miami Beach, 1833 Bay Road, 2nd Floor, Miami Beach, Florida 33139, www.miamibeachfl.gov PROPERTY MANAGEMENT DEPARTMENT, Tel: 305-673-7631 September 27, 2018 Re: Recommendation Letter Hulett Environmental Services, Inc. To Whom It May Concern: I am very pleased to have the opportunity to provide this recommendation to Hulett Environmental Services, Inc. Hulett Environmental Services, Inc., was contracted by the City of Miami Beach in order to provide Integrated Pest Management Services which includes General Fumigation Services for Dry Wood Termites. Hulett Environmental Services has done an outstanding job for the City of Miami Beach. They respond to our needs in a timely and efficient manner. At times they have gone above and beyond in order to meet our needs. Their employees are very courteous and professional. I would not hesitate to recommend Hulett Environmental Services for your Integrated Pest Management needs. Should you require any additional information or clarification, please do not hesitate to contact our office. Respectfully, Martha L. Torres Procurement Coordinator PROPERTY MANAGEMENT DEPARTMENT 1833 Bay Road, 2nd Floor, Miami Beach, FL 33139 Tel: 305.673.7631 | Ext: 2999 | marthatorres@miamibeachfl.gov www.miamibeachfl.gov State of Florida Department of State I certify from the records of this office that HULETT ENVIRONMENTAL SERVICES,INC.is a corporation organized under the laws of the State of Florida,filed on April 11,1983. The document number of this corporation is G32453. I further certify that said corporation has paid all fees due this office through December 31,2019,that its most recent annual report/uniform business report was filed on January 28,2019,and that its status is active. I further certify that said corporation has not filed Articles of Dissolution. Given under my hand and the Great Seal of the State of Florida at Tallahassee,the Capital,this the Seventeenth day of December, 2019 Tracking Number:9271873198CU To authenticate this certificate,visit the following site,enter this number,and then follow the instructions displayed. https://services.sunbiz.org/Filings/CertificateOfStatus/CertificateAuthentication STATE OF FLORIDA Dcpartmcrt of 9gricutturc anD @ongumcr Serbiceg BUREAU OF LICENSING AI\'D ENFORCEMENT THE ID CARD HOLDER NAMED BELOW HAS REGISTERED UNDER THE PROVISIONS OF CHAPTER 482 FOR THE PERIOD EXPIRING: November 30, 2020 AT HLiLETT EI.IVIRONMENTAL SERVICES INC. NAPLES, FL 34117 Wood Destroying Organism InspectorZACHARY JEROME FAUX HULETT ETWIRONMENTAL SERVICES INC, 7670 OKEECHOBEE BLVD WEST PALM BEACH, FL 334I I n t cdlt -&1""1 NICOLE "NIKKI'' FRIED. COMMISSIONER Date October 23, 2019 File No. 18247E99 Expires November 30, 2020 STATE OF FLORIDA Depnrtment of 9gricultrire anD Gongumcr $crbiceg BUREAU OF LICENSING A.I{D ENFORCEMENT Date File No. Expires October 23,2019 JE244EE5 November30,2020 THE ID CARD HOLDER NAMED BELOW HAS REGISTERED UNDER THE PROVISIONS OF CHAPTER 482 FOR THE PERIOD EXPIRING: November 30, 2020 AT HULETT ENVIRONMENTAL SERVICES TNC. NAPLES, FL 34117 EDUARDO VEL^ZQWZ HULETT ENVIRONMENTAL SERVICES INC. 7670 OKEECHOBEE BLVD WEST PALM BEACH, FL 334I I n t Crrll 4'1*rl NICoLE'NrKKI" rXrso, cour,rrssroNrn Wood Destroying Organism Inspector STATE OF'FLORIDA Dcpartment of 9grfuutturc anb @ongumcr $erbiccg BUREAU OF LICENSINC AND ENFORCEMENT THE ID CARD HOLDER NAMED BELOW HAS REGISTERED UNDER THE PROVISIONS OF CHAPTER 482 FOR THE PERIOD EXPIRING: November 30,2020 AT HULETT ENVIRONMENTAL SERVICES INC. NAPLES. FL 34II'I RegularUNIHERMAN MARIN HULETT ENVIRONMENTAL SERVICES INC. 7670 OKEECHOBEE BLVD WEST PALM BEACH, FL 334I I n t url -6'1*1 NrcoLE "NrKKr rXten, cort,trurssroNrn Date October 23, 2019 File No. JE13l052 Expires November 30, 2020 STATE OF FLORIDA Department of 9gricutture anb Gongumer Scrbiccg BUREAU OF LICENSING AIYD ENFORCEMENT THE ID CARD HOLDERNAMED BELOW HAS REGISTERED L'NDER THE PROVISIONS OF CHAPTER 482 FOR THE PERIOD EXPIRING: November 30, 2020 AT HULETT ENVIRONMENTAL SERVICES INC. NAPLES, FL 34II'1 n t c,rLL *1;"1 NrcoLE "NlKKr. rxrao. corr,tturrssloNrn RegularDANIEL RODRIGUEZ HULETT ENVIRONMENTAL SERVICES INC. 7670 OKEECHOBEE BLVD WEST PALM BEACH, FL 334I I Date October 23,2019 File No. 1E,87447 Expires November 30, 2020 STATE OF FLORIDA Dcpartmcrt of ggricutture anU @ongumtr $crbiccg BUREAU OF LICENSING AI\D ENFORCEMENT Date File No. ExPires October 23,2019 JE124668 November30,2020 THE ID CARD HOLDERNAMED BELOW HAS REGISTERED UNDER iHe pnovtsloNs oF cHAPTER482 FoRTHE PERIoD EXPIRING: November 30,2020 AT HULETT ENVIRONMENTA.L SERVICES INC. NAPLES, FL 34117 Regular ABEL RODRIGUEZ HULETT ENVIRONMENTAL SERVICES INC. 7670 OKEECHOBEE BLVD WEST PALM BEACH, FL 334I I nturu- -6-1-1 NrcoLE "NIKKI' rfueo. couutsstoruen Department of 9griculture anU Gongumr Serbircg BUREAU OF LICENSING AND ENFORCEMENT THE ID CARD HOLDER NAMED BELOW HAS REGISTERED LINDER THE PROVISIONS OF CHAPTER4S2 FORTHE PERIOD EXPIRING:November30,2020 AT HULETT ENVIRONMENTAL SERVICES INC. NAPLES,FL 34II7 STATE OF FLORIDA n t o{1.L -k1""1 NrcoLE "NIKKr" rfu eo. cornrutsstoNER Wood Destroying Orgrnism InspectorJON VIRGTN HULETT ENVIRONMENTAL SERVICES INC. 7670 OKEECHOBEE BLVD WEST PALM BEACH, FL 334I I Date October 23, 2019 File No. JE240843 Expires November 30, 2020 Safety Data Sheet 3/18/2014 8/4/2015 Replaces: Date: ADVION ANT GEL 1. PRODUCT IDENTIFICATION A20377A Use:Insecticide Product identifier on label:ADVION ANT GEL Manufacturer:Syngenta Crop Protection, LLC Post Office Box 18300 Greensboro NC 27419 Manufacturer Phone:1-800-334-9481 Emergency Phone:1-800-888-8372 Product No.: Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name ConcentrationCommon Name CAS Number Other inert ingredients Other inert ingredients Trade Secret 99.95% methyl (4aS)-7-chloro-2,5-dihydro-2- [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]in deno[1,2-e][1,3,4]oxadiazine-4a(3H)- carboxylate Indoxacarb Technical 173584-44-6 0.05% 2. HAZARDS IDENTIFICATION Not Applicable Classifications: Signal Word (OSHA): Not ApplicableHazard Statements: Not Applicable NoneOther Hazard Statements: Precautionary Statements:Not Applicable Hazard Symbols: Page 1 of 7 Safety Data Sheet 3/18/2014 8/4/2015 Replaces: Date: ADVION ANT GEL 4. FIRST AID MEASURES Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment. If swallowed: First aid measures are not normally required. If you feel unwell or have concerns, contact Syngenta (800-888-8372), a poison control center or doctor for treatment advice. If in eyes: Rinse eyes with water. First aid measures are not normally required. If concerned, call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. If on skin or clothing: First aid measures are not normally required. Wash material from the skin. If concerned, call Syngenta (800-888-8372), a poison control center or doctor for treament advice. If inhaled: First aid measures are not normally required. If you feel unwell or have concerns, contact Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Ingestion: Eye Contact: Skin Contact: Inhalation: Indication of immediate medical attention and special treatment needed: Most important symptoms/effects: There is no specific antidote if this product is ingested. Treat symptomatically. Not Applicable 5. FIRE FIGHTING MEASURES Suitable (and unsuitable) extinguishing media: Specific Hazards: Special protective equipment and precautions for firefighters: Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect runoff. During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Methods and materials for containment and cleaning up: Follow exposure controls/personal protection outlined in Section 8. Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. HANDLING AND STORAGE Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Page 2 of 7 Safety Data Sheet 3/18/2014 8/4/2015 Replaces: Date: ADVION ANT GEL Not Applicable 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingestion: Eye Contact: Skin Contact: Inhalation: THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. Occupational Exposure Limits: Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures: Chemical Name OtherOSHA PEL ACGIH TLV Source Other inert ingredients Not Applicable Not Applicable Not Applicable Not Applicable Indoxacarb Technical Not Established Not Established 1 mg/m³ 8hr & 12hr TWA (respirable) Manufacturer Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Where eye contact is likely use dust-proof chemical goggles. Where contact is likely, wear chemical-resistant gloves (such as barrier laminate, butyl rubber, nitrile rubber, neoprene rubber, natural rubber, polyvinyl chloride [PVC] or Viton), coveralls, socks and chemical-resistant footwear. A respirator is not normally required when handling this substance. In case of emergency spills, use a NIOSH approved respirator with any N, R, P or HE filter. Very faint Off-white, opaque gel 9. PHYSICAL AND CHEMICAL PROPERTIES Vapor Pressure: pH:7.2 (1% solution in H2O) Odor: Appearance: Not Available Not Available Initial boiling point and boiling range: Melting point/freezing point: Odor Threshold:Not Available Not Available Flammability:Not Available Not AvailableFlash Point (Test Method): Flammable Limits (% in Air): Vapor Density: Relative Density:1.15 - 1.24 g/ml @ ca.185°F (85°C) Not Available Indoxacarb Technical Not Available Page 3 of 7 Safety Data Sheet 3/18/2014 8/4/2015 Replaces: Date: ADVION ANT GEL Solubility (ies): Not AvailableAutoignition Temperature: Not AvailableDecomposition Temperature: Not AvailableViscosity: Not AvailablePartition coefficient: n-octanol/water: Not AvailableOther: Indoxacarb Technical Not Available Incompatible materials: Possibility of hazardous reactions:Will not occur. Chemical stability:Stable under normal use and storage conditions. 10. STABILITY AND REACTIVITY Not AvailableHazardous Decomposition Products: Reactivity:Not reactive. Conditions to Avoid:Not Available None known. 11. TOXICOLOGICAL INFORMATION Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Ingestion: Dermal: Inhalation: Eye Contact: Skin Contact: Skin Sensitization: Oral (LD50 Female Rat) : Non-Irritating (Rabbit) Non-Irritating (Rabbit) Not a Sensitizer (Mouse) Dermal (LD50 Rat) : Inhalation (LC50 Rat) : > 5000 mg/kg body weight > 5000 mg/kg body weight > 5.5 mg/l 4 hrs (applies to technical dry material) Reproductive/Developmental Effects Likely routes of exposure: Health effects information Symptoms of exposure: Delayed, immediate and chronic effects of exposure: Indoxacarb Technical: Animal testing showed effects on reproduction at levels equal to or above those causing parental toxicity. Animal testing showed effects on embryo-fetal development at levels equal to or above those causing maternal toxicity. Dermal, Inhalation Not Applicable Not Applicable Page 4 of 7 Safety Data Sheet 3/18/2014 8/4/2015 Replaces: Date: ADVION ANT GEL Chronic/Subchronic Toxicity Studies Carcinogenicity Toxicity of Other Components Target Organs Other Toxicity Information None Active Ingredients Inert Ingredients Indoxacarb Technical: The following effects occurred at levels of exposure that significantly exceed those expected under labeled usage conditions. Inhalation; rat; Incoordination, mortality, red blood cell destruction causing abnormal decrease in number of red blood cells (anemia) Indoxacarb Technical: Animal testing did not show any carcinogenic effects. Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Did not cause genetic damage in animals. Not Applicable Other inert ingredients Indoxacarb Technical: Nervous system Other inert ingredients: Not Applicable Chemical Name NTP/IARC/OSHA Carcinogen Other inert ingredients No methyl (4aS)-7-chloro-2,5-dihydro-2- [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]inden o[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate No 12. ECOLOGICAL INFORMATION Environmental Fate Eco-Acute Toxicity Information given is based on data on the components and the ecotoxicology of similar products. Environmental Hazards: Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark. Indoxacarb Technical: Indoxacarb Technical: Fish (Rainbow Trout) 96-hour LC50 0.65 mg/l Bird (Bobwhite Quail) LD50 Oral 98 mg/kg Invertebrate (Water Flea) Daphnia Magna 48-hour EC50 0.60 mg/l 13. DISPOSAL CONSIDERATIONS Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations. Disposal: Page 5 of 7 Safety Data Sheet 3/18/2014 8/4/2015 Replaces: Date: ADVION ANT GEL Characteristic Waste:Not Applicable Listed Waste:Not Applicable 14. TRANSPORT INFORMATION DOT Classification Ground Transport - NAFTA Not regulated Comments Water Transport - International Not regulated Air Transport Not regulated 15. REGULATORY INFORMATION RCRA Hazardous Waste Classification (40 CFR 261): Not Applicable TSCA Status: Exempt from TSCA, subject to FIFRA EPCRA SARA Title III Classification: Section 311/312 Hazard Classes: Section 313 Toxic Chemicals: CERCLA/SARA 304 Reportable Quantity (RQ): Not Applicable Pesticide Registration: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: California Proposition 65: EPA Registration Number(s): 100-1498 None Acute Health Hazard Caution: Avoid contact with skin, eyes or clothing. Wash thoroughly with soap and water after handling. Not Applicable 16. OTHER INFORMATION Page 6 of 7 Safety Data Sheet 3/18/2014 8/4/2015 Replaces: Date: ADVION ANT GEL 1 00 1 1 NFPA Hazard Ratings 2/22/2013 3/18/20148/4/2015 Health: Flammability: Instability: Replaces: Original Issued Date: Revision Date: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. HMIS Hazard Ratings Health: Flammability: Reactivity: 0 Minimal 1 Slight 2 Moderate 3 Serious 4 Extreme ASyngenta Hazard Category: 2Section(s) Revised: * Chronic 1 For non-emergency questions about this product call: 1-800-334-9481 Page 7 of 7 Safety Data Sheet 4/13/2017 5/19/2017 Replaces: Date: ADVION® COCKROACH GEL BAIT 1. PRODUCT IDENTIFICATION A20379A Use:Insecticide Product identifier on label:ADVION® COCKROACH GEL BAIT Manufacturer:Syngenta Crop Protection, LLC Post Office Box 18300 Greensboro NC 27419 Manufacturer Phone:1-800-334-9481 Emergency Phone:1-800-888-8372 Product No.: 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name ConcentrationCommon Name CAS Number Other inert ingredients Other inert ingredients Trade Secret 99.4% 2. HAZARDS IDENTIFICATION Warning Classifications: Signal Word (OSHA): May cause an allergic skin reactionHazard Statements: Skin Sensitizer: Category 1B NoneOther Hazard Statements: Precautionary Statements:Avoid breathing mist, vapors, spray. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves, protective clothing, eye protection. If on skin: Wash with plenty of soap and water. See Section 4 First Aid Measures. If skin irritation or rash occurs: Get medical advice. Wash contaminated clothing before reuse. Dispose of contents and container in accordance with local regulations. Hazard Symbols: Page 1 of 7 Safety Data Sheet 4/13/2017 5/19/2017 Replaces: Date: ADVION® COCKROACH GEL BAIT Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. methyl (4aS)-7-chloro-2,5-dihydro-2- [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]in deno[1,2-e][1,3,4]oxadiazine-4a(3H)- carboxylate Indoxacarb Technical 173584-44-6 0.6% 4. FIRST AID MEASURES Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison control center or doctor, or going for treatment. If swallowed: First aid measures are not normally required. If you feel unwell or have concerns, contact Syngenta (800-888-8372), a poison control center or doctor for treatment advice. If in eyes: Rinse eyes with water. First aid measures are not normally required. If concerned, call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. If on skin or clothing: First aid measures are not normally required. Wash material from the skin. If concerned, call Syngenta (800-888-8372), a poison control center or doctor for treament advice. If inhaled: First aid measures are not normally required. If you feel unwell or have concerns, contact Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Ingestion: Eye Contact: Skin Contact: Inhalation: Indication of immediate medical attention and special treatment needed: Most important symptoms/effects: There is no specific antidote if this product is ingested. Treat symptomatically. Persons suffering a temporary allergic reaction may respond to treatment with antihistamines or steroid creams and/or systemic steroids. Allergic skin reaction 5. FIRE FIGHTING MEASURES Suitable (and unsuitable) extinguishing media: Specific Hazards: Special protective equipment and precautions for firefighters: Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect runoff. During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. Prevent use of contaminated buildings, area, and equipment until decontaminated. Water runoff can cause environmental damage. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Methods and materials for containment and cleaning up: Follow exposure controls/personal protection outlined in Section 8. Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. Page 2 of 7 Safety Data Sheet 4/13/2017 5/19/2017 Replaces: Date: ADVION® COCKROACH GEL BAIT commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. HANDLING AND STORAGE Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Not Applicable 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingestion: Eye Contact: Skin Contact: Inhalation: THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. Occupational Exposure Limits: Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures: Chemical Name OtherOSHA PEL ACGIH TLV Source Other inert ingredients Not Applicable Not Applicable Not Applicable Not Applicable Indoxacarb Technical Not Established Not Established 1 mg/m³ 8hr & 12hr TWA (respirable) Manufacturer Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Where eye contact is likely use dust-proof chemical goggles. Where contact is likely, wear chemical-resistant gloves (such as barrier laminate, butyl rubber, nitrile rubber, neoprene rubber, natural rubber, polyvinyl chloride [PVC] or Viton), coveralls, socks and chemical-resistant footwear. A respirator is not normally required when handling this substance. In case of emergency spills, use a NIOSH approved respirator with any N, R, P or HE filter. None Yellow gel 9. PHYSICAL AND CHEMICAL PROPERTIES Odor: Appearance: Odor Threshold:Not Available Page 3 of 7 Safety Data Sheet 4/13/2017 5/19/2017 Replaces: Date: ADVION® COCKROACH GEL BAIT Vapor Pressure: Solubility (ies): pH:6.08 Not Available Not Available Initial boiling point and boiling range: Melting point/freezing point: Not Available Flammability:Not Available Not Available Not Available Flash Point (Test Method): Flammable Limits (% in Air): Autoignition Temperature: Vapor Density: Relative Density: Not AvailableDecomposition Temperature: Not AvailableViscosity: Not AvailablePartition coefficient: n-octanol/water: Not AvailableOther: 1.0755 g/ml @ 68°F (20°C) Not Available Indoxacarb Technical Not Available Indoxacarb Technical Not Available Incompatible materials: Possibility of hazardous reactions:Will not occur. Chemical stability:Stable under normal use and storage conditions. 10. STABILITY AND REACTIVITY Not AvailableHazardous Decomposition Products: Reactivity:Not reactive. Conditions to Avoid:None known None known. 11. TOXICOLOGICAL INFORMATION Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Ingestion: Dermal: Inhalation: Eye Contact: Oral (LD50 Rat) : Non-Irritating (Rabbit) Dermal (LD50 Rat) : Inhalation (LC50 Female Rat) : > 5000 mg/kg body weight > 5000 mg/kg body weight > 5.5 mg/l air - 4 hours Likely routes of exposure: Health effects information Symptoms of exposure: Delayed, immediate and chronic effects of exposure: Dermal, Inhalation Rash, redness or itching Allergic skin reaction Page 4 of 7 Safety Data Sheet 4/13/2017 5/19/2017 Replaces: Date: ADVION® COCKROACH GEL BAIT Chronic/Subchronic Toxicity Studies Carcinogenicity Toxicity of Other Components Skin Contact: Skin Sensitization: Non-Irritating (Rabbit) A skin sensitizer (Guinea Pig) Target Organs Other Toxicity Information None Reproductive/Developmental Effects Active Ingredients Inert Ingredients Indoxacarb Technical: The following effects occurred at levels of exposure that significantly exceed those expected under labeled usage conditions. Inhalation; rat; Incoordination, mortality, red blood cell destruction causing abnormal decrease in number of red blood cells (anemia) Indoxacarb Technical: Animal testing did not show any carcinogenic effects. Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Did not cause genetic damage in animals. Not Applicable Other inert ingredients Indoxacarb Technical: Animal testing showed effects on reproduction at levels equal to or above those causing parental toxicity. Animal testing showed effects on embryo-fetal development at levels equal to or above those causing maternal toxicity. Indoxacarb Technical: Nervous system Other inert ingredients: Not Applicable Chemical Name NTP/IARC/OSHA Carcinogen Other inert ingredients No methyl (4aS)-7-chloro-2,5-dihydro-2- [[(methoxycarbonyl)[4- (trifluoromethoxy)phenyl]amino]carbonyl]inden o[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate No 12. ECOLOGICAL INFORMATION Environmental Fate Eco-Acute Toxicity Indoxacarb Technical: Fish (Rainbow Trout) 96-hour LC50 0.65 mg/l Bird (Bobwhite Quail) LD50 Oral 98 mg/kg Invertebrate (Water Flea) Daphnia Magna 48-hour EC50 0.60 mg/l Page 5 of 7 Safety Data Sheet 4/13/2017 5/19/2017 Replaces: Date: ADVION® COCKROACH GEL BAIT Environmental Fate Information given is based on data on the components and the ecotoxicology of similar products. Environmental Hazards: Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark. Indoxacarb Technical: 13. DISPOSAL CONSIDERATIONS Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations. Characteristic Waste:Not Applicable Listed Waste:Not Applicable Disposal: 14. TRANSPORT INFORMATION DOT Classification Ground Transport - NAFTA Not regulated Comments Water Transport - International Not regulated Air Transport Not regulated 15. REGULATORY INFORMATION RCRA Hazardous Waste Classification (40 CFR 261): Not Applicable TSCA Status: EPCRA SARA Title III Classification: Section 311/312 Hazard Classes: Section 313 Toxic Chemicals: CERCLA/SARA 304 Reportable Quantity (RQ): Not Applicable Pesticide Registration: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Registration Number(s): 100-1484 None Acute Health Hazard Caution: Harmful if swallowed. Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes, or clothing. Page 6 of 7 Safety Data Sheet 4/13/2017 5/19/2017 Replaces: Date: ADVION® COCKROACH GEL BAIT TSCA Status: Exempt from TSCA, subject to FIFRA 1 00 1 2 16. OTHER INFORMATION NFPA Hazard Ratings 2/25/2013 4/13/20175/19/2017 Health: Flammability: Instability: Replaces: Original Issued Date: Revision Date: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. HMIS Hazard Ratings Health: Flammability: Physical Hazard: 0 Minimal 1 Slight 2 Moderate 3 Serious 4 Extreme C,SSyngenta Hazard Category: 2,4,11,16Section(s) Revised: * Chronic 2 For non-emergency questions about this product call: 1-800-334-9481 Page 7 of 7 Safety Data Sheet Alpine WSG Revision date : 2019/04/30 Page: 1/10 Version: 8.0 (30579644/SDS_CPA_US/EN) 1. Identification Product identifier used on the label Alpine WSG Recommended use of the chemical and restriction on use Recommended use*: insecticide Recommended use*: insecticide * The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF SE 67056 Ludwigshafen GERMANY Contact address: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932 USA Telephone: +1 973 245-6000 Emergency telephone number CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP (4357) Other means of identification Substance number: 552911 EPA Registration number: 499-561 Synonyms: Dinotefuran 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Classification of the product Aquatic Acute 1 Hazardous to the aquatic environment - acute Aquatic Chronic 1 Hazardous to the aquatic environment - chronic Combustible Dust Combustible Dust (1) Combustible Dust Safety Data Sheet Alpine WSG Revision date : 2019/04/30 Page: 2/10 Version: 8.0 (30579644/SDS_CPA_US/EN) Label elements Hazard Statement: May form combustible dust concentration in air. 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Weight % Chemical name 165252-70-0 40.0 % Dinotefuran 4. First-Aid Measures Description of first aid measures General advice: Remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air. If on skin: Wash thoroughly with soap and water. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. If swallowed: Rinse mouth and then drink 200-300 ml of water. Most important symptoms and effects, both acute and delayed Symptoms: (Further) symptoms and / or effects are not known so far Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Symptomatic treatment (decontamination, vital functions). 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, dry powder, foam Unsuitable extinguishing media for safety reasons : carbon dioxide Special hazards arising from the substance or mixture Safety Data Sheet Alpine WSG Revision date : 2019/04/30 Page: 3/10 Version: 8.0 (30579644/SDS_CPA_US/EN) Hazards during fire-fighting: carbon monoxide, carbon dioxide, nitrogen oxides, acid halides The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing. Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust formation. Environmental precautions Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For small amounts: Contain with dust binding material and dispose of. For large amounts: Sweep/shovel up. Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Avoid raising dust. 7. Handling and Storage Precautions for safe handling RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard 40 CFR part 170. Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect contents from the effects of light. Protect against heat. Protect from air. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Avoid dust formation. Do not return residues to the storage containers. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to national electric code. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition. Avoid dust formation. Dust can form an explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy. Safety Data Sheet Alpine WSG Revision date : 2019/04/30 Page: 4/10 Version: 8.0 (30579644/SDS_CPA_US/EN) Conditions for safe storage, including any incompatibilities Segregate from foods and animal feeds. Further information on storage conditions: Keep only in the original container in a cool, dry, well- ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Protect from temperatures below: -20 °C Changes in the properties of the product may occur if substance/product is stored below indicated temperature for extended periods of time. Protect from temperatures above: 60 °C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time. 8. Exposure Controls/Personal Protection Users of a pesticidal product should refer to the product label for personal protective equipment requirements. No occupational exposure limits known. Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment. Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS: Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied -air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head pro tection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No Safety Data Sheet Alpine WSG Revision date : 2019/04/30 Page: 5/10 Version: 8.0 (30579644/SDS_CPA_US/EN) eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs. 9. Physical and Chemical Properties Form: free flowing fine granules Odour: odourless Odour threshold: not applicable, odour not perceivable Colour: white pH value: approx. 6 - 7 ( 1 %(m)) melting range: 78 - 109 °C 111 - 144 °C Boiling point: not determined Flash point: not applicable, the product is a solid Flammability: not flammable Lower explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Upper explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Vapour pressure: not applicable Density: approx. 0.5 g/cm3 ( 20 °C) The statements are based on the properties of the individual components. Bulk density: 4.2645 Lb/USg Vapour density: not applicable Self-ignition temperature: not self-igniting Thermal decomposition: carbon monoxide, carbon dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat. Viscosity, dynamic: not applicable, the product is a solid Solubility in water: dispersible Evaporation rate: not applicable 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Oxidizing properties: not fire-propagating Dust explosivity characteristics: Kst: 74 m.bar/s Safety Data Sheet Alpine WSG Revision date : 2019/04/30 Page: 6/10 Version: 8.0 (30579644/SDS_CPA_US/EN) Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions The product is chemically stable. Hazardous polymerization will not occur. No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme temperatures. Avoid prolonged exposure to extreme heat. Avoid contamination. Avoid electro-static discharge. Avoid prolonged storage. This product may form an explosive mixture if: 1. the dust is suspended in the atmosphere as a dust cloud AND 2. the concentration of the dust is above the lower explosion limit (LEL) AND 3. the limiting oxygen concentration (LOC) is exceeded. Incompatible materials strong oxidizing agents, strong acids, strong bases Hazardous decomposition products Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat. 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Relatively nontoxic after single ingestion. Relatively nontoxic after short-term inhalation. Relatively nontoxic after short-term skin contact. Oral Type of value: LD50 Species: rat (female) Value: > 5,000 mg/kg Inhalation Type of value: LC50 Species: rat (male/female) Value: > 5.09 mg/l Exposure time: 4 h No mortality was observed. Safety Data Sheet Alpine WSG Revision date : 2019/04/30 Page: 7/10 Version: 8.0 (30579644/SDS_CPA_US/EN) Dermal Type of value: LD50 Species: rat (male/female) Value: > 5,000 mg/kg Assessment other acute effects Assessment of STOT single: The available information is not sufficient for the evaluation of specific target organ toxicity. The product has not been tested. The statement has been derived from the properties of the individual components. Irritation / corrosion Assessment of irritating effects: May cause slight irritation to the skin. May cause moderate but temporary irritation to the eyes. Sensitization Assessment of sensitization: There is no evidence of a skin-sensitizing potential. Buehler test Species: guinea pig Result: Skin sensitizing effects were not observed in animal studies. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual com ponents. No substance-specific organtoxicity was observed after repeated administration to animals. Genetic toxicity Assessment of mutagenicity: The product has not been tested. The statement has been derived from the properties of the individual compone nts. Mutagenicity tests revealed no genotoxic potential. Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components . The results of animal studies gave no indication of a fertility impairing effect. Teratogenicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. Other Information Misuse can be harmful to health. Symptoms of Exposure (Further) symptoms and / or effects are not known so far Medical conditions aggravated by overexposure Safety Data Sheet Alpine WSG Revision date : 2019/04/30 Page: 8/10 Version: 8.0 (30579644/SDS_CPA_US/EN) Individuals with pre-existing diseases of the respiratory system, skin or eyes may have increased susceptibility to excessive exposures. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to fish. There is a high probability that the product is not acutely harmful to aquatic invertebrates. There is a high probability that the product is not acutely harmful to aquatic plants. Toxicity to fish Information on: Dinotefuran technical LC50 (96 h) > 100 mg/l, Oncorhynchus mykiss LC50 (96 h) > 100 mg/l, Cyprinus carpio ---------------------------------- Aquatic invertebrates Information on: Dinotefuran technical EC50 (48 h) > 1,000 mg/l, Daphnia magna EC50 (96 h) 0.79 mg/l, Mysidopsis bahia ---------------------------------- Aquatic plants Information on: Dinotefuran technical EC50 (72 h) 97.6 mg/l (biomass), Pseudokirchneriella subcapitata ---------------------------------- Mobility in soil Assessment transport between environmental compartments The product has not been tested. The statement has been derived from the properties of the individual components. Information on: Dinotefuran technical Following exposure to soil, the product trickles away and can - dependant on degradation - be transported to deeper soil areas with larger water loads. ---------------------------------- Additional information Other ecotoxicological advice: Do not discharge product into the environment without control. 13. Disposal considerations Waste disposal of substance: Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a violation of federal law. If pesticide wastes cannot be disposed of according to label instructions, Safety Data Sheet Alpine WSG Revision date : 2019/04/30 Page: 9/10 Version: 8.0 (30579644/SDS_CPA_US/EN) contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container disposal: Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing, puncturing or other means to prevent unauthori zed use of used containers. RCRA: The waste codes are manufacturer's recommendations based on the designated use of the product. Other use and special waste disposal treatment on customer's location may require different waste - code assigments. This product is not regulated by RCRA. 14. Transport Information Land transport USDOT Not classified as a dangerous good under transport regulations Sea transport IMDG Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains DINOTEFURAN) Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains DINOTEFURAN) Further information The following provisions may apply for product in packages containing a net quantity of 5 kg or less ADR, RID, ADN: Special Provision 375; IMDG: 2.10.2.7; IATA: A197; TDG: Special Provision 99(2); 49CFR: §171.4 (c) (2). 15. Regulatory Information Federal Regulations Registration status: Crop Protection TSCA, US released / exempt Safety Data Sheet Alpine WSG Revision date : 2019/04/30 Page: 10/10 Version: 8.0 (30579644/SDS_CPA_US/EN) Chemical TSCA, US blocked / not listed EPCRA 311/312 (Hazard categories): Refer to SDS section 2 for GHS hazard classes applicable for this product. NFPA Hazard codes: Health: 1 Fire: 1 Reactivity: 1 Special: Labeling requirements under FIFRA This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label. CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Causes eye irritation. Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling. 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2019/04/30 We support worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. END OF DATA SHEET stop the stink & break down the gunk with Bac-Azap ® When you’re called to a job with big odor issues, turn to Bac-Azap. Its one-two punch first encapsulates the odor molecules to eliminate the smell, then a powerful blend of seven microbes go to work to break down the organic matter itself. Grease, “gunk,” vomit, skunk, urine and feces are no match for Bac-Azap. Remember, always read, understand and comply with the label. Bac-Azap and Nisus Corporation are registered trademarks of Nisus Corporation. ©2017 Nisus Corporation #BZ-FLY-0117 DO YOU GET THE application: target pests: Pour into drains to break down build-up and keep them smelling fresh. Foam into and around dumpsters. Spray garbage cans, dead animal or other organically contaminated sites as well as into crawl spaces. 100 Nisus Drive • Rockford, TN 37853 800.264.0870 • www.nisuscorp.comcreating a world of sustainability.drain buildup Garbagecan scum BAC-AZAP ® ANIMAL odorS Eliminates Organic Odor, Organic Stains • Removes Grease Build-Up in Drains Odor Encapsulation Technology Biodegradable  Salmonella Free  Non-Caustic  Non-Pathogenic  Contains Active Live Bacteria FIRST AID IF SWALLOWED: Drink 2 glasses of water or milk and induce vomiting by touching back of throat with finger. Get immediate medical attention. IF IN EYES: Immediately remove contact lenses if present, then flush eyes with gently running water for at least 15 minutes. Get immediate medical attention if irritation persists. Contains Water (CAS # 7732-18-5), Ethoxylated Alcohol (CAS # 68015-67-8), Nonylphenoxypolyethoxyethanol (CAS # 68412-54-4), a blend of non-pathogenic and enzyme producing bacteria and a proprietary fragrance blend. Harmful if swallowed. Avoid eye contact and prolonged or repeated skin contact. Store in original, closed container away from oxidizers. V.O.C. CONTENT: 0.6% by weight PRODUCT INFORMATION: Bac-Azap is composed of multiple strains of specifically bred bacteria that directly attack odor causing organic matter, eliminating the source of odors. Bac-Azap actually captures and destroys the odors, instead of simply covering them up. Bac-Azap chemical formulation instantly binds odor-causing molecules. It is unsurpassed in controlling odors caused by urine, feces, vomit, grease, fats, proteins, decomposing plant and animal matter, garbage odors, pet odors and other organic matter. It is especially effective in eliminating skunk odors and removes grease build-up in drain lines. Bac-Azap can be used in inedible product processing areas, non-processing areas, and/or exterior areas of official establishments operating under the Federal meat, poultry, shell egg grading and egg products inspection programs. NOTE: Do not use on food contact or food preparation surfaces. DIRECTIONS FOR USE: Bac-Azap is furnished full strength and ready to use for the toughest applications. In cases where the product is applied periodically as part of an ongoing maintenance program, the product may be diluted with 1 or 2 parts water to maximize coverage. BATHROOMS & FLOOR DRAINS: After cleaning, spray walls and fixtures with a 1+1 or 2+1 dilution (water + Bac- Azap) to prevent lingering odors. Pour 3 to 4 ounces of undiluted Bac-Azap directly into floor drains and urinals at the end of the day and allow to work overnight. FOAMING: Bac-Azap may be applied as a foam using an applicator device designed to create foam solutions. Place undiluted Bac-Azap into the applicator; do not dilute. Bac- Azap is specially formulated to be used with ProFoam® Platinum foam concentrate and may be applied into drain lines, to organic debris under heavy kitchen equipment, into wall voids where organic materials such as dead rodents may cause odor concerns and onto sides of garbage cans and dumpsters. START-UP: Apply 4 to 6 ounces to each drain where grease and organic debris is present. Continue daily for 5 to 10 days. MAINTENANCE: Apply 4 to 6 ounces once or twice a week. DRAINS & FOOD PREPARATION AREAS: For best results, apply product at end of day for overnight action. If drains are not used regularly, pour 2 to 3 gallons of warm water into drain opening to moisten drain surfaces before treatment. Use as a wash on all floors where organic debris may build up. In sewage overflow or pipe breakage situations, soak affected areas after removal of contaminants. WALL VOIDS: Bac-Azap can be applied into wall voids or other inaccessible areas by spray injection or in conjunction with a foam applicator. CRAWL SPACES, BASEMENTS & ATTICS: Spray onto surfaces or dirt in crawl spaces that may produce or retain odors from mold, mildew, sewage, wildlife and pets. Apply at the rate of 1 quart per 100 square feet. Bac-Azap may also be fogged into confined areas, such as crawl spaces or attics using a fogging device. Dilute product 2+1 (water + Bac-Azap) and apply as a fog at a rate of 1 gallon per 1000 cubic feet of confined space. NOTE: Do not fog Bac-Azap into areas where people or pets are present. Wait until fog has dissipated before re- entry. WALLS, FLOORS & CARPETS: Begin by thoroughly cleaning areas with appropriate materials and methods. Spray Bac-Azap on all surfaces where odors might originate including wall surfaces, floors and carpets. Apply at the rate of 1 quart per 100 square feet of surface area (approximately 3 fluid ounces per square yard). NOTE: Although Bac-Azap is designed to be non-staining, always test surface for colorfastness in an inconspicuous area before treating entire surface. Bac-Azap may also be fogged into confined areas, such as crawl spaces or attics using a fogging device. Dilute product 2+1 (water + Bac-Azap) and apply as a fog at a rate of 1 gallon per 1000 cubic feet of confined space. NOTE: Do not fog Bac-Azap into areas where people or pets are present. Wait until fog has dissipated before re-entry. COMPOSTING: Mix 6 to 8 ounces Bac-Azap per gallon of water. Pour evenly over compost pile 2 times a week. One gallon can treat up to 50 cubic feet of compost. For best results, turn and mix compost pile while adding the Bac- Azap solution. To speed up the composting process, add 8 ounces Bac-Azap to 1 gallon of water-soluble fertilizer. Pour over compost pile as described above. REFUSE CONTAINERS, GARBAGE CANS & DUMP- STERS: Once unit is empty, rinse it with water and liberally spray surfaces with Bac-Azap. If unit cannot be rinsed with water each time it is emptied, attempt to rinse with water daily or on a regular basis to remove excess soils and debris. Apply Bac-Azap to the point of surface wetness as often as possible, to control odors and remove organic matter. WARRANTY DISCLAIMER Manufacturer warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes stated on the label when used in strict accordance with the directions, subject to the inherent risks set forth below. To the extent not prohibited by applicable law, EXCEPT AS EXPRESSLY STATED HEREIN, MANUFACTURER MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY AND EXPRESSLY DISCLAIMS ALL OTHER WARRANTIES, INCLUDING ANY WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. Inherent Risks of Use The directions for use of this product are believed to be adequate and must be carefully followed. It is impossible to eliminate all risks associated with use of this product. Lack of performance or other unintended consequences may result because of such factors as use of the product contrary to label instructions, abnormal conditions, the presence of other materials, climatic conditions or the manner of use/application, all of which are beyond the control of the Manufacturer. The buyer/user assumes all such risks. Limitation of Remedies The sole and exclusive remedy for losses or damages resulting from this product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer’s election, one of the following: 1. Refund of purchase price paid by buyer or user for product bought, or 2. Replacement of amount of product used. Manufacturer shall not be liable for losses or damages resulting from handling or use of this product unless Manufacturer is promptly notified of such loss or damage in writing; and IN NO CASE SHALL MANUFACTURER BE LIABLE FOR DIRECT, CONSEQUENTIAL OR INCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Limitation of Remedies cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner. It is not intended that this product be used to practice any applicable patent, whether mentioned or not, without procurement of a license, if necessary, from the owner, following investigation by the user. 100 Nisus Drive • Rockford, TN 37853 (800) 264-0870 • www.nisuscorp.com Bac-Azap and Nisus Corporation are registered trademarks of Nisus Corporation. ProFoam is a registered trademark of NPD, Ltd. and manufactured and distributed by Nisus Corporation. ©2016 Nisus Corporation #BZ-SL-0816a SAFETY DATA SHEET Health Emergencies: INFOTRAC® (800) 535-5053 1. PRODUCT AND COMPANY INFORMATION Product Identity: BAC-AZAP® Recommended use of the chemical and restrictions on use: Use as a deodorizer for most organic source odors. Manufacturer: Nisus Corporation 100 Nisus Drive Rockford, TN 37853 Telephone: Phone: (800) 264-0870 Fax: (865) 577-5825 Emergency Phone: 800-535-5053 (INFOTRAC) SDS Date of Preparation: 08/10/16 2. HAZARDS IDENTIFICATION This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of this product. This SDS should be retained and available for employees and other users of this product. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. Amount 1,2-Benzisothiazolin-3-one 2634-33-5 0.02-0.04% Water 7732-18-5 70-99% Other proprietary materials Various 1-29.5% The exact formulation is being withheld as a trade secret. 4. FIRST AID MEASURES Eye: Rinse thoroughly with plenty of water, also under eyelids. If symptoms persist, contact call a physician. Skin: Wash with soap and water. May cause an allergic skin reaction. In the case of skin irritation or allergic reactions, see a physician. Ingestion: Rinse mouth immediately and drink plenty of water. Inhalation: Move victim to fresh air. Most Important Symptoms: Itch and/or rashes and/or hives Indication of immediate medical attention/special treatment: Treat symptomatically 5. FIRE FIGHTING MEASURES Suitable (and Unsuitable) Extinguishing Media: Use media appropriate to area. Specific hazards arising from the chemical: May cause sensitization of skin. Special Protective Equipment and Precautions for Fire-Fighting Instructions: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures: Avoid contact with eyes or skin. Methods and Materials for Containment and Cleaning Up: Contain spill and pick up and transfer to labeled containers. Soak up with inert absorbent materials. 7. HANDLING AND STORAGE Precautions for Safe Handling: Avoid contact with the eyes and skin and clothing. Nonrefillable container. Do not reuse containers. Product residues in empty containers can be hazardous. Follow all SDS precautions when handling empty containers. Conditions for Safe Storage, Including Any Incompatibilities: Keep container closed. Strong acids and alkalis and strong oxidizing agents may react with product and inactivate bacterial cultures. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies. Others: None Engineering Controls: Showers, eyewash, ventilation. Respiratory Protection: No protective equipment needed under normal use. If irritation observed, ventilation may be required. Skin Protection: Wear protective gloves and protective clothing. Eye Protection: Wear safety goggles where splashing is possible. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Clear to tan liquid with pleasant scent Physical State: Liquid Odor Threshold: Not established Vapor Density: Not Determined Initial Boiling Point/Range: 212°F (100°C) Solubility In Water: Dispersible Vapor Pressure: Not determined Relative Density: Not determined Evaporation Rate: Not determined Melting/Freezing Point: Not determined pH: 6.5-8.8 Percent Volatile: >90% average as water and other volatiles Octanol/Water Coefficient: Not determined Solubility: Water Decomposition Temperature: Not determined Viscosity: Not determined Flammability (solid, gas): Not determined Flashpoint: Not determined Autoignition Temperature: None Flammable Limits: LEL: Not determined UEL: Not determined 10. STABILITY AND REACTIVITY Reactivity: Not normally reactive Chemical Stability: Stable under normal storage and handling conditions. Possibility of Hazardous Reactions: Material is not known to polymerize. Conditions to Avoid: Exposure to extreme temperatures. Incompatible Materials: Avoid strong oxidizing agents and strong alkali and acids which might deactive the bacterial cultures. Hazardous Decomposition Products: When heated to decomposition emits oxides of carbon. 11. TOXICOLOGICAL INFORMATION HEALTH HAZARDS: Ingestion: No specific information available. Inhalation: No specific information available. Eye: No specific information available. Skin: No specific information available. Chronic: None known. Sensitization: Itches, rashes, hives. Carcinogenicity: None of the components is listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA. Germ Cell Mutagenicity: Not expected to cause germ cell mutagenicity. Reproductive Toxicity: Not expected to cause reproductive toxicity. Numerical Measures of Toxicity: Not applicable for this product. 12. ECOLOGICAL INFORMATION This product is not expected to have any negative ecological effect. Ecotoxicity: No negative effect expected. Persistence and Degradability: No data available for mixture. Bioaccumulative Potential: No data available for mixture. Mobility in Soil: No data available for mixture. Other Adverse Effects: No data available for mixture. 13. DISPOSAL CONSIDERATION Dispose in accordance with local, state and federal environmental regulations. This material is not deemed hazardous under 40 CFR 261. 14. TRANSPORTATION INFORMATION DOT Hazardous Materials Description: Not Regulated (unless package contains a reportable quantity) Not regulated under TDG, MEX, ICAO, IATA, IMDG/IMO, RID, ADR, ADN. 15. REGULATORY INFORMATION FIFRA: This product is not regulated under FIFRA. CERCLA: This product is not regulated under CERCLA. Report all spills in accordance with regulations SARA Hazard Category (311/312): Acute Health SARA 313: This product contains a chemical subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372) EPA TSCA Inventory: All of the ingredients in this product are TSCA compliant. 16. OTHER INFORMATION HMIS Rating: Health = 1 Flammability = 0 Physical Hazard = 0 SDS Revision History: 05/01/15: New SDS 08/10/16: Revised-I WARRANTY DISCLAIMER The information, data and recommendations contained herein are believed to be accurate but may not be all inclusive and should only be used as a guide. The information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the product for his particular use and on condition that they assume the risk of the use thereof. With respect to this publication and the product related thereto, unless otherwise expressly provided by Manufacturer in writing, MANUFACTURER MAKES NO EXPRESS OR IMPLIED WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. Remedy/Liability Limits The exclusive remedy for losses or damages resulting from this publication or the related product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer’s sole election, one of the following: 1. Refund of purchase price paid by buyer or user for product bought, or 2. Replacement of amount of product used. Manufacturer shall not be liable for losses or damages resulting from use of this publication or handling or use of this product, IN NO CASE SHALL MANUFACTURER BE LIABLE FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Remedy/Liability Limits cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner. 100 Nisus Drive • Rockford, TN 37853 USA • (800) 264-0870 Bac-Azap and Nisus Corporation are registered trademarks of Nisus Corporation. ©2016 Nisus Corporation • #BZ-SDS-081016a 100 Nisus Drive • Rockford, TN 37853 USA 800-264-0870 Safety Data Sheet CimeXa™ Insecticide Dust Rockwell - RP0012 Page 1 of 9 ______________________________________________________________________________________________ 1. PRODUCT IDENTIFICATION 1.1. Product Identifiers Product name : CimeXa™ Insecticide Dust 1.2. Other Means of Identification Product synonyms : none 1.3. Recommended Uses/Restrictions to Use Uses : Amorphous silica gel dust for the control of various pest species per label Restrictions : See product label for details 1.4. Supplier Details Company : Rockwell Labs Ltd 1257 Bedford Avenue North Kansas City, MO 64116-4308 USA Telephone : 1 816-283-3167 1.5. Emergency Contact Outside normal business hours Emergency Phone # : 1 800-424-9300 (USA & Canada) 1 703-527-3887 (Outside USA & Canada) _______________________________________________________________________________________ 2. HAZARDS IDENTIFICATION 2.1. Classification of Substance or Mixture none 2.2. GHS label elements, including precautionary statements Pictogram(s) none Signal word none Hazard statement(s) none Precautionary statement(s) none 2.3. Other hazards which do not result in classification This product is very absorbent and may have a drying effect on skin and eyes. When exceeding the OEL (Occupational Exposure Limit) a mechanical overburdening of the respiratory system is possible. Safety Data Sheet CimeXa™ Insecticide Dust Rockwell - RP0012 Page 2 of 9 __________________________________________________________________________ 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Chemical Identity Contains (% w/w) CAS-No. Hazard Classification Silicon Dioxide (as amorphous silica) 89-95 7631-86-9 none 3.2. Mixtures Not applicable _______________________________________________________________________________________ 4. FIRST AID MEASURES 4.1. Description of first aid measures General advice Consult a physician or poison control center. Provide this safety data sheet to medical personnel. Move out of hazardous areas. If inhaled Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice. In case of skin contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. In case of eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. If swallowed Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed None known 4.3. Indication of any immediate medical attention and special treatment needed, if necessary None known _______________________________________________________________________________________ 5. FIRE FIGHTING MEASURES 5.1. Extinguishing media Suitable extinguishing media: use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2. Specific hazards arising from the chemical No data available 5.3. Special protective equipment and precautions for fire fighters Wear self contained breathing apparatus for firefighting if deemed necessary. Safety Data Sheet CimeXa™ Insecticide Dust Rockwell - RP0012 Page 3 of 9 Additional information: none. 5.4. Further information No data available _______________________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with spilled product and contaminated surfaces. Evacuate personnel to safe areas during emergencies. For safe handling instructions see section 7. For proper PPE see section 8. 6.2. Environmental precautions Prevent further leakage or spillage if safe to do so. 6.3. Methods and materials for containment and cleaning up Sweep up any spilled material and dispose of according to instructions in section 13. Vacuuming or wet sweeping may be used to avoid dust dispersal. Wash contaminated surfaces with soap and water. _______________________________________________________________________________________ 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Handle in accordance with good industrial hygiene practices. Wash hands thoroughly with soap and water after use and before eating, drinking, chewing gum, using tobacco or using the toilet. Remove contaminated clothing and wash before reuse. For additional precautions see section 2.2. 7.2. Conditions for safe storage, including any incompatibilities Store product tightly sealed in original container. Store in a dry location. Do not store where children or animals may gain access. _______________________________________________________________________________________ 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Components with workplace parameters Component CAS-No. Value Control parameters Basis Amorphous silica 7631-86-9 IDHL 3000 mg/m3 ----- TWA 80 mg/m3/% SiO2 OSHA PEL TWA 6 mg/m3 NIOSH REL TWA 10*, 5** mg/m3 ACGIH TLV *Total dust, ** Respirable fraction 8.2. Appropriate engineering controls Ensure relevant engineering controls are employed to prevent exceeding threshold values for the listed control parameters in section 8.1. 8.3. Individual protection measures, such as personal protective equipment (PPE) In normal use and handling conditions refer to the product label for required PPE. In all other cases the following recommendations would apply. Eye/face protection Safety Data Sheet CimeXa™ Insecticide Dust Rockwell - RP0012 Page 4 of 9 Safety glasses or other similar eye protection conforming to ANSI Z87.1 standards recommended when handling product. Skin protection Chemical resistant nitrile rubber or similarly compatible gloves recommended when handling product. Dispose of contaminated gloves after use in accordance with applicable local and state regulations. Wash exposed skin with soap and water immediately. Wash all contaminated clothing prior to reuse. Respiratory protection Not required under normal use conditions. When risk assessment shows need for air-purifying respirators use NIOSH approved respirators when handling material with the following airborne concentrations: Up to 30 mg/m3: (APF = 5) Any quarter-mask respirator. Up to 60 mg/m3: (APF = 10) Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100, P100. (APF = 10) Any supplied-air respirator Up to 150 mg/m3: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode (APF = 25) Any powered, air-purifying respirator with a high-efficiency particulate filter. Up to 300 mg/m3: (APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. (APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode (APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter (APF = 50) Any self-contained breathing apparatus with a full facepiece (APF = 50) Any supplied-air respirator with a full facepiece Up to 3000 mg/m3: (APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode Thermal hazards None known _______________________________________________________________________________________ 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance; White powder Odor; Odorless Odor threshold; No data available pH; 2.0 – 4.5 (20 °C) Melting point/freezing point; >1700 °C (>3092 °F) Safety Data Sheet CimeXa™ Insecticide Dust Rockwell - RP0012 Page 5 of 9 Initial boiling point and boiling range; >1700 °C (>3092 °F) Flash point; No data available Evaporation rate; No data available Flammability (solid, gas); Product is not flammable Upper/lower flammability or explosive limits; No data available Vapor pressure; No data available Vapor density; No data available Relative density; 0.24 g/ml Solubility; Insoluble Partition coefficient: n- octanol/water; No data available Auto-ignition temperature; No data available Decomposition temperature; No data available Viscosity; No data available 9.2. Additional Information No data available _______________________________________________________________________________________ 10. STABILITY AND REACTIVITY 10.1. Reactivity No dangerous reactions known. 10.2. Chemical stability Stable under recommended storage conditions. 10.3. Possibility of hazardous reactions No data available 10.4. Conditions to avoid No data available 10.5. Incompatible materials No data available 10.6. Hazardous decomposition products Other decomposition products – no data available In the event of a fire: see Section 5 _______________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Acute Toxicity LD50 Oral – Rat – > 5000 mg/kg Safety Data Sheet CimeXa™ Insecticide Dust Rockwell - RP0012 Page 6 of 9 LD50 Dermal – Rat – > 6000 mg/kg LD50 Inhalation – Rat – > 2000 mg/m3/4h Maximum attainable concentration, mortality does not appear. Skin corrosion/irritation Skin – Rabbit Results: not an irritant (OECD Test Guideline 404) Serious eye damage/irritation Eye – Rabbit Results: not an irritant (OECD Test Guideline 405) Respiratory or skin sensitization Not a known sensitizer Germ cell mutagenicity AMES Test – > 5 mg/plate (in vitro) Results: negative, with and without metabolic activation (OECD Test Guideline 471) Carcinogenicity IARC: Category for silica, amorphous (7631-86-9) applies to silicas that may contain crystalline silica. The silica in this product is synthetic and does not contain crystalline silica. IARC: Category 3. ACGIH: No component of this product presents at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by ACGIH. NTP: No component of this product presents at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by NTP. OSHA: No component of this product presents at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by OSHA. Repeated Dose Toxicity Oral – NOAEL (90 d) – Rat Results: 9000 mg/kg bw/day (OECD Test guideline 408) Inhalative – NOAEC (90 d) – Rat Results: 1 mg/m3 (rat) (OECD Test Guideline 413) Reproductive toxicity Oral – NOAEL (maternal toxicity/teratogenicity) – Rat Results: 1350 mg/kg bw/day (OECD Test Guideline 414) Specific target organ toxicity – single exposure No data available Specific target organ toxicity – repeated exposure No data available Safety Data Sheet CimeXa™ Insecticide Dust Rockwell - RP0012 Page 7 of 9 Aspiration hazard No data available 11.2. Other information No data available _______________________________________________________________________________________ 12. ECOLOGICAL INFORMATION 12.1. Toxicity Toxicity to fish LC50 – Danio rerio (Zebra Fish) - > 10,000 mg/l – 96 h Toxicity to daphnia EC50 – Daphnia magna (Water flea) - > 1000 mg/l – 24 h and other aquatic EC50 – Scenedesmus subspicatus (Algae) - > 10000 mg/l – 72 h invertebrates 12.2. Persistence and degradability Amorphous silica dioxide is chemically and biologically inert. By the insolubility in water there is a separation at every filtration and sedimentation process. 12.3. Bioaccumulative potential Does not accumulate in organisms. 12.4. Mobility in soil No data available 12.5. Other adverse effects No data available _______________________________________________________________________________________ 13. DISPOSAL CONSIDERATIONS 13.1. Disposal Methods. The best disposal method is to use the entire quantity per label directions. If it is necessary to dispose of unused material then follow the label instructions and relevant local, state and federal waste disposal guidelines. Product Disposal: Do not contaminate water, food or feed by storage or disposal. Packaging Disposal: If empty: Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency or 1- 800-CLEANUP which is managed as a public-private partnership. See section 8 for proper PPE and precautionary handling measures. _______________________________________________________________________________________ 14. TRANSPORT INFORMATION DOT Not dangerous goods IMDG Not dangerous goods IATA Not dangerous goods Safety Data Sheet CimeXa™ Insecticide Dust Rockwell - RP0012 Page 8 of 9 ______________________________________________________________________________________________ 15. REGULATORY INFORMATION This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: KEEP OUT OF THE REACH OF CHILDREN CAUTION Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. SARA 302 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards None California Proposition 65 Components This product does not contain any chemicals known to the state of California to cause cancer, birth defects, or reproductive harm. TSCA All components of this product are listed, exempted, or excluded from listing on the U.S. Toxic Substances Control Act chemical substance inventory. _______________________________________________________________________________________ 16. OTHER INFORMATION Acronyms and abbreviations used LD50 Lethal Dose, 50% OECD Organization for Economic Cooperation and Development IARC International Agency for Research on Cancer ACGIH American Conference of Industrial Hygienists NTP National Toxicology Program OSHA Occupational Safety and Health Administration DOT Department of Transportation IMDG International Maritime Dangerous Goods IATA International Air Transport Association SARA Superfund Amendments and Reauthorization Act TSCA Toxic Substances Control Act Safety Data Sheet CimeXa™ Insecticide Dust Rockwell - RP0012 Page 9 of 9 CAS-No. Chemical Abstract Services - Number PPE Personal Protective Equipment HMIS Hazardous Materials Identification System NFPA National Fire Protection Association PPM Parts Per Million TWA Time Weighted Average IDLH Immediately Dangerous to Life or Health PEL Permissible Exposure Limit REL Recommended Exposure Limit TLV Threshold Limit Value LC50 Lethal Concentration, 50% EC50 Effective concentration, half maximal ANSI American National Standards Institute APF Assigned Protection Factor Hazard Rating System Crossover HMIS Rating NFPA Rating Health Hazard: 0 Health Hazard: 0 Flammability: 0 Flammability: 0 Reactivity: 0 Reactivity: 0 Preparation information Prepared by: Rockwell Labs Ltd Version: 1.1 Revision Date: May 17, 2017 Reason for revision: Updated ingredient composition with more appropriate information Notice to Reader: The information provided in this Safety Data Sheet has been obtained from sources believed to be reliable. Rockwell Labs Ltd provides no warranties, express or implied, and assumes no responsibility for the accuracy and completeness of the data contained herein. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are trademarks of Rockwell Labs Ltd. Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 1/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) 1. Identificación Identificador del producto utilizado en la etiqueta Cy-Kick CS. Uso recomendado del producto químico y restricciones de uso Utilización adecuada*: Insecticida * El 'Uso recomendado' identificado para este producto se facilita únicamento para cumplir con un requerimiento federal y no es parte de las especificaciones publicadas por el vendedor. Los términos de esta Ficha de Datos de Seguridad (FDS) no crean ni generan ninguna garantía, expresa o implícita, incluída por incorporación en el acuerdo de venta con el vendedor o en referencia al mismo. Datos del proveedor de la ficha de datos de seguridad Empresa: BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA Dirección de contacto: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932 USA Teléfono: +1 973 245-6000 Teléfono de emergencia CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP (4357) Otros medios de identificación Número de sustancia: 792075 Número de Registro de la EPA: 499-304 2. Identificación de los peligros Según la reglamentación 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Clasificación del producto Flam. Liq. 4 Líquidos inflamables Elementos de la etiqueta Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 2/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) Indicaciones de peligro: H227 Líquido combustible. 3. Composición / Información Sobre los Componentes Según la reglamentación 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Número CAS Peso % Nombre químico 68359-37-5 6.0 % Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2- dimethyl-, cyano(4-fluoro-3-phenoxyphenyl)methyl ester 4. Medidas de primeros auxilios Descripción de los primeros auxilios Indicaciones generales: Quitarse la ropa contaminada. En caso de inhalación: Reposo, respirar aire fresco. En caso de contacto con la piel: Lavar abundantemente con agua y jabón. En caso de contacto con los ojos: Lavar los ojos abundantemente durante 15 minutos con agua corriente y los párpados abiertos. En caso de ingestión: Lavar la boca y beber posteriormente abundante agua. Principales síntomas y efectos, agudos y retardados Síntomas: Los efectos y síntomas conocidos más importantes se describen en la etiqueta (ver sección 2) y/o en la sección 11., Síntomas y efectos adicionales más importantes son desconocidos hasta ahora. Indicación de cualquier atención médica inmediata y de los tratamientos especiales que se requieran. Indicaciones para el médico Tratamiento: Tratamiento sintomático (descontaminación, funciones vitales). 5. Medidas de lucha contra incendios Medios de extinción Medios de extinción adecuados: agua pulverizada, extintor de polvo, espuma, dióxido de carbono Peligros específicos derivados de la sustancia o la mezcla Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 3/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) Peligro al luchar contra incendio: monóxido de carbono, dióxido de carbono, ácido clorhídrico, Hydrofluoric acid, oxidos de nitrógeno, Compuestos organoclóricos En caso de incendio las sustancias/grupos de sustancias citadas pueden desprenderse. Recomendaciones para el personal de lucha contra incendios Equipo de Protección personal en caso de fuego: Use equipo respiratorio autónomo y traje de protección. Información adicional: Refrigerar con agua los recipientes en peligro. En caso de incendio y/o de explosión no respire los humos. Acumular separadamente el agua de extinción contaminada, al no poder ser vertida al alcantarillado general o a los desagües. Eliminar los restos del incendio y el agua de extinción contaminada respetando las legislaciones locales vigentes. 6. Indicaciones en caso de fuga o derrame Precauciones personales, equipo de protección y procedimientos de emergencia No respirar el vapor/aerosol. Utilizar ropa de protección personal. Evitar el contacto con la piel, ojos y vestimenta. Precauciones relativas al medio ambiente Evitar el vertido en el suelo/subsuelo. Evitar el vertido en el alcantarillado, aguas superficiales o subterráneas. Métodos y material de contención y de limpieza Cercar/retener con diques. Recoger con materiales absorbentes adecuados. Coloque en contenedores adecuados para su reutilización o eliminación en una instalación autorizada. Siempre que sea posible, la sustancia/producto vertidos se debe recuperar y aplicar conforme a las instrucciones de la etiqueta. Si la aplicación de la sustancia/producto vertidos no es posible, se rá necesario recoger, solidificar y colocar los vertidos en contenedores adecuados para su eliminación. Después de descontaminar, el área de derrame se puede lavar con agua. Recoja el agua de lavado para su eliminación adecuada. 7. Manipulación y almacenamiento Precauciones para una manipulación segura RECOMENDACIONES PARA TRABAJADORES DE PLANTAS DE FABRICACIÓN, MEZCLAS COMERCIALES Y ENVASADO. TRABAJADORES Y APLICADORES DE PESTICIDAS deben consultar la Etiqueta del Producto y las Directrices de Uso que se encuentran junto al producto. Procurar buena ventilación de los locales; dado el caso, instalar aspiración localizada en el lugar de trabajo. Conservar alejado de toda llama o fuente de chispas - No fumar. Mantener los recipientes cerrados herméticamente. Proteger de los efectos del calor. Abrir y manipular cuidadosamente el recipiente. No abra hasta que esté listo para su uso Consumir lo antes posible el contenido de envases dañados. Proporcione medios para controlar fugas y vertidos. Seguir las advertencias indicadas en la etiqueta, también con los envases vacíos. La sustancia/el producto sólo debe ser manipulado por personal especializado. Evitar todo contacto directo con la sustancia / pr oducto. Evitar el contacto con la piel, ojos y vestimenta. Evitar la inhalación de polvos/neblinas/vapores. Lleve la indumentaria y el equipo de protección personal adecuados. Protección contra incendio/explosión: No se recomienda ninguna medida especial. La sustancia/el producto no es combustible. El producto no es explosivo. Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 4/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) Condiciones de almacenamiento seguro, incluidas posibles incompatibilidades Separar de alimentos, bebidas y alimentos para animales Otras especificaciones sobre condiciones almacenamiento: Conservar alejado del calor. Proteger de la irradiación solar directa. 8. Controles de exposición/Protección personal Usuarios de productos pesticidas deben observar en la etiqueta del producto los equipos requeridos para protección del personal. No hay límites de exposición profesional conocidos Equipo de protección personal RECOMENDACIONES PARA LOS TRABAJADORES EN L A FABRICACIÓN, MEZCLA COMERCIAL Y EMBALAJE: Protección de las vías respiratorias: Protección de las vías respiratorias en caso de ventilación insuficiente. Utilice un respirador para vapores orgánicos y de partículas certificado por NIOSH (Instituto Nacional de Salud y Seguridad Ocupacional) (o equivalente). En situaciones en las que las concentraciones de aire excedan el nivel en el que un respirador purificante de aire sea efectivo, o en las que los niveles son desconocidos o Inmediatamente Peligrosos para la Vida o la Salud (IDLH), debe utilizarse un aparato respiratorio autónomo (SCBA) a demanda que cubra toda la cara certificado por el NIOSH (Instituto Nacional de Salud y Seguridad Ocupacional) o un respirador de aire (SAR) a demanda que cubra toda la cara con válvula de escape. Protección de las manos: Guantes de protección resistentes a productos químicos, La selección del guante protector debe basarse en la evaluación de riesgos en el puesto de trabajo del usuario Protección de los ojos: Gafas protectoras con cubiertas laterales. Gafas de seguridad con cierre hermético (Gafas cesta). Usar pantalla facial, si existe riesgo de pulverización. Protección corporal: La protección corporal debe ser seleccionada dependiendo de la actividad y pos ible exposición, Ejemplo: Protección para la cabeza (casco), mandil, botas y ropa de protección química. Medidas generales de protección y de higiene: Para la manipulación de productos fitosanitarios en envases destinados al usuario final, se han de tener en consideración las recomendaciones de uso. Se recomienda llevar ropa de trabajo cerrada. Guardar por separado la ropa de trabajo. Manténgase lejos de alimentos, bebidas y piensos. 9. Propiedades físicas y químicas Forma: líquido Olor: inodoro Umbral de olor: no aplicable, olor no perceptible Color: blanquecino Valor pH: aprox. 5.5 - 7.5 ( 20 °C) Punto de fusión: aprox. 0 °C Información aplicable al disolvente. Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 5/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) Temperatura de ebullición: aprox. 100 °C Información aplicable al disolvente. Punto de inflamación: > 85 °C Infllamabilidad: no aplicable Límite inferior de explosividad: Como resultado de nuestra experiencia con este producto y de nuestro conocimiento de su composición, no esperamos que presente ningún peligro siempre y cuando el producto se utilice adecuadamente y de acuerdo con el uso previsto Límite superior de explosividad: Como resultado de nuestra experiencia con este producto y de nuestro conocimiento de su composición, no esperamos que presente ningún peligro siempre y cuando el producto se utilice adecuadamente y de acuerdo con el uso previsto Autoinflamación: aprox. > 300 °C El producto no ha sido ensayado. La valoración ha sido calculada a partir de las propiedades de sus componentes individuales. Presión de vapor: aprox. 23.4 hPa ( 20 °C) Información aplicable al disolvente. Densidad: aprox. 1.0 g/cm3 ( 20 °C) Densidad de vapor: no aplicable Coeficiente de reparto n-octanol/agua (log Pow): no aplicable Descomposición térmica: Ninguna descomposición, si se almacena y aplica como se indica/está prescrito. Viscosidad, cinemática: aprox. 500 mm2/s ( 40 °C) Solubilidad en agua: dispersable Velocidad de evaporación: no aplicable Otra información: El producto no ha sido ensayado. La indicación se ha deducido a partir de sustancias o productos de una estructura o composición similar. 10. Estabilidad y reactividad Reactividad Ninguna reacción peligrosa, si se tienen en consideración las normas/indicaciones sobre almacenamiento y manipulación. Propiedades comburentes: Debido a la estructura el producto no se clasifica como comburente. Estabilidad química El producto es estable si se tienen en consideración las normas/indicaciones sobre almacenamiento y manipulación. Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 6/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) Posibilidad de reacciones peligrosas Ninguna reacción peligrosa, si se tienen en consideración las normas/indicaciones sobre almacenamiento y manipulación. Condiciones que deben evitarse Ver FDS capítulo 7 - Manipulación y almacenamiento. Materiales incompatibles ácidos fuertes, bases fuertes, fuertes agentes oxidantes Productos de descomposición peligrosos Productos de la descomposición: Productos peligrosos de descomposición: No se presentan productos peligrosos de descomposición, si se tienen en consideración las normas/indicaciones sobre almacenamiento y manipulación. Descomposición térmica: Ninguna descomposición, si se almacena y apl ica como se indica/está prescrito. 11. Información sobre toxicología vías primarias de la exposición Las rutas de entrada para sólidos y líquidos son la ingestión y la inhalació n pero puede incluirse contacto con la piel o los ojos. Las rutas de entrada para gases incluye la inhalación y el contacto con los ojos. El contacto con la piel puede ser una ruta de entrada para gases licuados. Toxicidad aguda/Efectos Toxicidad aguda Valoración de toxicidad aguda: Después de una ingestión oral prácticamente no es tóxico. Prácticamente no tóxico, después de una única inhalación. Prácticamente no tóxico por un único contacto cutáneo. El producto no ha sido ensayado. La indicación se ha deducido a partir de sustancias o productos de una estructura o composición similar. Oral Tipo valor: DL50 Especies: rata (hembra) valor: > 5,000 mg/kg (directriz OCDE 425) No se observó mortalidad. Inhalación Tipo valor: CL50 Especies: rata (macho/hembra) valor: > 5.1 mg/l (Directiva 403 de la OCDE) No se observó mortalidad. Dérmica Tipo valor: DL50 Especies: rata (macho/hembra) valor: > 5,000 mg/kg (Directiva 402 de la OCDE) No se observó mortalidad. Valoración de otros efectos agudos. Evaluación simple de la STOT (Toxicidad específica en determinados órganos): Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 7/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) Basado en la información disponible no se espera toxicidad específica en determinados órganos tras una sóla exposición El producto no ha sido ensayado. La valoración ha sido calculada a partir de las propiedades de sus componentes individuales. Irritación/ Corrosión Valoración de efectos irritantes: No es irritante para la piel. No es irritante para los ojos. El producto no ha sido ensayado. La indicación se ha deducido a partir de sustancias o productos de una estructura o composición similar. piel Especies: conejo Resultado: no irritante ojo Especies: conejo Resultado: no irritante Sensibilización Valoración de sensibilización: No existen evidencias de un potencial efecto de sensibilización de la piel. El producto no ha sido ensayado. La indicación se ha deducido a partir de sustancias o productos de una estructura o composición similar. Prueba Buehler Especies: cobaya Resultado: El producto no es sensibilizante. Toxicidad crónica/Efectos Toxicidad en caso de aplicación frecuente Valoración de toxicidad en caso de aplicación frecuente: El producto no ha sido ensayado. La valoración ha sido calculada a partir de las propiedades de sus componentes individuales. Tras una administación repetida en animales de ensayo no se observó ninguna toxicidad en órganos de sustancia específica. Toxicidad genética Valoración de mutagenicidad: El producto no ha sido ensayado. La valoración ha sido calculada a partir de las propiedades de sus componentes individuales. Los test de mutagenicidad no dan ninguna indicación sobre un potencial genotóxico. Carcinogenicidad Valoración de carcinogenicidad: El producto no ha sido ensayado. La valoración ha sido calculada a partir de las propiedades de sus componentes individuales. En varios ensayos realizados en animales no se han observado efectos carcinogénicos. Toxicidad en la reproducción Valoración de toxicidad en la reproducción: El producto no ha sido ensayado. La valoración ha sido calculada a partir de las propiedades de sus componentes individuales. Durante los ensayos en el animal no se observaron efectos que perjudican la fertilidad. Teratogenicidad Valoración de teratogenicidad: El producto no ha sido ensayado. La valoración ha sido calculada a partir de las propiedades de sus componentes individuales. En ensayos con animales realizados a una dosis que no es tóxica para los progenitores no se observaron efectos teratogénicos. Otra información Una incorrecta utilización puede ser perjudicial para la salud. Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 8/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) Síntomas de la exposición Los efectos y síntomas conocidos más importantes se describen en la etiqueta (ver sección 2) y/o en la sección 11., Síntomas y efectos adicionales más importantes son desconocidos hasta ahora. 12. Información ecológica Toxicidad Toxicidad acuática Valoración de toxicidad acuática: Muy tóxico para los organismos acuáticos, con efectos nocivos duraderos. El producto no ha sido ensayado. La valoración ha sido calculada a partir de las propiedades de sus componentes individuales. Toxicidad en peces Indicaciones para: CYFLUTHRIN Tech 98% CL50 (96 h) 0.00047 mg/l, Oncorhynchus mykiss ---------------------------------- Invertebrados acuáticos Indicaciones para: CYFLUTHRIN Tech 98% CE50 (48 h) 0.00016 mg/l, Daphnia magna ---------------------------------- Plantas acuáticas Indicaciones para: CYFLUTHRIN Tech 98% CE50 (96 h) > 10 mg/l, Scenedesmus subspicatus ---------------------------------- Toxicidad crónica peces Indicaciones para: CYFLUTHRIN Tech 98% NOEC (307 Días) 0.00014 mg/l, Oncorhynchus mykiss NOEC (58 Días) 0.00001 mg/l, Oncorhynchus mykiss ---------------------------------- Persistencia y degradabilidad Valoración de biodegradación y eliminación (H2O) El producto no ha sido ensayado. La valoración ha sido calculada a partir de las propiedades de sus componentes individuales. Valoración de biodegradación y eliminación (H2O) Indicaciones para: CYFLUTHRIN Tech 98% Según los criterios de la OCDE el producto no es fácilmente biodegradable, a pesar de esto es potencialmente biodegradable ---------------------------------- Potencial de bioacumulación Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 9/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) Evaluación del potencial de bioacumulación El producto no ha sido ensayado. La valoración ha sido calculada a partir de las propiedades de sus componentes individuales. Potencial de bioacumulación Indicaciones para: CYFLUTHRIN Tech 98% Factor de bioconcentración: 854 (14 Días), Lepomis macrochirus ---------------------------------- Movilidad en el suelo Evaluación de la movilidad entre compartimentos medioambientales El producto no ha sido ensayado. La valoración ha sido calculada a pa rtir de las propiedades de sus componentes individuales. Indicaciones para: CYFLUTHRIN Tech 98% En caso de vertido a suelo, el producto se infiltra en él y, dependiendo de su degradación biológica, puede ser transportado por volúmenes grandes de agua a las capas más profundas del suelo. ---------------------------------- Indicaciones adicionales Más informaciones ecotoxicológicas: No permitir el vertido de forma incontrolada en el medio ambiente. 13. Consideraciones relativas a la eliminación / disposición de residuos Eliminación de la sustancia (residuos): Los residuos de pesticidas están regulados. Si los residuos de pesticida no se pueden eliminar conforme a las instrucciones de la etiqueta, pó ngase en contacto con la Autoridad Estatal sobre Pesticidas, la Agencia de Control Medioambiental o el representante de Residuos Peligrosos de la Oficina Regional de la EPA (Agencia de Protección del Medio Ambiente) más cercana. depósitos de envases: Enjuague a fondo al menos tres veces (triple enjuague) conforme a las recomendaciones de la EPA (Agencia de Protección del Medio Ambiente). Consulte a las autoridades locales o estatales de eliminación de residuos sobre procedimientos alternativos aprobados, como el reciclaje de contenedores. Se recomienda el prensado, la perforación u otras medidas para prevenir el uso no autorizado de contenedores usados. 14. Información relativa al transporte Transporte por tierra USDOT Mercancía no peligrosa según los criterios de la reglamentación del transporte Transporte marítimo por barco IMDG Sea transport IMDG Clase de peligrosidad: 9 Hazard class: 9 Grupo de embalaje: III Packing group: III Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 10/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) Número ID: UN 3082 ID number: UN 3082 Etiqueta de peligro: 9, EHSM Hazard label: 9, EHSM Contaminante marino: SÍ Marine pollutant: YES Denominación técnica de expedición: SUSTANCIA LÍQUIDA PELIGROSA PARA EL MEDIO AMBIENTE, N.E.P. (contiene CIFLUTHRINE) Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains CIFLUTHRINE) Transporte aéreo IATA/ICAO Air transport IATA/ICAO Clase de peligrosidad: 9 Hazard class: 9 Grupo de embalaje: III Packing group: III Número ID: UN 3082 ID number: UN 3082 Etiqueta de peligro: 9, EHSM Hazard label: 9, EHSM Denominación técnica de expedición: SUSTANCIA LÍQUIDA PELIGROSA PARA EL MEDIO AMBIENTE, N.E.P. (contiene CIFLUTHRINE) Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains CIFLUTHRINE) 15. Reglamentaciones Reglamentaciones federales Situación del registro: Producto químico TSCA, US no autorizado / no inscrito protección de cultivos TSCA, US libre / exento EPCRA 311/312 (categorías de peligro): Consulte la sección 2 de la Hoja de Datos de Seguridad para los peligros del Sistema Globalmente Armonizado aplicables a este producto. EPCRA 313: Número CAS Nombre químico 68359-37-5 Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)- 2,2-dimethyl-, cyano(4-fluoro-3-phenoxyphenyl)methyl ester Reglamentación estatal RTK - Estado Número CAS Nombre químico NJ 68359-37-5 Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)- 2,2-dimethyl-, cyano(4-fluoro-3-phenoxyphenyl)methyl ester Safe Drinking Water & Toxic Enforcement Act, CA Prop. 65: ADVERTENCIA: Este producto puede exponerle a productos químicos incluyendo METHANOL , conocido por el Estado de California que puede causar defectos congénitos u otros daños durante la reproducción. Para mayor información, consulte www.P65Warnings.ca.gov. Requerimientos de etiquetado según FIFRA Esta sustancia es un producto pesticida registrado por la Agencia de Protección del Medioambiente y está sujeta a ciertos requerimientos de etiquetado bajo la ley federal de pesticidas. Estos requerimientos difieren de los criterios de clasificación e información de sustancias peligrosas para Hoja de Seguridad Cy-Kick CS. Fecha de revisión : 2018/08/16 Página: 11/11 Versión: 1.1 (30666765/SDS_CPA_US/ES) las FDS, y etiquetas de lugar de trabajo respecto a los productos químicos no pesticidas. A continuación se facilita la información de peligrosidad tal como se requiere en la etiqueta del pesticida. ATENCIÓN: MANTENGASE FUERA DEL ALCANCE DE LOS NINOS. MANTENGA FUERA DEL ALCANCE DE ANIMALES DOMESTICOS Peligroso si es absorbido a través de la piel. Provoca irritación ocular. Evitar el contacto con la piel, ojos y vestimenta. Lavar a fondo tras su manipulación. 16. Otra información FDS creado por: BASF NA Producto Regularizado FDS creado en: 2018/08/16 Respaldamos las iniciativas Responsible Care® a nivel mundial. Valoramos la salud y seguridad de nuestros empleados, clientes, suministradores y vecinos, y la protección del medioambiente. Nuestro compromiso con el Resposible Care es integral llevando a cabo a nuestro negocio y operando nuestras fábricas de forma segura y medioambientalmente responsable, ayudando a nuestros clientes y suministradores a asegurar la manipulación segura y respetuosa con el medioambiente de nuestros productos, y minimizando el impacto de nuestras actividades en la sociedad y en el medioambiente durante la producción, almacenaje, transporte uso y elminación de nuestros productos. Final de la Ficha de Datos de Seguridad DOMINANT®1% application: target pests: Apply DominAnt 1% using refillable liquid bait stations placed at multiple locations around the structure. Refill stations as needed. creating a world of sustainability. Large colonies of ants require large amounts of bait. DominAnt 1% is formulated to have all the attractants of regular DominAnt with a 1% A.I. that gives ants the time to feed the entire colony. DominAnt 1% is specifically formulated for very large or multi-queen ant colonies. The lower active ingredient allows for greater consumption, which helps spread the bait throughout the larger colonies. This gives you effective control over big ant problems. DOMINANT ® 1% = giant kill Remember, always read, understand and comply with the label. DominAnt and Nisus Corporation are registered trademarks of Nisus Corporation. ©2017 Nisus Corporation #DOM1-FLY-0117 100 Nisus Drive • Rockford, TN 37853 800.264.0870 • www.nisuscorp.comLARGE COLONY ANTS Labeled for Argentine ants. • Kills and Controls Sweet Eating Ants • Contains Borax • No Offensive Odors • Use Indoors and Outdoors• Rapidly Attracts Ants ACTIVE INGREDIENT: Sodium Tetraborate Decahydrate (Borax) ..................................... 1.0% OTHER INGREDIENTS .................................................................. 99.0% TOTAL ............................................................................................ 100.0% EPA Reg. No. 64405-24 EPA Est. 64405-TN-1 Keep Out of Reach of Children FOR USE IN AND AROUND: Apartments, Boats, Cafeterias, Commercial and Cruise Ships, Food Processing Plants, Garages, Grocery Stores, Homes, Hospitals, Hotels, Institutional Buildings, Kennels, Military Bases, Military Ships, Mills, Mobile Homes, Motels, Nursing Homes, Pet Stores, Public and Private Institutions, Restaurants, Schools, Storage Areas, Supermarkets, Theaters, Vending Machines, Warehouses and Zoos. APPLY NEAR, ON OR INTO: Appliances, Bathrooms, Baseboards, Corners, Cracks, Crawl Spaces, Crevices, Decks, Dining Rooms, Edible Waste Storage Areas, Fences, Floors, Food Storage Areas, Foundations, Garages, Kitchens, Janitorial Closets, Loading Docks, Liquid Bait Stations, Locker Rooms, Maintenance Rooms, Mechanical Rooms, Offices, Packing Areas, Pallets, Piers, Processing Areas, Receiving Areas, Storage Areas, Trash Rooms, Trees, Utility Rooms, Vending Machines, Walls and Other Areas Ants May Forage. ATTRACTS AND KILLS ALL COMMON HOUSEHOLD ANTS INCLUDING (except pharaoh, carpenter, fire and harvester ants): Acrobat Ants, Argentine Ants, Big-Headed Ants, Cornfield Ants, Crazy Ants, Ghost Ants, Little Black Ants, Odorous House Ants, Pavement Ants, White-Footed Ants and other Sweet-Eating Ants. Precautionary Statements Environmental Hazards: Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high-water mark. Do not contaminate water when disposing of equipment washwaters or rinsate. Physical/Chemical Hazards: Do not mix or allow contact with an oxidizing agent. Hazardous chemical reaction may occur. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Place bait in areas inaccessible to children and pets. DominAnt 1% Liquid Ant Bait is a ready-to-use solution for control of very large, multi-queen or multi-colony ant infestations. BAIT STATIONS: Add DominAnt 1% Liquid Ant Bait solution into bait stations designed to hold liquid bait. Follow directions included with the bait stations to obtain best results. SPRAY APPLICATIONS: Outdoors: Apply bait as a spot or spray application to areas such as foundations, walls, fence posts, piers and other stationary structural components. Indoors: Apply bait into cracks and crevices in kitchens, bathrooms, utility rooms and other areas. Do not over-apply and do not let liquid seep out onto non-target areas. APPLICATION FOR FOOD PROCESSING AND HANDLING ESTABLISHMENTS, INCLUDING FEDERALLY INSPECTED POULTRY AND MEAT PLANTS: In food areas, only apply product into cracks, crevices and other inaccessible areas. Avoid contamination of food and feed stuffs. Cover or remove any food during application. Do not apply product directly onto a surface where food is prepared, served or stored. Any product left visible on a food surface after treatment should be removed and surface washed. In food handling and other areas, record the number and location of bait stations. This product is designed to be used as a residual treatment in an Integrated Pest Management program incorporating good sanitation practices. Food Areas Include: Serving areas, such as dining rooms, food storage areas, receiving areas, processing areas, including enclosed systems such as oil and syrup plants, mills; packing areas, including canning, bottling, wrapping and boxing; and edible waste storage areas. In these areas, direct product applications into cracks and crevices, such as along baseboards and between elements of construction. Do not allow product on any surfaces that may be contacted by food. Do not apply when facility is in operation or when food is exposed. Non-Food areas include: Bathrooms, locker rooms, offices, maintenance rooms, mechanical rooms, trash rooms, garages, janitorial closets, storage areas after bottling or canning and floor drains leading to sewer entries. In these areas, apply product as labeled for other non-food areas. Storage and Disposal Do not contaminate water, food or feed by storage or disposal. STORAGE: Store in a cool dry place. Do not store where children or animals may gain access. PESTICIDE DISPOSAL AND CONTAINER HANDLING: Nonrefillable Container. Do not reuse or refill this container. If Empty: Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency for disposal instructions. Never place unused product down any indoor or outdoor drain. Warranty Disclaimer Manufacturer warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes stated on the label when used in strict accordance with the directions, subject to the inherent risks set forth below. TO THE EXTENT NOT PROHIBITED BY APPLICABLE LAW, MANUFACTURER MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. Inherent Risks of Use The directions for use of this product are believed to be adequate and must be carefully followed. It is impossible to eliminate all risks associated with use of this product. Lack of performance or other unintended consequences may result because of such factors as use of the product contrary to label instructions, abnormal conditions, the presence of other materials, climatic conditions or the manner of use/application, all of which are beyond the control of the Manufacturer. The buyer/user assumes all such risks. Limitation of Remedies To the extent not prohibited by applicable law, the exclusive remedy for losses or damages resulting from this product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer’s election, one of the following: 1. Refund of purchase price paid by buyer or user for product bought, or 2. Replacement of amount of product used. To the extent not prohibited by applicable law: a) Manufacturer shall not be liable for losses or damages resulting from handling or use of this product unless Manufacturer is promptly notified of such loss or damage in writing; and b) TO THE EXTENT NOT PROHIBITED BY APPLICABLE LAW, IN NO CASE SHALL MANUFACTURER BE LIABLE FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Limitation of Remedies cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner. It is not intended that this product be used to practice any applicable patent, whether mentioned or not, without procurement of a license, if necessary, from the owner, following investigation by the user. Nisus Corporation 100 Nisus Drive • Rockford, TN 37853 USA (800) 264-0870 DominAnt and Nisus Corporation are trademarks or registered trademarks of Nisus Corporation. Patent pending. ©2015 Nisus Corporation #DOM1-SL-0415a-SAL081514 SAFETY DATA SHEET Health Emergencies: INFOTRAC® (800) 535-5053 1. PRODUCT AND COMPANY INFORMATION Product Identity: DOMINANT™ 1% Liquid Ant Bait Recommended use of the chemical and restrictions on use: Kills and controls sweet eating ants. Read and understand the entire label before using. Use only according to label directions. It is a violation of Federal law to use this product in a manner inconsistent to label directions. Manufacturer: Nisus Corporation 100 Nisus Drive Rockford, TN 37853 Telephone: Phone: (800) 264-0870 Fax: (865) 577-5825 Emergency Phone: 800-535-5053 (INFOTRAC) SDS Date of Preparation: 01/12/16 2. HAZARDS IDENTIFICATION GHS Classification: Physical Health Environment Not Hazardous Not Hazardous Not Hazardous GHS Label Elements: TE None Required Statements of Hazard Precautionary Statement None Required None Required 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. Amount Non-Hazardous Ingredients Proprietary 99% Sodium Tetraborate Decahydrate (Borax) 1303-96-4 1% The exact formulation is being withheld as a trade secret. 4. FIRST AID MEASURES Eye: Flush victim's eyes with large quantities of water, while holding the eyelids apart. Get medical attention if irritation develops or persists. Skin: Wash skin thoroughly with soap and water. Get medical attention if irritation develops. Remove and launder clothing before re-use. Ingestion: Do not induce vomiting unless directed to do so by a medical professional. Get medical attention for large ingestions or if symptoms develop or if you feel unwell. Inhalation: Remove victim to fresh air. If breathing is difficult or irritation persists, get medical attention. Most important Symptoms: May cause slight eye irritation. Indication of immediate medical attention/special treatment: Immediate medical attention should not be required. 5. FIRE FIGHTING MEASURES Suitable (and Unsuitable) Extinguishing Media: Use media appropriate for surrounding fire. Specific hazards arising from the chemical: Burning may produce carbon monoxide and carbon dioxide. Special Protective Equipment and Precautions for Fire-Fighting Instructions: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures: Wear appropriate protective clothing as described in Section 8. Methods and Materials for Containment and Cleaning Up: Collect with an inert absorbent and place in appropriate containers for disposal. Clean spill area thoroughly. Prevent spill from entering sewers and watercourses. Report releases as required by local, state and federal authorities. 7. HANDLING AND STORAGE Precautions for Safe Handling: Avoid contact with the eyes, skin and clothing. Wear protective clothing and equipment as described in Section 8. Wash thoroughly with soap and water after handling. Remove contaminated clothing immediately and wash before reuse. Remove PPE immediately after handling. Wash thoroughly after using and change into clean clothing. Do not apply this product in a way that will contact workers or other persons. Only protected handlers may be in the area during application. Keep containers closed when not in use. Refer product label for additional information on use and handling. Nonrefillable container. Do not reuse containers. Empty containers retain product residues and can be hazardous. Follow all SDS precautions when handling empty containers. Conditions for Safe Storage, Including Any Incompatibilities: Store in a cool, dry area away from incompatible materials. Keep containers closed when not in use. Do not store where children or animals may gain access. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines: Sodium Tetraborate Decahydrate (as borate compounds) 2 mg/m3 TWA, 6 mg/m3 STEL ACGIH TLV (Inhalable) Engineering Controls: Use with adequate ventilation to maintain exposure levels below the occupational exposure limits. Refer product label for additional information. Respiratory Protection: In operations where exposure levels are exceeded, a NIOSH approved respirator with dust/mist cartridges appropriate for the form and concentration of the contaminants should be used. Selection and use of respiratory equipment must be in accordance with OSHA 1910.134 and good industrial hygiene practice. Refer to the product label for additional information. Skin Protection: Use waterproof gloves for normal application of this product. Eye Protection: Wear safety glasses to prevent eye contact. Other: Wear long-sleeve shirts, long pants, socks and shoes when using this product. Suitable washing facilities should be available in the work area. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Clear odorless liquid Physical State: Liquid Odor Threshold: Not established Vapor Density: N/A Initial Boiling Point/Range: 104°C (220°F) Solubility In Water: 100% Vapor Pressure: Not determined Relative Density: Not determined Evaporation Rate: Not determined Melting/Freezing Point: N/A pH: 7.12 Percent Volatile: None Octanol/Water Coefficient: N/A Solubility: Soluble in water Decomposition Temperature: N/A Viscosity: Not determined Flammability (solid, gas): N/A Flashpoint: Not flammable Autoignition Temperature: None Flammable Limits: LEL: Not determined UEL: Not determined 10. STABILITY AND REACTIVITY Reactivity: Not normally reactive Chemical Stability: Stable under normal storage and handling conditions. Possibility of Hazardous Reactions: Contact with oxidizing agents may cause an adverse reaction. Conditions to Avoid: None known. Incompatible Materials: Avoid oxidizing agents. Hazardous Decomposition Products: When heated to decomposition emits carbon monoxide and carbon dioxide. 11. TOXICOLOGICAL INFORMATION HEALTH HAZARDS: Ingestion: May be harmful if large quantities are ingested. Eye: May cause slight irritation. Skin: Not expected to cause irritation. Chronic: Borates have been shown to have some chronic toxicity in animals fed high doses, similar to that of alcohol, but this has not been found in humans. Sensitization: This material is not expected to cause sensitization. Carcinogenicity: None of the components is listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA. Germ Cell Mutagenicity: No data available Reproductive Toxicity: Borates have been found to have some reproductive toxicity in animals, but this has not been found in humans. Numerical Measures of Toxicity: Product Toxicity Data: Oral rat LD50: >5000 mg/kg, Dermal rabbit LD50: >2000 mg/kg 12. ECOLOGICAL INFORMATION This product breaks down naturally in the environment to provide organic matter and boron micro nutrients. Boron occurs naturally in sea water at an average concentration of 5 mg B/l and fresh water at 1 mg B/l or less. In dilute aqueous solutions the predominant boron species present is undissociated boric acid. Ecotoxicity: Sodium Tetraborate Decahydrate: 96hr LC50 Common Dab: 74 mg B/L, 48hr LC50 Daphnia magna: 530 mg B/L, 96hr EC10 Green algae: 24 mg B/L Persistence and Degradability: Boron is naturally occurring and ubiquitous in the environment. Dominant 1% Liquid Ant Bait decomposes in the environment to natural borate. Bioaccumulative Potential: Not determined. Mobility in Soil: Not determined. Other Adverse Effects: Some plants are sensitive to boron. Avoid releases into the environment. This product is designed to be used for certain types of insects. Use product only as directed on the label. Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high-water mark. Do not contaminate water when disposing of equipment washwaters or rinsate. See product label for full instructions and restrictions on use. 13. DISPOSAL CONSIDERATION Do not contaminate water when disposing of equipment washwaters or rinsate. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Non-refillable container; do not reuse or refill this container. Completely empty container into application equipment, then offer for recycling, if available; otherwise dispose of empty container in a sanitary landfill or by incineration. Never place unused product down any indoor or outdoor drain. Dispose in accordance with local, state and federal environmental regulations. 14. TRANSPORTATION INFORMATION DOT Hazardous Materials Description: Not Regulated 15. REGULATORY INFORMATION This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. FIFRA Labeling: Dominant 1% Liquid Ant Bait EPA Reg. No. 64405-24 Keep Out of Reach of Children PRECAUTIONARY STATEMENTS Environmental Hazards: Do not apply directly to water, to areas where surface water is present, or to intertidal areas below the mean high- water mark. Do not contaminated water when disposing of equipment washwaters or rinsate. Physical/Chemicals Hazards: Do not mix or allow contact with oxidizing agent. Hazardous chemical reaction may occur. CERCLA: This product is not subject to reporting under CERCLA. Some states have more stringent reporting requirements. Report all spills in accordance with local, state, and federal regulations. SARA Hazard Category (311/312): Not hazardous SARA 313: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): None EPA TSCA Inventory: This product is regulated under FIFRA, thus exempt. 16. OTHER INFORMATION NFPA Rating: Health = 0 Flammability = 0 Instability = 0 HMIS Rating: Health = 1 Flammability = 0 Physical Hazard = 0 SDS Revision History: 03/26/15: New SDS 01/12/16: Revised WARRANTY DISCLAIMER The information, data and recommendations contained herein are believed to be accurate but may not be all inclusive and should only be used as a guide. The information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the product for his particular use and on condition that they assume the risk of the use thereof. With respect to this publication and the product related thereto, unless otherwise expressly provided by Manufacturer in writing, MANUFACTURER MAKES NO EXPRESS OR IMPLIED WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. Remedy/Liability Limits The exclusive remedy for losses or damages resulting from this publication or the related product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer’s sole election, one of the following: 1. Refund of purchase price paid by buyer or user for product bought, or 2. Replacement of amount of product used. Manufacturer shall not be liable for losses or damages resulting from use of this publication or handling or use of this product, IN NO CASE SHALL MANUFACTURER BE LIABLE FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Remedy/Liability Limits cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner. 100 Nisus Drive • Rockford, TN 37853 USA • (800) 264-0870 DominAnt and Nisus Corporation are trademarks or registered trademarks of Nisus Corporation. ©2016• #DOM1-SDS-011216a 100 Nisus Drive • Rockford, TN 37853 USA 800-264-0870 Essentria IC3 Insect Concentrate Safety Data Sheet Date of issue: 01/26/2015 Revision date: 01/18/2018 Supersedes: 12/08/2017 Version: 1.1 01/18/2018 EN (English US)Page 1 SECTION 1: Identification 1.1.Identification Product form :Mixture Trade name :Essentria IC3 Insect Concentrate Synonyms :674610, 100208730, 100208930, 100532769 1.2.Recommended use and restrictions on use Recommended use :Insecticide. Restrictions on use :Keep out of reach of children. Avoid contact with eyes, skin and clothing. Do not use or store near heat or open flame. Do NOT take internally. 1.3.Supplier Envincio, LLC 1501 E. Woodfield Road, Suite 200W Schaumburg, IL 60173 - United States 1.4.Emergency telephone number Emergency number : 1-800-248-7763 1-800-424-9300 - CHEMTREC 1-703-527-3887 - CHEMTREC - Outside North America - Collect Calls Accepted SECTION 2: Hazard(s) identification 2.1.Classification of the substance or mixture GHS-US classification Flammable liquids Category 4 Combustible liquid Acute toxicity (oral) Category 4 Harmful if swallowed Skin corrosion/irritation Category 2 Causes skin irritation Serious eye damage/eye irritation Category 1 Causes serious eye damage Skin sensitization, Category 1 May cause an allergic skin reaction Reproductive toxicity Category 1B May damage fertility or the unborn child Specific target organ toxicity (single exposure) Category 3 May cause drowsiness or dizziness Aspiration hazard Category 1 May be fatal if swallowed and enters airways 2.2.GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US): GHS05 GHS07 GHS08 Signal word (GHS-US):Danger Hazard statements (GHS-US):Combustible liquid Harmful if swallowed May be fatal if swallowed and enters airways Causes skin irritation May cause an allergic skin reaction Causes serious eye damage May cause drowsiness or dizziness May damage fertility or the unborn child Precautionary statements (GHS-US):Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, open flames, sparks. - No smoking. Avoid breathing fume, gas, mist, spray, vapors. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace Wear Gloves. If swallowed: Immediately call un centro de toxicología o a un médico Essentria IC3 Insect Concentrate Safety Data Sheet 01/18/2018 EN (English US)2/7 If swallowed: Call un centro de toxicología o a un médico if you feel unwell If on skin: Wash with plenty of water If inhaled: Remove person to fresh air and keep comfortable for breathing If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If exposed or concerned: Get medical advice/attention. Immediately call a poison center or doctor. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Wash contaminated clothing before reuse. In case of fire: Use media other than water to extinguish. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Dispose of contents/container to in accordance with local/regional/national/international regulations 2.3.Other hazards which do not result in classification Other hazards not contributing to the classification :Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. 2.4.Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1.Substances Not applicable 3.2.Mixtures Name Product identifier % Rosemary oil (CAS-No.) 8000-25-7 10 Geraniol (CAS-No.) 106-24-1 5 Peppermint Oil (CAS-No.) 8030-01-1 2 Wintergreen Oil (CAS-No.) 68917-75-9 37 Mineral oil, white (CAS-No.) 8042-47-5 40 Vanillin (CAS-No.) 121-33-5 3 Other ingredients (CAS-No.) N/A Balance SECTION 4: First-aid measures 4.1.Description of first aid measures First-aid measures general :Call a physician immediately. First-aid measures after inhalation :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact :IF ON SKIN: Wash with plenty of soap and water. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. If eye irritation persists: Get medical advice and attention. First-aid measures after ingestion :IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Call a physician immediately. Do NOT induce vomiting unless directed to do so by medical personnel. 4.2.Most important symptoms and effects (acute and delayed) Symptoms/effects :May cause drowsiness or dizziness. Symptoms/effects after skin contact :Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact :Serious damage to eyes. Symptoms/effects after ingestion :Aspiration Hazard - may be fatal if swallowed and enters airways. Harmful if swallowed. Chronic symptoms :May damage fertility or the unborn child. 4.3.Immediate medical attention and special treatment, if necessary Treat symptomatically. Essentria IC3 Insect Concentrate Safety Data Sheet 01/18/2018 EN (English US)3/7 SECTION 5: Fire-fighting measures 5.1.Suitable (and unsuitable) extinguishing media Suitable extinguishing media :Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media :Do not use water. May spread fire. 5.2.Specific hazards arising from the chemical Fire hazard :Combustible liquid. Containers may explode when heated. Liquid will float and may re-ignite on surface of water. Reactivity :The product is non-reactive under normal conditions of use, storage and transport. 5.3.Special protective equipment and precautions for fire-fighters Firefighting instructions :Do not allow fire fighting water to escape into waterways or sewers. Eliminate all ignition sources if safe to do so. Do not use direct stream of water. A direct stream of water may spread fire. Ventilate closed spaces before entering. Do not breathe gas/fumes/vapor/spray. Protection during firefighting :Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1.Personal precautions, protective equipment and emergency procedures 6.1.1.For non-emergency personnel Emergency procedures :No open flames, no sparks, and no smoking. Only qualified personnel equipped with suitable protective equipment may intervene. Avoid breathing dust/fume/gas/mist/vapors/spray. 6.1.2.For emergency responders Protective equipment :Do not attempt to take action without suitable protective equipment. For further information refer to section 8: Exposure controls/personal protection. Emergency procedures :ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Evacuate unnecessary personnel. Stop leak if safe to do so. Ventilate area. 6.2.Environmental precautions Avoid release to the environment. 6.3.Methods and material for containment and cleaning up Methods for cleaning up :Absorb spills with an inert material, clay granules or other inert absorbent material and put in container for disposal. Wear appropriate personal protective equipment, avoid direct contact. SECTION 7: Handling and storage 7.1.Precautions for safe handling Precautions for safe handling :Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Wear personal protective equipment. Do not handle until all safety precautions have been read and understood. Use only outdoors or in a well-ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes. Hygiene measures :Separate working clothes from town clothes. Launder separately. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2.Conditions for safe storage, including any incompatibilities Storage conditions :Store in a well-ventilated place. Keep cool. Store locked up. Keep container tightly closed. Keep from freezing. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Incompatible materials :Heat, sparks, open flame. Strong oxidizers. SECTION 8: Exposure controls/personal protection 8.1.Control parameters Mineral oil, white (8042-47-5) ACGIH ACGIH TWA (mg/m³)5 mg/m³ ACGIH ACGIH STEL (mg/m³)10 mg/m³ OSHA OSHA PEL (TWA) (mg/m³)5 mg/m³ Vanillin (121-33-5) AIHA WEEL TWA (mg/m³)10 mg/m³ Essentria IC3 Insect Concentrate Safety Data Sheet 01/18/2018 EN (English US)4/7 8.2.Appropriate engineering controls Appropriate engineering controls :Adequate ventilation systems as needed to control concentrations of airborne contaminants below applicable threshold limit values. Environmental exposure controls :Avoid release to the environment. 8.3.Individual protection measures/Personal protective equipment Hand protection: Wear chemically resistant protective gloves. Eye protection: Chemical goggles or face shield Skin and body protection: It is recommended for handlers to wear appropriate clothing to prevent skin contact including long sleeves, long pants, socks and shoes. Respiratory protection: In case of insufficient ventilation, use NIOSH approved respiratory protection. SECTION 9: Physical and chemical properties 9.1.Information on basic physical and chemical properties Physical state :Liquid Appearance :Clear, light brown liquid Color :Light brown Odor :Faint, mint-like Odor threshold :No data available pH :No data available Melting point :Not applicable Freezing point :No data available Boiling point :No data available Flash point :145 °F (62.8 °C) Relative evaporation rate (butyl acetate=1):No data available Flammability (solid, gas):Not applicable Vapor pressure :No data available Relative vapor density at 20 °C :No data available Relative density :0.985 g/ml Solubility :Insoluble Log Pow :No data available Auto-ignition temperature :No data available Decomposition temperature :No data available Viscosity, kinematic :No data available Viscosity, dynamic :No data available Explosion limits :No data available Explosive properties :Not explosive Oxidizing properties :Not applicable 9.2.Other information No additional information available Essentria IC3 Insect Concentrate Safety Data Sheet 01/18/2018 EN (English US)5/7 SECTION 10: Stability and reactivity 10.1.Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2.Chemical stability Stable under normal conditions. 10.3.Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4.Conditions to avoid Avoid contact with hot surfaces. Excessive heat > 110° F. Keep away from fire. No flames, no sparks. Eliminate all sources of ignition. Direct sunlight. Do not freeze. 10.5.Incompatible materials Strong oxidizing agents. 10.6.Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. May decompose upon heating to produce toxic vapors/gases. SECTION 11: Toxicological information 11.1.Information on toxicological effects Essentria IC3 Insect Concentrate ATE (Oral)1841 mg/kg body weight Rosemary oil (8000-25-7) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 10000 mg/kg LC50 inhalation rat (mg/l)(No data available) Geraniol (106-24-1) LD50 oral rat 3600 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat (mg/l)(No data available) Wintergreen Oil (68917-75-9) LD50 oral rat 887 mg/kg LD50 dermal (No data available) LC50 inhalation rat (mg/l)(No data available) Mineral oil, white (8042-47-5) LD50 oral rat > 5000 mg/kg LD50 dermal > 2000 mg/kg LC50 inhalation rat (mg/l)> 5 mg/l/4h Vanillin (121-33-5) LD50 oral rat 1580 mg/kg LD50 dermal rabbit > 5010 mg/kg LD50 dermal (No data available) GHS-US Properties Classification Acute toxicity Oral: Harmful if swallowed. Skin corrosion/irritation Causes skin irritation. Serious eye damage/irritation Causes serious eye damage. Respiratory or skin sensitization May cause an allergic skin reaction. Germ cells mutagen Not classified Carcinogenicity Not classified Reproductive toxicity May damage fertility or the unborn child. Specific target organ toxicant (single exposure) May cause drowsiness or dizziness. Specific target organ toxicant (repeated exposure) Not classified Aspiration hazard May be fatal if swallowed and enters airways. Essentria IC3 Insect Concentrate Safety Data Sheet 01/18/2018 EN (English US)6/7 Potential health effects Inhalation Acute :May cause drowsiness and dizziness. Skin Acute :May cause an allergic reaction in individuals with a sensitivity to Wintergreen oil or Geraniol, Causes skin irritation. Eye Acute :May cause serious eye damage. Ingestion Acute :Aspiration hazard - small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema, Harmful if swallowed. Reproductive Effects :Wintergreen causes birth defects and effects on reproduction. SECTION 12: Ecological information 12.1.Toxicity No additional information available 12.2.Persistence and degradability No additional information available 12.3.Bioaccumulative potential No additional information available 12.4.Mobility in soil No additional information available 12.5.Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1.Disposal methods Product/Packaging disposal recommendations :Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. SECTION 14: Transport information UN number Proper Shipping Name Transport hazard class(es) Packing group Environmental hazards DOT Not regulated Not regulated Not regulated Not regulated Not regulated IMDG Not regulated Not regulated Not regulated Not regulated Not regulated IATA UN3334 Aviation regulated liquid, n.o.s. (rosemary oil) 9 III Not applicable SECTION 15: Regulatory information 15.1. US Federal regulations Rosemary oil (8000-25-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Geraniol (106-24-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Essentria IC3 Insect Concentrate Safety Data Sheet 01/18/2018 EN (English US)7/7 Wintergreen Oil (68917-75-9) Listed on the United States TSCA (Toxic Substances Control Act) inventory Mineral oil, white (8042-47-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Vanillin (121-33-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. US State regulations No additional information available SECTION 16: Other information Date of issue :26 January 2015 Revision date :18 January 2018 Supersedes :08 December 2017 Indication of changes: Revised Sec. 1. Revised Sec. 3. SDS US (GHS HazCom 2012) - CGP The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Safety Data Sheet Section 1: Identification Product identifier Product Name •Extinguish Plus Synonyms •100501900; 100518540; 24550; 24560; 24570; EPA Reg. No 2724-496 Product Description •Pale yellow granule. Relevant identified uses of the substance or mixture and uses advised against Recommended use • Restrictions on use • Pesticide KEEP OUT OF REACH OF CHILDREN. Avoid contact with skin, eyes, or clothing. Details of the supplier of the safety data sheet Manufacturer •Wellmark International 1501 E. Woodfield Road, Suite 200 West Schaumburg, IL 60173 United States www.prestrike.com Emergency telephone number Manufacturer (Transportation)•1-800-424-9300 - CHEMTREC Manufacturer (Transportation)•1-703-527-3887 - CHEMTREC - Outside North America - Collect Calls Accepted Manufacturer •1-800-347-8272 Section 2: Hazard Identification United States (US) According to: OSHA 29 CFR 1910.1200 HCS Classification of the substance or mixture OSHA HCS 2012 •Reproductive Toxicity 1B Combustible Dust Skin Sensitization 1B Label elements OSHA HCS 2012 DANGER Extinguish PlusExtinguish PlusExtinguish PlusExtinguish Plus Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014 Revision Date: 28/February/2018 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 1 of 9Page 1 of 9Page 1 of 9Page 1 of 9 Hazard statements •May damage fertility or the unborn child. May form combustible dust concentrations in air. May cause an allergic skin reaction Precautionary statements Prevention •Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves . Avoid breathing dust, fume, gas, mist, vapors and/or spray. Response •IF exposed or concerned: Get medical advice/attention. Specific treatment, see supplemental first aid information. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Storage/Disposal •Store locked up. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Other hazards OSHA HCS 2012 •This product is toxic to fish. Section 3 - Composition/Information on Ingredients Substances •Material does not meet the criteria of a substance. Mixtures Composition Chemical Name Identifiers % Hydroquinone, tert-butyl- CAS:1948-33-0 0.05% (s)-Methoprene CAS:65733-16-6 0.25% Hydramethylnon CAS:67485-29-4 0.36% Other ingredients NDA Balance Defatted Grits CAS:68525-86-0 85% TO 95% Section 4: First-Aid Measures Description of first aid measures Inhalation •IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a position comfortable for breathing. If signs/symptoms continue, get medical attention. Skin •IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Eye •IF IN EYES: Rinse with water for several minutes. If eye irritation persists: Get medical advice/attention. Extinguish PlusExtinguish PlusExtinguish PlusExtinguish Plus Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014 Revision Date: 28/February/2018 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 2 of 9Page 2 of 9Page 2 of 9Page 2 of 9 Ingestion •IF SWALLOWED: Call a POISON CONTROL center or doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting unless directed by medical personnel. Most important symptoms and effects, both acute and delayed •May cause allergic skin reaction. (Tertiary butylhydroquinone is a skin sensitizer), may damage fertility or the unborn child. Refer to Section 11 - Toxicological Information. Indication of any immediate medical attention and special treatment needed Notes to Physician •Treat symptomatically and supportively. Section 5: Fire-Fighting Measures Extinguishing media Suitable Extinguishing Media •Use water, foam, carbon dioxide, or dry chemical. Unsuitable Extinguishing Media •Avoid heavy hose streams. Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards •Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Hazardous Combustion Products •Thermal decomposition may produce hydrogen fluoride and oxides of carbon and nitrogen. Advice for firefighters •Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. Runoff from fire control may cause pollution. Do not allow run-off to enter waterways. Section 6 - Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions •Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Do not walk through spilled material. Keep all sources of ignition away and avoid creating dusty conditions. Use appropriate Personal Protective Equipment (PPE) Ventilate enclosed areas. Emergency Procedures •ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Contain spill and monitor for excessive dust accumulation. Avoid unnecessary personnel and equipment traffic in the spill area. Environmental precautions •Avoid run off to waterways and sewers. Methods and material for containment and cleaning up Extinguish PlusExtinguish PlusExtinguish PlusExtinguish Plus Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014 Revision Date: 28/February/2018 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 3 of 9Page 3 of 9Page 3 of 9Page 3 of 9 Containment/Clean-up Measures •Carefully shovel or sweep up spilled material and place in suitable container. Avoid generating dust. Use clean nonsparking tools to collect material. Section 7 - Handling and Storage Precautions for safe handling Handling •Wear appropriate personal protective equipment, avoid direct contact. Avoid breathing dust. Avoid contact with skin, eyes, and clothing. Do not use in areas without adequate ventilation. Take precautionary measures against static charges. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. Wear appropriate personal protective equipment including long-sleeved shirt, long pants, chemical resistant gloves, shoes and socks. Avoid direct contact. Conditions for safe storage, including any incompatibilities Storage •Do not contaminate water, food, or feed by storage or disposal. Store in cool, dry, secure place. Keep container tightly closed. Store container away from pets. This product is formulated with oil. Prolonged exposure to air may turn oil rancid and reducethe attractiveness of the bait. Use within 3 months after opening. Store locked up. Section 8 - Exposure Controls/Personal Protection Control parameters Exposure controls Engineering Measures/Controls •Local exhaust ventilation. Ensure that dust handling systems (such as exhaust ducts, dust collectors, vessels and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is not leakage from the equipment). It is recommended that dust control equipment such as local exhaust ventilation and material transport systems involved in handling of this product contain explosion relief vents or an explosion supression system or an oxygen-deficient environment. Use only appropriately classified electrical equipment. Personal Protective Equipment Pictograms • Respiratory •If airborne dust is present or in case of inadequate ventilation, use appropriate respiratory protection. Eye/Face •Wear safety goggles. Hands •Wear appropriate gloves. Skin/Body •Wear long sleeves and/or protective coveralls. Environmental Exposure Controls •Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. Follow best practice for site management and disposal of waste. Extinguish PlusExtinguish PlusExtinguish PlusExtinguish Plus Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014 Revision Date: 28/February/2018 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 4 of 9Page 4 of 9Page 4 of 9Page 4 of 9 Section 9 - Physical and Chemical Properties Information on Physical and Chemical Properties Material Description Physical Form Solid Appearance/Description Pale yellow granule. Color Pale yellow.Odor mild; corn-like. Odor Threshold No data available General Properties Boiling Point No data available Melting Point/Freezing Point No data available Decomposition Temperature No data available pH No data available Specific Gravity/Relative Density 1.08 g/cc Bulk Density 0.31 g/cc (19 lbs per cubic foot) Water Solubility Insoluble Viscosity Not relevant Volatility Vapor Pressure No data available Vapor Density No data available Evaporation Rate No data available Flammability Flash Point Not relevant UEL No data available LEL No data available Heat of Combustion (ΔHc) No data available Flammability (solid, gas) Data lacking Environmental Octanol/Water Partition coefficient No data available Section 10: Stability and Reactivity Reactivity •This material is friable and can create small dust particles during any handling, processing, and transfer operations. This material can form explosive dust/air suspensions that are ignitable under some conditions. Chemical stability •Stable under normal temperatures and pressures. Possibility of hazardous reactions •Hazardous polymerization not indicated. Conditions to avoid •Heat, sparks, open flame. Incompatible materials •Strong oxidizers. Hazardous decomposition products •Thermal decomposition may produce hydrogen fluoride and oxides of carbon and nitrogen. Section 11 - Toxicological Information Information on toxicological effects Extinguish PlusExtinguish PlusExtinguish PlusExtinguish Plus Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014 Revision Date: 28/February/2018 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 5 of 9Page 5 of 9Page 5 of 9Page 5 of 9 CAS Extinguish Plus NDA Acute Toxicity:Ingestion/Oral-Rat LD50 • >5010 mg/kg 14 Day(s); Skin-Guinea Pig • 5 Week(s) • Comments: Weak skin sensitizer.; Skin-Rabbit LD50 • >5010 mg/kg 14 Day(s); Irritation:Eye-Rabbit • 0.1 g 72 Hour(s) • Essentially non-irritating; Skin-Rabbit • 0.5 g 7 Day(s) • Mild irritation GHS Properties Classification Acute toxicity OSHA HCS 2012 •Classification criteria not met Skin corrosion/Irritation OSHA HCS 2012 •Classification criteria not met Serious eye damage/Irritation OSHA HCS 2012 •Classification criteria not met Skin sensitization OSHA HCS 2012 •Skin Sensitizer 1B Respiratory sensitization OSHA HCS 2012 •Classification criteria not met Aspiration Hazard OSHA HCS 2012 •Classification criteria not met Carcinogenicity OSHA HCS 2012 •Classification criteria not met Germ Cell Mutagenicity OSHA HCS 2012 •Classification criteria not met Toxicity for Reproduction OSHA HCS 2012 •Toxic to Reproduction 1B STOT-SE OSHA HCS 2012 •Classification criteria not met STOT-RE OSHA HCS 2012 •Classification criteria not met Route(s) of entry/exposure •Inhalation, Skin, Eye, Ingestion Potential Health Effects Inhalation Acute (Immediate)•Exposure to dust may cause irritation. Chronic (Delayed)•No data available Skin Acute (Immediate)•May cause an allergic reaction in individuals with a sensitivity to tertiary butylhydroquinone. Chronic (Delayed)•No data available Eye Acute (Immediate)•Exposure to dust may cause mechanical irritation. Chronic (Delayed)•No data available. Ingestion Acute (Immediate)•No data available. Chronic (Delayed)•No data available Reproductive Effects •Repeated and prolonged exposure may cause reproductive effects. Section 12 - Ecological Information Toxicity Components (s)-Methoprene (0.25%)65733-16-6 Aquatic Toxicity-Fish:96 Hour(s) LC50 Rainbow Trout 0.76 mg/L [Acute] 96 Hour(s) LC50 Bluegill >0.37 mg/L [Acute] NOEC Fathead Minnow 0.048 mg/L [Chronic] Aquatic Toxicity-Crustacea: NOEC Mysid Shrimp 0.014 mg/L [Chronic] 48 Hour(s) LC50 Daphnia 0.36 mg/L [Acute] Extinguish PlusExtinguish PlusExtinguish PlusExtinguish Plus Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014 Revision Date: 28/February/2018 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 6 of 9Page 6 of 9Page 6 of 9Page 6 of 9 Hydramethylnon (0.36%)67485-29-4 Aquatic Toxicity-Fish:96 Hour(s) LC50 Rainbow Trout 0.16 mg/L [Acute] Aquatic Toxicity-Crustacea:48 Hour(s) EC50 Water Flea Daphnia magna 1.14 mg/L [Acute] Aquatic Toxicity-Algae and Other Aquatic Plant(s): EC50 Algae 1.4 µg/L [Acute] Persistence and degradability •Methoprene degrades rapidly in sunlight, both in water and on inert surfaces. The pesticide also is metabolized rapidly in soil and does not leach. Bioaccumulative potential •No data available. Mobility in Soil •Methoprene: 10-14 days, rapidly hydrolyzed in soil. Other adverse effects Potential Environmental Effects •This product is toxic to fish. Section 13 - Disposal Considerations Waste treatment methods Product waste •Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Do not empty into drains. Packaging waste •Nonrefillable container. Do not reuse or refill this container. Triple rinse (or equivalent). Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 - Transport Information UN number UN proper shipping name Transport hazard class(es) Packing group DOT Not applicable Not regulated Not applicable Not applicable Environmental hazards IMO/IMDG UN3077 Packaging 5 kg or greater: Environmentally Hazardous Substance, Solid, N.O.S. (contains hydramethylnon)9 III Marine Pollutant IATA/ICAO UN3077 Packaging 5 kg or greater: Environmentally Hazardous Substance, Solid, N.O.S. (contains hydramethylnon)9 III Acute Aquatic Toxicity Special precautions for user •None specified. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code •Not relevant. Other information IMO/IMDG •No data available IATA/ICAO •No data available Section 15 - Regulatory Information Extinguish PlusExtinguish PlusExtinguish PlusExtinguish Plus Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014 Revision Date: 28/February/2018 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 7 of 9Page 7 of 9Page 7 of 9Page 7 of 9 Not applicable Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications •SARA Title III Section 313, Acute, Chronic FIFRA – Pesticide Labeling This material is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non- pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION Precautionary Statements • KEEP OUT OF REACH OF CHILDREN. Hazards to Humans and Domestic Animals •CAUTION: Avoid contact with skin or clothing. Wash hands thoroughly with soap and water after handling. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. First Aid •IF ON SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. You may also contact 1-800-347-8272 for emergency medical treatment information. User Safety Recommendations: Users should: Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. After handling this product, immediately wash the outside of gloves before removing them, then remove gloves and all other PPE. Immediately wash thoroughly and change into clean clothing. Environmental Hazards •This product is toxic to fish. Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment wash waters. Do not apply when weather conditions favor drift from target areas. Inventory Component CAS TSCA (s)-Methoprene 65733-16-6 No Defatted Grits 68525-86-0 Yes Hydramethylnon 67485-29-4 No Hydroquinone, tert- butyl-1948-33-0 Yes United States Environment U.S. - CERCLA/SARA - Section 313 - Emission Reporting •Hydroquinone, tert-butyl-1948-33-0 Not Listed •Hydramethylnon 67485-29-4 1.0 % de minimis concentration •Defatted Grits 68525-86-0 Not Listed •(s)-Methoprene 65733-16-6 Not Listed Extinguish PlusExtinguish PlusExtinguish PlusExtinguish Plus Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014 Revision Date: 28/February/2018 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 8 of 9Page 8 of 9Page 8 of 9Page 8 of 9 Section 16 - Other Information Revision Summary Revision Date MSDS Number Changes 28/February/2018 •Section 14 revised Revision Date •28/February/2018 Last Revision Date •06/April/2016 Preparation Date •24/October/2014 Disclaimer/Statement of Liability •The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Extinguish PlusExtinguish PlusExtinguish PlusExtinguish Plus Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014Preparation Date: 24/October/2014 Revision Date: 28/February/2018 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 9 of 9Page 9 of 9Page 9 of 9Page 9 of 9 Safety Data Sheet Section 1: Identification Product identifier Product Name •Gentrol Aerosol Synonyms •100525782; 37820; EPA Reg. No.: 2724-484; RF 9707 Aerosol Product Description •Clear to pale yellow aerosol spray. Relevant identified uses of the substance or mixture and uses advised against Recommended use •Insect growth regulator Restrictions on use •Keep out of the reach of children. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks and flame. Use in well ventilated area. Do not take internally. Do not inhale. Details of the supplier of the safety data sheet Manufacturer •Wellmark International 1501 E. Woodfield Road, Suite 200W Schaumburg, IL 60173 United States Emergency telephone number Manufacturer •1-800-248-7763 Manufacturer (Transportation)•1-800-424-9300 - CHEMTREC Manufacturer (Transportation)•1-703-527-3887 - CHEMTREC - Outside North America - Collect Calls Accepted Section 2: Hazard Identification United States (US) According to: OSHA 29 CFR 1910.1200 HCS Classification of the substance or mixture OSHA HCS 2012 •Flammable Aerosols 2 Aspiration 1 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Compressed Gas Label elements OSHA HCS 2012 DANGER Gentrol AerosolGentrol AerosolGentrol AerosolGentrol Aerosol Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016 Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 1 of 9Page 1 of 9Page 1 of 9Page 1 of 9 Hazard statements •Flammable aerosol May cause drowsiness or dizziness May be fatal if swallowed and enters airways Contains gas under pressure; may explode if heated Precautionary statements Prevention •Avoid breathing dust, fume, gas, mist, vapors and/or spray. Use only outdoors or in a well-ventilated area. Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Response •IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison control center or doctor if you feel unwell. Call a POISON CENTER or doctor/physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Storage/Disposal •Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Other hazards OSHA HCS 2012 •Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Section 3 - Composition/Information on Ingredients Substances •Material does not meet the criteria of a substance according to United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Mixtures Composition Chemical Name Identifiers % (s)-Hydroprene CAS:65733-18-8 0.36% Distillates (petroleum), hydrotreated light CAS:64742-47-8 8.56% Propane CAS:74-98-6 11.5% Butane CAS:106-97-8 9.5% Other ingredients NDA Balance Section 4: First-Aid Measures Description of first aid measures Inhalation •IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a Gentrol AerosolGentrol AerosolGentrol AerosolGentrol Aerosol Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016 Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 2 of 9Page 2 of 9Page 2 of 9Page 2 of 9 position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin •IF ON SKIN: Wash with plenty of soap and water. Get medical attention if symptoms occur. Eye •IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison control center or doctor for treatment advice. Ingestion •IF SWALLOWED: Aspiration hazard - do NOT induce vomiting. Call a poison control center or doctor immediately for treatment advice. Most important symptoms and effects, both acute and delayed •Aspiration hazard, may cause dizziness or drowsiness if inhaled. Refer to Section 11 - Toxicological Information. Indication of any immediate medical attention and special treatment needed Notes to Physician •Contains petroleum distillate vomiting may cause aspiration pneumonia. Treat symptomatically and supportively. Section 5: Fire-Fighting Measures Extinguishing media Suitable Extinguishing Media •LARGE FIRE: Water spray, fog or regular foam. SMALL FIRES: Dry chemical, CO2, water spray or regular foam. Unsuitable Extinguishing Media •Avoid heavy hose streams. Firefighting Procedures •Flammable aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards •At temperatures above 130°F, container may rupture. Flammable aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. Hazardous Combustion Products •Thermal decomposition may produce toxic vapors/gases. Advice for firefighters •Wear positive pressure self-contained breathing apparatus (SCBA). Section 6 - Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions •Approach leaking or punctured pressurized containers cautiously. Isolate leaking container from all sources of ignition. Avoid breathing fumes. Ventilate enclosed areas. Emergency Procedures • Gentrol AerosolGentrol AerosolGentrol AerosolGentrol Aerosol Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016 Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 3 of 9Page 3 of 9Page 3 of 9Page 3 of 9 ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Avoid unnecessary personnel and equipment traffic in the spill area. Turn off electric power to area. As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Stay upwind. Ventilate closed spaces before entering. Environmental precautions •Avoid run off to waterways and sewers. Methods and material for containment and cleaning up Containment/Clean-up Measures •Keep away from fire, sparks and heated surfaces. SMALL SPILLS: Take up with sand or other non-combustible absorbent material and place into containers for later disposal. Section 7 - Handling and Storage Precautions for safe handling Handling •Do not use or store near heat or open flame. Exposure to temperatures above 130ºF may cause bursting. Do not smoke while using this product. Do not allow product to freeze. Contents under pressure, do not crush, puncture or incinerate. Avoid breathing fumes. Conditions for safe storage, including any incompatibilities Storage •Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF. Keep container tightly closed when not in use. Store in a well-ventilated place. Store in a cool, dry place. Keep out of reach of children. Keep away from sources of ignition – No Smoking. Keep from freezing. NFPA Aerosol Classification: Level 1. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Incompatible Materials or Ignition Sources •Heat, sparks, open flame. Section 8 - Exposure Controls/Personal Protection Control parameters Exposure Limits/Guidelines Result ACGIH NIOSH OSHA Butane (106-97-8) STELs 1000 ppm STEL Not established Not established TWAs Not established 800 ppm TWA; 1900 mg/m3 TWA Not established Propane (74-98-6)TWAs See Appendix F: Minimal Oxygen Content 1000 ppm TWA; 1800 mg/m3 TWA 1000 ppm TWA; 1800 mg/m3 TWA Exposure Limits Supplemental ACGIH •Propane (74-98-6): TLV Basis - Critical Effects: (asphyxia (See Appendix F: Minimal Oxygen Content)) •Butane (106-97-8): TLV Basis - Critical Effects: (CNS impairment) Exposure controls Engineering Measures/Controls •Use adequate ventilation to remove vapors (fumes, dust etc) Personal Protective Equipment Gentrol AerosolGentrol AerosolGentrol AerosolGentrol Aerosol Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016 Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 4 of 9Page 4 of 9Page 4 of 9Page 4 of 9 Pictograms • Respiratory •In case of insufficient ventilation, use NIOSH approved respiratory protection. Eye/Face •Wear safety goggles. Hands •Wear appropriate gloves. Skin/Body •If prolonged exposure is anticipated, it is recommended for handlers to wear appropriate clothing to prevent skin contact. Environmental Exposure Controls •No data available Section 9 - Physical and Chemical Properties Information on Physical and Chemical Properties Material Description Physical Form Aerosol Appearance/Description Clear to pale yellow aerosol spray. Color Clear to pale yellow.Odor No data available. Aerosol Type Spray Odor Threshold No data available General Properties Boiling Point No data available Melting Point/Freezing Point No data available Decomposition Temperature No data available Heat of Decomposition No data available pH Not relevant Specific Gravity/Relative Density = 0.83 Water=1 Water Solubility Insoluble Viscosity No data available Volatility Vapor Pressure No data available Vapor Density No data available Evaporation Rate No data available VOC (Wt.) 20 % Flammability Flash Point Not relevant UEL No data available LEL No data available Heat of Combustion (ΔHc) 9.94 kJ/g Flammability (solid, gas) Flammable aerosol. Environmental Octanol/Water Partition coefficient No data available Section 10: Stability and Reactivity Reactivity •Non-reactive under normal handling and storage conditions. Chemical stability •Stable under normal temperatures and pressures. Possibility of hazardous reactions •Flammable, aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. Conditions to avoid •Heat, sparks, open flame. Excess heat. Gentrol AerosolGentrol AerosolGentrol AerosolGentrol Aerosol Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016 Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 5 of 9Page 5 of 9Page 5 of 9Page 5 of 9 Incompatible materials •Heat, strong acids, strong bases and oxidizing agents. Hazardous decomposition products •Thermal decomposition may produce toxic vapors and/or gases. Section 11 - Toxicological Information Information on toxicological effects Components (s)-Hydroprene (0.36%) 65733-18- 8 Acute Toxicity:Ingestion/Oral-Rat LD50 • >34600 mg/kg; Inhalation-Rat LC50 • >5.5 mg/L 4 Hour(s); Skin- Rabbit LD50 • >5000 mg/kg; Irritation:Eye-Rabbit • Essentially non-irritating; Skin-Rabbit • Essentially non-irritating GHS Properties Classification Acute toxicity OSHA HCS 2012 •Acute Toxicity - Dermal - Classification criteria not met; Acute Toxicity - Inhalation - Classification criteria not met; Acute Toxicity - Oral - Classification criteria not met Skin corrosion/Irritation OSHA HCS 2012 •Classification criteria not met Serious eye damage/Irritation OSHA HCS 2012 •Classification criteria not met Skin sensitization OSHA HCS 2012 •Classification criteria not met Respiratory sensitization OSHA HCS 2012 •Classification criteria not met Aspiration Hazard OSHA HCS 2012 •Aspiration 1 Carcinogenicity OSHA HCS 2012 •Classification criteria not met Germ Cell Mutagenicity OSHA HCS 2012 •Classification criteria not met Toxicity for Reproduction OSHA HCS 2012 •Classification criteria not met STOT-SE OSHA HCS 2012 •Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects STOT-RE OSHA HCS 2012 •Classification criteria not met Potential Health Effects Inhalation Acute (Immediate)•May affect the central nervous system. Symptoms may include dizziness or drowsiness. Chronic (Delayed)•No data available Skin Acute (Immediate)•May cause mild irritation. Chronic (Delayed)•No data available. Eye Acute (Immediate)•Under normal conditions of use, no health effects are expected. Chronic (Delayed)•No data available Ingestion Acute (Immediate)•Aspiration Hazard - may be fatal if swallowed and enters airways. Chronic (Delayed)•No data available Gentrol AerosolGentrol AerosolGentrol AerosolGentrol Aerosol Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016 Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 6 of 9Page 6 of 9Page 6 of 9Page 6 of 9 Mutagenic Effects •(s)-Hydroprene is not a mutagen. Carcinogenic Effects •(s)-Hydroprene is not a carcinogen. No other components present at 0.1% or greater is listed by IARC, OSHA or NTP. Reproductive Effects •Hydroprene does not produce developmental or reproductive effects. Section 12 - Ecological Information Toxicity Components (s)-Hydroprene (0.36%)65733-18-8 Aquatic Toxicity-Fish:96 Hour(s) NOEC Rainbow trout >0.43 mg/L [Acute] Persistence and degradability •No data available Bioaccumulative potential •No data available Mobility in Soil •No data available Other adverse effects Potential Environmental Effects •No data available. Section 13 - Disposal Considerations Waste treatment methods Product waste •Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste •Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Do not puncture or incinerate. Nonrefillable container. Do not reuse or refill container. See product label for container disposal instructions. Section 14 - Transport Information UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards DOT UN1950 Aerosols 2.1 None Not Applicable IMO/IMDG UN1950 Aerosols 2.1 None Not Applicable IATA/ICAO UN1950 Aerosols, flammable 2.1 None Not Applicable Special precautions for user •None specified. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code •No data available Other information IMO/IMDG •No data available Gentrol AerosolGentrol AerosolGentrol AerosolGentrol Aerosol Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016 Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 7 of 9Page 7 of 9Page 7 of 9Page 7 of 9 IATA/ICAO •No data available Section 15 - Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications •Acute FIFRA – Pesticide Labeling This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non- pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION Precautionary Statements •KEEP OUT OF THE REACH OF CHILDREN. Hazards to Humans and Domestic Animals •Harmful if inhaled or absorbed through skin. Avoid breathing spray mist. Causes moderate eye irritation. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash clothing before reuse. First Aid •IF ON SKIN OR CLOTHING • Take off contaminated clothing• Rinse skin immediately with plenty of water for 15-20 minutes.• Call a poison control center or doctor for further treatment advice. IF IN EYES Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth to mouth if possible. Physical or Chemical Hazards •Contents under pressure. Do not use or store near heat or open flame. Do not puncture or incinerate. Exposure to temperatures above 130° F may cause bursting. Do not use this product in or on electrical equipment due to the possibility of shock hazard. Inventory Component CAS TSCA Butane 106-97-8 Yes Distillates (petroleum), hydrotreated light 64742-47-8 Yes Propane 74-98-6 Yes (s)-Hydroprene 65733-18-8 No Section 16 - Other Information Revision statement: formulation change. Gentrol AerosolGentrol AerosolGentrol AerosolGentrol Aerosol Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016 Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 8 of 9Page 8 of 9Page 8 of 9Page 8 of 9 Revision Date •20/July/2016 Last Revision Date •12/February/2016 Preparation Date •12/February/2016 Disclaimer/Statement of Liability •The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Gentrol AerosolGentrol AerosolGentrol AerosolGentrol Aerosol Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016Preparation Date: 12/February/2016 Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016Revision Date: 20/July/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 9 of 9Page 9 of 9Page 9 of 9Page 9 of 9 Zoecon Gentrol IGR Concentrate Safety Data Sheet Date of issue: 09/07/2015 Revision date: 05/24/2019 Supersedes: 05/15/2019 Version: 1.3 05/24/2019 EN (English US)Page 1 SECTION 1: Identification 1.1.Identification Product form :Mixture Trade name :Zoecon Gentrol IGR Concentrate Synonyms :37860A, 37880A, 100540535, EPA Reg. No.: 2724-351, Zoecon RF-259 Emulsifiable Concentrate 1.2.Recommended use and restrictions on use Recommended use :Insect growth regulator. Restrictions on use :Avoid contact with eyes, skin or clothing. Keep out of reach of children. Avoid inhalation of vapors or fumes. Do NOT take internally. 1.3.Supplier Wellmark International 1501 E. Woodfield Road, Suite 200W Schaumburg, IL 60173 - United States www.zoecon.com 1.4.Emergency telephone number 1-800-248-7763Emergency number : 1-800-424-9300 - CHEMTREC 1-703-527-3887 - CHEMTREC - Outside North America - Collect Calls Accepted SECTION 2: Hazard(s) identification 2.1.Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 2 Causes skin irritation Serious eye damage/eye irritation Category 2B Causes eye irritation Specific target organ toxicity (single exposure) Category 3 May cause drowsiness or dizziness Aspiration hazard Category 1 May be fatal if swallowed and enters airways 2.2.GHS Label elements, including precautionary statements GHS US labeling Hazard pictograms (GHS US): GHS07 GHS08 Signal word (GHS US):Danger Hazard statements (GHS US):May be fatal if swallowed and enters airways Causes skin irritation Causes eye irritation May cause drowsiness or dizziness Precautionary statements (GHS US):Avoid breathing dust/fume/gas/mist/vapors/spray. Wash hands, forearms and face thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: Immediately call a poison center or doctor. If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center or doctor if you feel unwell. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Zoecon Gentrol IGR Concentrate Safety Data Sheet 05/24/2019 EN (English US)2/6 Dispose of contents/container to in accordance with local/regional/national/international regulations. 2.3.Other hazards which do not result in classification Other hazards not contributing to the classification :Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. 2.4.Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1.Substances Not applicable 3.2.Mixtures Name Product identifier % (S)-Hydroprene (CAS-No.) 65733-18-8 9 Distillates (petroleum), hydrotreated light (CAS-No.) 64742-47-8 59.12 Alkyl (C10-16 benzenesulfonic acid, calcium salt (CAS-No.) 68584-23-6 5.6 - 6.5 Trade secret (CAS-No.) Trade secret 2.17 Other ingredients (CAS-No.) N/A Balance SECTION 4: First-aid measures 4.1.Description of first aid measures First-aid measures after inhalation :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact :IF ON SKIN: Wash with plenty of soap and water. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice and attention. First-aid measures after ingestion :IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Call a physician immediately. Rinse mouth. Do NOT induce vomiting unless directed to do so by medical personnel. 4.2.Most important symptoms and effects (acute and delayed) Symptoms/effects :May cause drowsiness or dizziness. Symptoms/effects after skin contact :Causes skin irritation. Symptoms/effects after eye contact :Causes mild eye irritation. Symptoms/effects after ingestion :Risk of lung edema. 4.3.Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1.Suitable (and unsuitable) extinguishing media Suitable extinguishing media :Water spray. Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media :Avoid heavy hose streams. 5.2.Specific hazards arising from the chemical Reactivity :The product is non-reactive under normal conditions of use, storage and transport. 5.3.Special protective equipment and precautions for fire-fighters Protection during firefighting :Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1.Personal precautions, protective equipment and emergency procedures 6.1.1.For non-emergency personnel Emergency procedures :Ventilate spillage area. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes. Avoid release to the environment. Zoecon Gentrol IGR Concentrate Safety Data Sheet 05/24/2019 EN (English US)3/6 6.1.2.For emergency responders Protective equipment :Do not attempt to take action without suitable protective equipment. For further information refer to section 8: Exposure controls/personal protection. 6.2.Environmental precautions Avoid release to the environment. 6.3.Methods and material for containment and cleaning up Methods for cleaning up :Absorb spills with an inert material, clay granules or other inert absorbent material and put in container for disposal. Use appropriate PPE. SECTION 7: Handling and storage 7.1.Precautions for safe handling Precautions for safe handling :Do not handle until all safety precautions have been read and understood. Wear personal protective equipment. Use only outdoors or in a well-ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes. Do not use this product in or on electrical portions of equipment due to the possibility of shock hazard. Hygiene measures :Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2.Conditions for safe storage, including any incompatibilities Storage conditions :Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Keep from freezing. SECTION 8: Exposure controls/personal protection 8.1.Control parameters Distillates (petroleum), hydrotreated light (64742-47-8) ACGIH ACGIH TWA (mg/m³)Absorbed through skin. 200 mg/m³, (as total hydrocarbon vapor) 8 hours. 8.2.Appropriate engineering controls Appropriate engineering controls :Adequate ventilation systems as needed to control concentrations of airborne contaminants below applicable threshold limit values. Environmental exposure controls :Avoid release to the environment. 8.3.Individual protection measures/Personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear long-sleeved shirt and long pants, and shoes plus socks. Respiratory protection: In case of insufficient ventilation, use NIOSH approved respiratory protection. SECTION 9: Physical and chemical properties 9.1.Information on basic physical and chemical properties Physical state :Liquid Appearance :Straw-colored liquid Color :Straw-colored Zoecon Gentrol IGR Concentrate Safety Data Sheet 05/24/2019 EN (English US)4/6 Odor :Weak, neutral, paint-like Odor threshold :No data available pH :7.29 Melting point :Not applicable Freezing point :No data available Boiling point :No data available Flash point :200 °F Relative evaporation rate (butyl acetate=1):No data available Flammability (solid, gas):Not applicable Vapor pressure :No data available Relative vapor density at 20 °C :No data available Relative density :0.87 g/cc (7.3 lb/gal) Solubility :No data available Log Pow :No data available Auto-ignition temperature :No data available Decomposition temperature :No data available Viscosity, kinematic :No data available Viscosity, dynamic :< 50 cP Explosion limits :No data available Explosive properties :Not explosive Oxidizing properties :Not applicable 9.2.Other information No additional information available SECTION 10: Stability and reactivity 10.1.Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2.Chemical stability Stable under normal conditions. 10.3.Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4.Conditions to avoid Excessive heat > 110° F. Keep away from fire. Do not use this product in or on electrical portions of equipment due to the possibility of shock hazard. 10.5.Incompatible materials Strong oxidizing agents. 10.6.Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1.Information on toxicological effects Zoecon Gentrol IGR Concentrate LD50 oral rat > 5100 mg/kg LD50 dermal rabbit > 2100 mg/kg LC50 inhalation rat (mg/l)> 7.2 mg/l/4h GHS-US Properties Classification Acute toxicity (oral)Not classified Acute toxicity (dermal)Not classified Acute toxicity (inhalation)Not classified Skin corrosion/irritation Causes skin irritation. Serious eye damage/irritation Causes eye irritation. Respiratory or skin sensitization Not classified Zoecon Gentrol IGR Concentrate Safety Data Sheet 05/24/2019 EN (English US)5/6 Germ cells mutagen Not classified Carcinogenicity Not classified Reproductive toxicity Not classified Specific target organ toxicant (single exposure) May cause drowsiness or dizziness. Specific target organ toxicant (repeated exposure) Not classified Aspiration hazard May be fatal if swallowed and enters airways. Potential health effects Inhalation Acute :Causes drowsiness and dizziness. Skin Acute :Causes skin irritation. Eye Acute :May cause mild eye irritation. Ingestion Acute :Aspiration hazard - small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Mutagenicity :(s)-Hydroprene is not a mutagen. Carcinogenicity :(s)-Hydroprene did not cause cancer in laboratory animal studies. Reproductive Effects :(s)-Hydroprene did not produce developmental or reproductive effects in laboratory animal studies. SECTION 12: Ecological information 12.1.Toxicity (S)-Hydroprene (65733-18-8) NOEC (acute)> 0.43 mg/l (Exposure time: 96h - Rainbow trout) 12.2.Persistence and degradability No additional information available 12.3.Bioaccumulative potential No additional information available 12.4.Mobility in soil No additional information available 12.5.Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1.Disposal methods Product/Packaging disposal recommendations :Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. SECTION 14: Transport information UN number Proper Shipping Name Transport hazard class(es) Packing group Environmental hazards DOT Not regulated Not regulated Not regulated Not regulated Not applicable IMDG Not regulated Not regulated Not regulated Not regulated Not applicable IATA Not regulated Not regulated Not regulated Not regulated Not applicable Zoecon Gentrol IGR Concentrate Safety Data Sheet 05/24/2019 EN (English US)6/6 SECTION 15: Regulatory information 15.1. US Federal regulations Distillates (petroleum), hydrotreated light (64742-47-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Alkyl (C10-16 benzenesulfonic acid, calcium salt (68584-23-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Trade secret (Trade secret) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the Chemical Data Reporting Rule, (40 CFR 711). 15.2. US State regulations No additional information available SECTION 16: Other information Date of issue :07 September 2015 Revision date :24 May 2019 Supersedes :15 May 2019 Indication of changes: Revised Sec. 1 - added material number(s). SDS US (GHS HazCom 2012) - CGP The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. FIFRA Labelling EPA Registration Number 2724-351 This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. FIFRA Signal word Caution FIFRA Precautionary Statement KEEP OUT OF REACH OF CHILDREN. FIFRA Hazards to Humans and Domestic Animals Harmful if swallowed or absorbed through skin. Causes moderate eye irritation. Avoid contact with eyes, skin, or clothing. Wash thoroughly with soap and water after handling. FIFRA First Aid Call a poison control center or doctor immediately for treatment advice. If swallowed: Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give any liquid to the person. Do not give anything by mouth to an unconscious person. If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes. Then continue rinsing eye. If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth, if possible. Note to Physician: Contains petroleum distillates. Vomiting may cause aspiration pneumonia. FIFRA Physical Hazard Do not use this product in or on electrical portions of equipment due to the possibility of shock hazard Safety Data Sheet Section 1: Identification Product identifier Product Name •Gentrol Point Source Roach Control Device Synonyms •37890A; EPA Reg. No.: 2724-469; Zoecon (s)-Hydroprene Roach Control Station II Product Description •Straw-colored liquid in a clear ampoule. Relevant identified uses of the substance or mixture and uses advised against Recommended use •Insecticide. Restrictions on use •KEEP OUT OF THE REACH OF CHILDREN. Avoid contact with eyes, skin and clothing. Do not use or store near heat or open flame. Details of the supplier of the safety data sheet Manufacturer •Wellmark International 1501 E. Woodfield Road, Suite 200W Schaumburg, IL 60173 United States Emergency telephone number Manufacturer •1-800-248-7763 Manufacturer (Transportation)•1-800-424-9300 - CHEMTREC Manufacturer (Transportation)•1-703-527-3887 - CHEMTREC - Outside North America - Collect Calls Accepted Section 2: Hazard Identification United States (US) According to: OSHA 29 CFR 1910.1200 HCS Classification of the substance or mixture OSHA HCS 2012 •Flammable Liquids 4 Eye Mild Irritation 2B Skin Sensitization 1B Label elements OSHA HCS 2012 WARNING Hazard statements •May cause an allergic skin reaction Gentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control Device Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015 Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 1 of 9Page 1 of 9Page 1 of 9Page 1 of 9 Combustible liquid Causes eye irritation Precautionary statements Prevention •Wash thoroughly after handling. Avoid breathing dust, fume, gas, mist, vapors and/or spray. Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Response •IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media for extinction. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage/Disposal •Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Store in a well-ventilated place. Keep cool. Other hazards OSHA HCS 2012 •Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Section 3 - Composition/Information on Ingredients Substances •Material does not meet the criteria of a substance. Mixtures Composition Chemical Name Identifiers % (S)-Hydroprene CAS:65733-18-8 90.6% Butylated hydroxytoluene CAS:128-37-0 9.4% Section 4: First-Aid Measures Description of first aid measures Inhalation •IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or doctor for further treatment advice. Skin •IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Eye •IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical Gentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control Device Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015 Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 2 of 9Page 2 of 9Page 2 of 9Page 2 of 9 advice/attention. Ingestion •IF SWALLOWED: Do not induce vomiting unless told to by a poison control center or doctor. Get medical attention if symptoms occur. Most important symptoms and effects, both acute and delayed •Causes eye irritation. May cause an allergic skin reaction. Refer to Section 11 - Toxicological Information. Indication of any immediate medical attention and special treatment needed Notes to Physician •Treat symptomatically and supportively. Section 5: Fire-Fighting Measures Extinguishing media Suitable Extinguishing Media •LARGE FIRE: Water spray, fog or regular foam. SMALL FIRES: Dry chemical, CO2, water spray or regular foam. Unsuitable Extinguishing Media •Avoid heavy hose streams. Firefighting Procedures •LARGE FIRES: Move containers from fire area if you can do it without risk. Stay upwind. Ventilate closed spaces before entering. Do not breathe gas/fumes/vapor/spray. Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards •Combustible liquid. Hazardous Combustion Products •No data available. Advice for firefighters •Wear positive pressure self-contained breathing apparatus (SCBA). Section 6 - Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions •Do not walk through spilled material. Ventilate enclosed areas. Wear appropriate personal protective equipment, avoid direct contact. Emergency Procedures •ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Ventilate closed spaces before entering. Environmental precautions •LARGE SPILLS: Prevent entry into waterways, sewers, basements or confined areas. Methods and material for containment and cleaning up Containment/Clean-up Measures •Absorb spills with an inert material, clay granules or other inert absorbent material and put in container for disposal. Gentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control Device Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015 Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 3 of 9Page 3 of 9Page 3 of 9Page 3 of 9 Section 7 - Handling and Storage Precautions for safe handling Handling •Keep away from fire - No Smoking. Avoid breathing fumes. Use only in well ventilated areas. Wear appropriate personal protective equipment, avoid direct contact. Conditions for safe storage, including any incompatibilities Storage •Store in a cool/low-temperature, well-ventilated dry place away from heat and ignition sources. Incompatible Materials or Ignition Sources •Heat, sparks, open flame. Other Information •See product label for additional information. Section 8 - Exposure Controls/Personal Protection Control parameters Exposure Limits/Guidelines •No data available. Exposure Limits/Guidelines Result ACGIH NIOSH Butylated hydroxytoluene (128-37-0) TWAs 2 mg/m3 TWA (inhalable fraction and vapor)10 mg/m3 TWA Exposure Limits Supplemental ACGIH •Butylated hydroxytoluene (128-37-0): TLV Basis - Critical Effects: (upper respiratory tract irritation) Exposure controls Engineering Measures/Controls •Use adequate ventilation to remove vapors (fumes, dust, etc.) Personal Protective Equipment Pictograms • Respiratory •In case of insufficient ventilation, wear suitable NIOSH approved respiratory protection. Eye/Face •Wear chemical splash safety goggles. Hands •Wear appropriate gloves. Skin/Body •If prolonged exposure is anticipated, it is recommended for handlers to wear appropriate clothing to prevent skin contact. Environmental Exposure Controls •Refer to Section 13 - Disposal Considerations. Section 9 - Physical and Chemical Properties Information on Physical and Chemical Properties Gentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control Device Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015 Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 4 of 9Page 4 of 9Page 4 of 9Page 4 of 9 Material Description Physical Form Liquid Appearance/Description Straw-colored liquid in a clear ampoule. Color Straw colored.Odor Faint fruity. Odor Threshold No data available General Properties Boiling Point No data available Melting Point/Freezing Point No data available Decomposition Temperature No data available pH No data available Specific Gravity/Relative Density = 0.89 Water=1 Water Solubility Insoluble Water Solubility is 0.54 PPM Viscosity No data available Critical Temperature No data available Volatility Vapor Pressure < 1 mmHg (torr) @ 77 °F(25 °C)Vapor Density No data available Evaporation Rate < 1 n-Butyl Acetate = 1 Flammability Flash Point 182ºF (84ºC)UEL No data available LEL No data available Autoignition No data available Flammability (solid, gas) No data available Environmental Octanol/Water Partition coefficient No data available Section 10: Stability and Reactivity Reactivity •Non-reactive Chemical stability •Stable Possibility of hazardous reactions •Hazardous polymerization will not occur. Conditions to avoid •Heat, sparks, open flame, other ignition sources, and oxidizing conditions. Incompatible materials •Store away from oxidizers. Hazardous decomposition products •No data available. Section 11 - Toxicological Information Information on toxicological effects CAS Gentrol Point Source Roach Control Device NDA Irritation:Eye-Rabbit • Mild irritation; Skin-Rabbit • Mild irritation Components (S)-Hydroprene (90.6%)65733-18-8 Acute Toxicity:Ingestion/Oral-Rat LD50 • >34600 mg/kg; Inhalation-Rat LC50 • >5.5 mg/L 4 Hour (s); Skin-Rabbit LD50 • >5000 mg/kg Gentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control Device Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015 Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 5 of 9Page 5 of 9Page 5 of 9Page 5 of 9 GHS Properties Classification Acute toxicity OSHA HCS 2012 •Acute Toxicity - Dermal - Classification criteria not met; Acute Toxicity - Inhalation - Classification criteria not met; Acute Toxicity - Oral - Classification criteria not met Skin corrosion/Irritation OSHA HCS 2012 •Classification criteria not met Serious eye damage/Irritation OSHA HCS 2012 •Eye Mild Irritation 2B Skin sensitization OSHA HCS 2012 •Skin Sensitizer 1B Respiratory sensitization OSHA HCS 2012 •Classification criteria not met Aspiration Hazard OSHA HCS 2012 •Classification criteria not met Carcinogenicity OSHA HCS 2012 •Classification criteria not met Germ Cell Mutagenicity OSHA HCS 2012 •Not classified - data lacking Toxicity for Reproduction OSHA HCS 2012 •Classification criteria not met STOT-SE OSHA HCS 2012 •Classification criteria not met STOT-RE OSHA HCS 2012 •Classification criteria not met Potential Health Effects Inhalation Acute (Immediate)•Under normal conditions of use, no health effects are expected. Chronic (Delayed)•No data available Skin Acute (Immediate)•May cause an allergic skin reaction. Chronic (Delayed)•No data available Eye Acute (Immediate)•Causes eye irritation. Chronic (Delayed)•No data available Ingestion Acute (Immediate)•Under normal conditions of use, no health effects are expected. Chronic (Delayed)•CHRONIC TOXICITY/CARCINOGENICITY (S)-Hydroprene: A chronic toxicity/carcinogenicity study in rats identified ovaries and the thyroid as target organs. An increased incidence of benign thyroid tumors was present in male rats only at the highest dose tested. Increased weights and macroscopic and microscopic changes in the ovaries were observed at the highest doses. NOEL for males was 1,000 ppm and for females 100 ppm. SUBCHRONIC TOXICITY (S)-Hydroprene: In a 90 -day subchronic feeding study in rats, the NOEL was 50 mg/kg/day. Changes in body weight and organ weights were observed at higher dose levels. Liver and ovaries were identifed as target organs. No immunotoxic effects were observed in a study in mice when (S)-Hydroprene was fed (diet) at dose levels up to and including 1,200 mg/kg/day, continuously for 30 days. Mutagenic Effects •MUTAGENICITY: (S)-Hydroprene has been found negative for mutagenicity potential. It has tested negative in: 1) Ames Test, 2) in vivo cytogenetic assay, 3) micronucleus test (in vivo) and in 4) test for DNA effects- UDS in rats (in vitro). Carcinogenic Effects •(S)-Hyrdoprene: A chronic toxicity/carcinogenicity study in rats identified ovaries and the thyroid as target organs. An increased incidence of benign thyroid tumors was present in male rats only at the highest dose tested. Increased weights and Gentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control Device Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015 Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 6 of 9Page 6 of 9Page 6 of 9Page 6 of 9 macroscopic and microscopic changes in the ovaries were observed at the highest doses. NOEL for males was 1,000 ppm and for females 100 ppm. Reproductive Effects •DEVELOPMENTAL AND REPRODUCTIVE TOXICITY(S)-Hydroprene: Parental reproductive performance in rats remained unaffected up to a dose level of 7,500 ppm, when evaluated in a 2- generation reproduction/toxicity study. Histologically, all females of 7,500 ppm dose group had cytoplasmic vacuolation in the ovaries, but without affecting reproductive performance. The NOEL for pup development was 1,500 ppm.No teratogenic or fetotoxic effects were observed in rats when pregnant animals were exposed (gavage) to (S) Hydroprene at levels up to 1,000 mg/kg/day (highest dose tested). NOEL for maternal toxicity was 1,000 mg/kg/day. Section 12 - Ecological Information Toxicity Components (S)-Hydroprene (90.6%)65733-18-8 Aquatic Toxicity-Fish:96 Hour(s) NOEC Rainbow trout >0.43 mg/L [Acute] Persistence and degradability •No data available. Bioaccumulative potential •No data available. Mobility in Soil •No data available. Other adverse effects Potential Environmental Effects •No data available. Section 13 - Disposal Considerations Waste treatment methods Product waste •Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste •Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. See product label for disposal instructions. Section 14 - Transport Information UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards DOT Not Applicable Not regulated in non-bulk packaging Not Applicable Not Applicable Not Applicable NA1993 Bulk packaging: Combustible liquid, n.o.s.3 III Not Applicable IMO/IMDG Not Applicable Not Regulated Not Applicable Not Applicable Not Applicable Gentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control Device Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015 Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 7 of 9Page 7 of 9Page 7 of 9Page 7 of 9 IATA/ICAO Not Applicable Not Regulated Not Applicable Not Applicable Not Applicable Special precautions for user •None specified. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code •No data available Other information IMO/IMDG •No data available IATA/ICAO •No data available Section 15 - Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications •Acute FIFRA – Pesticide Labeling This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non- pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION Precautionary Statements •KEEP OUT OF THE REACH OF CHILDREN. Hazards to Humans and Domestic Animals •HAZARDS TO HUMANS AND DOMESTIC ANIMALS -CAUTION: Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. First Aid •IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Inventory Component CAS TSCA Butylated hydroxytoluene 128-37-0 Yes (S)-Hydroprene 65733-18-8 No Section 16 - Other Information Revision Summary Revision Date MSDS Number Changes 06/April/2016 •Section 3 changed. Revised composition. Gentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control Device Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015 Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 8 of 9Page 8 of 9Page 8 of 9Page 8 of 9 Revision Date •06/April/2016 Last Revision Date •20/July/2015 Preparation Date •20/July/2015 Disclaimer/Statement of Liability •The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Gentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control DeviceGentrol Point Source Roach Control Device Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015Preparation Date: 20/July/2015 Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016Revision Date: 06/April/2016 Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US)Format: GHS Language: English (US) OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012OSHA HCS 2012Page 9 of 9Page 9 of 9Page 9 of 9Page 9 of 9 SAFETY DATA SHEET MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT 1/10 Version 2.1 / USA Revision Date: 02/09/2018 102000021972 Print Date: 08/17/2018 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT Product code (UVP) 79695888 SDS Number 102000021972 EPA Registration No. 432-1255 Relevant identified uses of the substance or mixture and uses advised again st Use Insecticide Restrictions on use See product label for restrictions. Information on supplier Supplier Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 USA Responsible Department Email: SDSINFO.BCS-NA@bayer.com Emergency telephone no. Emergency Telephone Number (24hr/ 7 days) 1-800-334-7577 Product Information Telephone Number 1-800-331-2867 SECTION 2: HAZARDS IDENTIFICATION Classification in accordance with regulation HCS 29CFR §1910.1200 Specific target organ toxicity - repeated exposure: Category 1 Reproductive toxicity: Category 1B Labelling in accordance with regulation HCS 29CFR §1910.1200 Signal word: Danger Hazard statements May damage fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. SAFETY DATA SHEET MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT 2/10 Version 2.1 / USA Revision Date: 02/09/2018 102000021972 Print Date: 08/17/2018 Precautionary statements Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Wear protective gloves/ protective clothing/ eye protection/ face protection. Do not breathe dust. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF exposed or concerned: Get medical advice/ attention. Store locked up. Dispose of contents/container in accordance with local regulation. Hazards Not Otherwise Classified (HNOC) No physical hazards not otherwise classified. No health hazards not otherwise classified. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name CAS-No. Concentration % by weight Hydramethylnon 67485-29-4 1.0 SECTION 4: FIRST AID MEASURES Description of first aid measures General advice When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. Inhalation Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Skin contact Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately. Eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Most important symptoms and effects, both acute and delayed SAFETY DATA SHEET MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT 3/10 Version 2.1 / USA Revision Date: 02/09/2018 102000021972 Print Date: 08/17/2018 Symptoms To date no symptoms are known. Indication of any immediate medical attention and special treatment needed Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote. SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable None known. Special hazards arising from the substance or mixture Dangerous gases are evolved in the event of a fire. Advice for firefighters Special protective equipment for firefighters Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing. Further information Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. Flash point Not applicable Auto-ignition temperature No data available Lower explosion limit Not applicable Upper explosion limit Not applicable Explosivity No data available SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Methods and materials for containment and cleaning up Methods for cleaning up Avoid dust formation. Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations. SAFETY DATA SHEET MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT 4/10 Version 2.1 / USA Revision Date: 02/09/2018 102000021972 Print Date: 08/17/2018 Additional advice Use personal protective equipment. If the product is accidentally spilled, do not allow to enter soil, waterways or waste water canal. Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid dust formation. Ensure adequate ventilation. Advice on protection against fire and explosion Dust may form explosive mixture in air. Keep away from heat and sources of ignition. Hygiene measures Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers Store in original container and out of the reach of children, preferably in a locked storage area. Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters No known occupational limit values. Exposure controls Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations. Hand protection Chemical resistant nitrile rubber gloves Eye protection Safety glasses with side-shields SAFETY DATA SHEET MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT 5/10 Version 2.1 / USA Revision Date: 02/09/2018 102000021972 Print Date: 08/17/2018 Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks. General protective measures Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance yellow-brown to brown Physical State granular Odor characteristic Odour Threshold No data available pH No data available Vapor Pressure No data available Vapor Density (Air = 1) No data available Bulk density 20 - 26 lb/ft³ Evaporation rate Not applicable Boiling Point Not applicable Melting / Freezing Point Not applicable Water solubility Not applicable Minimum Ignition Energy No data available Decomposition temperature No data available Partition coefficient: n- octanol/water Not applicable Viscosity Not applicable Flash point Not applicable Auto-ignition temperature No data available Lower explosion limit Not applicable Upper explosion limit Not applicable Explosivity No data available Other information Further safety related physical-chemical data are not known. SAFETY DATA SHEET MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT 6/10 Version 2.1 / USA Revision Date: 02/09/2018 102000021972 Print Date: 08/17/2018 SECTION 10: STABILITY AND REACTIVITY Reactivity Thermal decomposition No data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions No hazardous reactions when stored and handled according to prescribed instructions. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials No data available Hazardous decomposition products No decomposition products expected under normal conditions of use. SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Skin contact, Ingestion Immediate Effects Skin Harmful if absorbed through skin. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Information on toxicological effects Acute oral toxicity LD50 (Rat) > 5,000 mg/kg Acute inhalation toxicity No data available Acute dermal toxicity LD50 (Rabbit) > 2,000 mg/kg Skin irritation Slight irritant effect - does not require labelling. (Rabbit) Eye irritation No eye irritation (Rabbit) Sensitisation Non-sensitizing. (Guinea pig) Assessment STOT Specific target organ toxicity – repeated exposure Hydramethylnon caused specific target organ toxicity in experimental animal studies in the following organ(s): Testes, Kidney. Assessment mutagenicity Hydramethylnon was not mutagenic or genotoxic in a battery of in vitro and in vivo tests. Assessment carcinogenicity Hydramethylnon was not carcinogenic in lifetime feeding studies in rats and mice. ACGIH SAFETY DATA SHEET MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT 7/10 Version 2.1 / USA Revision Date: 02/09/2018 102000021972 Print Date: 08/17/2018 None. NTP None. IARC None. OSHA None. Assessment toxicity to reproduction Hydramethylnon caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. Hydramethylnon caused testicular damage and male infertility. Assessment developmental toxicity Hydramethylnon caused developmental toxicity only at dose levels toxic to the dams. Hydramethylnon caused a delayed foetal growth. Further information Acute toxicity studies have been bridged from a similar formulation(s). The non-acute information pertains to the active ingredient(s). SECTION 12: ECOLOGICAL INFORMATION Toxicity to fish LC50 (Ictalurus punctatus (Channel catfish)) 0.09 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient hydramethylnon. Toxicity to aquatic invertebrates NOEC (Daphnia magna (Water flea)) 0.000088 mg/l Exposure time: 21 Days The value mentioned relates to the active ingredient hydramethylnon. EC50 (Mysidopsis bahia (mysid shrimp)) 0.0544 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient hydramethylnon. Toxicity to aquatic plants EC50 (Scenedesmus quadricauda (Green algae)) 0.01112 mg/l Exposure time: 72 h The value mentioned relates to the active ingredient hydramethylnon. Biodegradability Hydramethylnon: Not rapidly biodegradable Koc Hydramethylnon: Koc: 730000 Bioaccumulation Hydramethylnon: Bioconcentration factor (BCF) 34,900 Does not bioaccumulate. SAFETY DATA SHEET MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT 8/10 Version 2.1 / USA Revision Date: 02/09/2018 102000021972 Print Date: 08/17/2018 Mobility in soil Hydramethylnon: Immobile in soil Environmental precautions Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Apply this product as specified on the label. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Product Pesticide, spray mixture or rinse water that cannot be used according to label instructions may be disposed of on site or at an approved waste disposal facility. Never place unused product down any indoor or outdoor drain. Contaminated packaging Do not re-use empty containers. Place empty container in trash. Follow advice on product label and/or leaflet. RCRA Information Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply. SECTION 14: TRANSPORT INFORMATION 49CFR Not dangerous goods / not hazardous material IMDG UN number 3077 Class 9 Packaging group III Marine pollutant YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (HYDRAMETHYLNON MIXTURE) IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark YES Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (HYDRAMETHYLNON MIXTURE ) This transportation information is not intended to convey all specific regulatory information relating to this SAFETY DATA SHEET MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT 9/10 Version 2.1 / USA Revision Date: 02/09/2018 102000021972 Print Date: 08/17/2018 product. It does not address regulatory variations due to package size or special transportation requirements. SECTION 15: REGULATORY INFORMATION EPA Registration No. 432-1255 US Federal Regulations TSCA list None. US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section 302 - Notification and Information None. SARA Title III - Section 313 - Toxic Chemical Release Reporting Hydramethylnon 67485-29-4 US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Hydramethylnon 67485-29-4 Developmental toxin. Hydramethylnon 67485-29-4 Male reproductive toxin. US State Right-To-Know Ingredients Hydramethylnon 67485-29-4 NJ Canadian Regulations Canadian Domestic Substance List None. Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: SAFETY DATA SHEET MAXFORCE® COMPLETE BRAND GRANULAR INSECT BAIT 10/10 Version 2.1 / USA Revision Date: 02/09/2018 102000021972 Print Date: 08/17/2018 Signal word: Caution! Hazard statements: Harmful if absorbed through skin. Avoid contact with skin, eyes and clothing. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. SECTION 16: OTHER INFORMATION Abbreviations and acronyms 49CFR Code of Federal Regulations, Title 49 ACGIH US. ACGIH Threshold Limit Values ATE Acute toxicity estimate CAS-Nr. Chemical Abstracts Service number CERCLA Comprehensive Environmental Response, Compensation, and Liability Act EINECS European inventory of existing commercial substances ELINCS European list of notified chemical substances IARC International Agency for Research on Cancer IATA International Air Transport Association IMDG International Maritime Dangerous Goods N.O.S. Not otherwise specified NTP US. National Toxicology Program (NTP) Report on Carcinogens OECD Organization for Economic Co-operation and Development TDG Transportation of Dangerous Goods TWA Time weighted average UN United Nations WHO World health organisation NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 1 Instability - 0 Others - none HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 1 Physical Hazard - 0 PPE - 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: The following sections have been revised: Section 9: Physical and Chemical Properties. Reviewed and updated for general editorial purposes. Revision Date: 02/09/2018 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer. Use it to NIBAN® ACTIVE ingredient: 5% ORTHOBORIC ACID application: target pests: Scatter granular bait around perimeter of structures and near heavy infestations or entry points. Inside, use Niban in wall voids and under cabinets & appliances. and CREATE A SUSTAINABLE TREATMENT PROGRAM. Ants, cockroaches, crickets, silverfish, slugs and snails all consume Niban bait. Non- target species, such as birds, mammals, amphibians and reptiles, don’t. The active ingredient in Niban disrupts the metabolic process in the target pests’ guts, giving you the control you need. This metabolic disruption is specific to insects and gastropods. On top of that, Niban has no known resistance to target pests. Niban helps create a sustainable treatment program – and that helps you build a sustainable business. Remember, always read, understand and comply with the label. Niban and Nisus Corporation are registered trademarks of Nisus Corporation. ©2017 Nisus Corporation #NI-FLY-0117 100 Nisus Drive • Rockford, TN 37853 800.264.0870 • www.nisuscorp.comcreating a world of sustainability.ants CRICKETS SILVERFISHcockroaches A Weather/Moisture Resistant Bait to Kill and Control Ants (except fire ants), Carpenter Ants, Cockroaches, Crickets, Mole Crickets, Earwigs, Silverfish, Snails and Slugs ACTIVE INGREDIENT: Orthoboric Acid ..................................................... 5.0% OTHER INGREDIENTS ........................................ 95.0% TOTAL .................................................................. 100.0% EPA Reg. No. 64405-2 EPA Est. 64405-TN-1 FOR BOTH INTERIOR AND EXTERIOR USE Above-ground Transformers, Aircraft, Apartments, Apartment Buildings, Boats, Buses, Campgrounds, Camps, Cemeteries, Factories, Federally Inspected (USDA) Meat and Poultry Plants, Flower Gardens, Food Handling - Establishments, Food Processing Plants, Garages, Greens of Golf Courses, Grocery Stores, Groundcovers, Homes, Home Lawns, Hospitals, Hotels, -Industrial Plants, In- ground Utility Boxes, lnteriorscapes, Kennels, Lath Houses, Lawns, Libraries, Markets, Military Bases, Mobile Homes, Motels, New Construction, Nursing Homes, Offices, - Ornamental Home Greenhouses, Ornamental Turf, Ornamentals, Other Structures, Parks, Pedestal Boxes, Pet Stores, Picnic Areas, Playing Fields, Public and Private Institutions, Recreational Turf, Recreational Vehicles, Restaurants, Restaurants (non-food areas), Schools, Sewers, Ships, Shrubs, Stores, Supermarkets, Theaters, Trains, Trucks, Utilities, Vending Machines, Warehouses, Yachts, Zoos PRECAUTIONARY STATEMENTS Hazards to Humans & Domestic Animals CAUTION: Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. PERSONAL PROTECTIVE EQUIPMENT (PPE) Applicators and handlers must wear: Long-sleeved shirt and long pants; water-proof gloves; and shoes plus socks. Follow manufacturer’s instructions for cleaning/ maintaining PPE. If no such instructions for washables are given, use detergent and hot water. USER SAFETY RECOMMENDATIONS Users should: • Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. • Remove clothing immediately if pesticide gets inside; then thoroughly wash and put on clean clothing. • Immediately remove PPE after handling this product. Wash the outside of gloves before removing. As soon as possible, thoroughly wash and change into clean clothing. ENVIRONMENTAL HAZARDS Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high-water mark. Do not contaminate water when disposing of equipment washwaters or rinsate. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. GENERAL INFORMATION This product is a ready-to-use, weather/moisture resistant bait that controls and kills Ants (except fire ants), Cockroaches, Crickets, Earwigs, Silverfish, Snails and Slugs, specifically: ANTS: Argentine, Carpenter, Thief, Pharaoh, Little Black, Pavement, Odorous House and Crazy Ants. COCKROACHES: Asian, American, Brown, Brownbanded, Smokeybrown, German and Oriental Cockroaches. CRICKETS: Camel, House, Field and Mole Crickets. SNAILS AND SLUGS. EUROPEAN EARWIGS. Do not contaminate this product with other pesticides. If this product becomes contaminated with another pesticide it will lose its effectiveness. Do not apply directly to food and avoid contamination of feed and foodstuff. In commercial food handling facilities, cover or remove any food during application. In food handling and other areas, bait may be placed in removable bait First Aid If in Eyes: • Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. • Call a poison control center or doctor for treatment advice. If on Skin: • Take off contaminated clothing. • Immediately rinse with plenty of water for 15 – 20 minutes. • Call a poison control center or doctor for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment.. stations. Always record the number and location of bait stations. This product is designed to be used as a residual treatment in an Integrated Pest Management program incorporating good sanitation practices. This product may be applied in appropriate areas with a power duster (except in California). Consult equipment manufacturer for recommended settings. Keep children and pets out of treatment area until application has been completed. Do not treat pets with this product. Avoid over-application around ornamental plants and fish ponds. Do not apply this product in combination with fertilizers, other pesticides or other biologically-active materials. APPLICATION INSTRUCTIONS To Control and Kill Ants (except fire ants), Cockroaches, Crickets, Mole Crickets, Snails and Slugs on Campgrounds, Cemeteries, Greens of Golf Courses, Home Lawns, Lawns, Ornamental Turf, Parks, Picnic Areas, Playing Fields and Recreational Turf: Apply bait evenly to affected areas at the rate of 2 pounds per 1,000 square feet (3.2 ounces or 2/3 cup per 100 square feet) or 90 pounds per acre. When treating for mole crickets: Thoroughly irrigate treatment areas in the late afternoon prior to application. For maximum effectiveness, do not irrigate treated area immediately after application. Exterior Baiting to Control and Kill Snails and Slugs in Flower Gardens and Around Ornamentals, Ground- covers and Shrubs: At the beginning of the spring planting season (before damage occurs), broadcast 6 ounces per 100 square feet in areas likely to be infested with snails and slugs. It is best to apply the bait during early morning or evening when slugs and snails are present and eating. Reapply every four weeks for satisfactory control. To Control and Kill Snails and Slugs in Ornamental Home Greenhouses and Lath Houses: Evenly distribute granules on and under benches at the rate of 6 ounces per 100 square feet. Do not place in flats or pots. To Control and Kill Snails and Slugs in Interiorscapes or Ornamental Gardens: Evenly apply bait to soil at a rate of 6 ounces per 100 square feet no more than once every 4 to 6 weeks. Exterior Baiting to Control and Kill Ants (except fire ants), Including Carpenter Ants, Around Apartment Buildings, Food Processing Plants, Garages, Homes, Hospitals, Hotels, Kennels, Motels, Pet Stores, Public & Private Institutions, Recreational Vehicles, Restaurants, Schools, Supermarkets, Warehouses and Other Structures: Treat exterior perimeter areas of structure in a band 2 to 4 feet wide at a rate of 6 ounces per 100 square feet. Also apply product in a 2 to 4 foot band around all trees, stumps, firewood piles and other locations where carpenter ants may nest. If the nest is located in a hollow tree or stump, apply 1/2 to 1 ounce of product directly into the cavity. Apply along ant trails and in areas where ant activity has been noted. To Control and Kill Ants (except fire ants), Cock- roaches, Crickets, Earwigs and Silverfish Within and Around the Exterior of Structures such as Apartment Buildings, Food Processing Plants (non-food areas), Garages, Homes, Hospitals, Hotels, Kennels, Motels, Pet Stores, Public & Private Institutions, Recrea- tional Vehicles, Restaurants (non-food areas), Schools, Sewers, Stores, Supermarkets and Ware- houses: Apply at a rate of 4 pounds per 1000 square feet (6 ounces or 1-1/4 cups per 100 square feet) of surface area. Spread evenly in crawl spaces, attics, drop ceilings and cellars with dirt or gravel floors. Concentrate application in areas where insect activity is most prevalent. In attics, be sure to apply in eaves and access drains. In warehouses, garages and basements, concentrate application along walls and baseboards. This product may also be applied in inaccessible areas such as cracks and crevices where insects may hide. Any bait visible after application must be brushed into cracks and crevices or removed. Apply in pits of elevator, dumbwaiter and trash chute shafts. Apply under and behind pallets and boxes in storerooms. Bait may also be placed in removable bait stations in areas accessible to insects but inaccessible to children and pets. Always record the location and number of bait stations. Regularly inspect bait stations and replace bait as needed. In sewers, apply along ledges and around manhole entrances. Treat exterior perimeter building walls in a band approximately 2 feet wide and scatter bait in flower beds, leaf litter, wood piles, trash cans and refuse areas. Reapply as necessary. For treating new construction: Apply in wall voids and other areas where insects may hide. For perimeter treatments: Spread bait at a rate of 6 ounces or 1-1/4 cups per 100 square feet in a band at least 2 feet wide around foundations, patios, driveways, sidewalks, entrances to homes and buildings, or other areas where insects are present. Apply around landscape lighting, floodlights, street lamps or other exterior fixtures and scatter bait in flower beds, leaf litter, wood piles, trash cans and refuse areas. Reapply as necessary. For treating ant mounds: Apply 1/2 to 1 ounce of this product around all ant mounds. Supplement by broadcast application in immediate area and along ant trails and in areas where ant activity has been noted. To Control and Kill Ants (except fire ants), Cockroaches, Crickets, Earwigs and Silverfish in: Aircraft, Apartment Buildings, Apartments, Boats, Buses, Camps, Factories, Food Handling Establish- ments, Food Processing Plants, Garages, Grocery Stores, Homes, Hospitals, Hotels, Industrial Plants, Kennels, Libraries, Markets, Military Bases, Mobile Homes, Motels, New Construction, Nursing Homes, Offices, Pet Stores, Private & Public Institutions, Recreational Vehicles, Restaurants, Schools, Sewers, Ships, Supermarkets, Theaters, Trains, Trucks, Utilities, Warehouses, Yachts and Zoos: Food area application limited to only crack and crevice treatment. Apply only in areas inaccessible to children and pets. Avoid contamination of feed and foodstuffs. Apply, scattering/dusting under and behind refrigerator, cooler, stove, sink, dishwasher, washing machine and dryer tubs; counters; into openings around drains, water pipes and electrical conduits; and in cracks and crevices along baseboards and corners of cabinets, counter tops, cupboards and closets. Remove all lower drawers in kitchen and bathroom cabinets, bedroom dressers and chests of drawers, then scatter/dust in drawer wells. Bait may also be applied into and around areas of insect infestation of above-ground transformers, in- ground utility boxes, pedestal boxes and vending machines. Any bait visible after application must be brushed into cracks and crevices or removed. Reapply as necessary. Bait may also be placed in bait stations in areas accessible to insects but inaccessible to children and pets. Always record the location and number of bait stations. Regularly inspect bait stations and replace bait as needed. Crack and Crevice Applications In Aircraft, Apartment Buildings, Apartments, Boats, Buses, Camps, Factories, Food Handling Establishments, Food Processing Plants, Garages, Grocery Stores, Homes, Hospitals, Hotels, Industrial Plants, Kennels, Libraries, Markets, Military Bases, Mobile Homes, Motels, New Construction, Nursing Homes, Offices, Pet Stores, Private & Public Institutions, Recreational Vehicles, Restaurants, Schools, Sewers, Ships, Supermarkets, Theaters, Trains, Trucks, Utilities, Warehouses, Yachts and Zoos: Crack and crevice applications may be made using most types of dust applicators. A bellows type duster works best. Insert stem into gaps, cracks and crevices and apply 2 to 6 puffs per lineal foot, depending upon the severity of the infestation. Any bait visible after application must be brushed into cracks and crevices or removed. Drill small holes to gain access into wall voids and under cabinets. This product may also be applied in appropriate areas with a power duster (except in California). Consult equipment manufacturer for recommended settings Application Sites and Directions: 1. Apply under and behind appliances in kitchens, bathrooms and utility rooms (remove kick plates if possible). 2. Kitchen and bathroom cabinets and vanities often have a space between the floor and the bottom drawer or cabinet. If a gap exists along the top of the kickplate, dust this product into the void area. If no gaps are present, drill a small hole every two feet along the kickplate drilling at least one hole under each cabinet and apply this product through the holes. 3. Apply in voids around plumbing pipes behind water heaters and under sinks in kitchens, bathrooms, showers and utility rooms. Pull back escutcheon plates around pipes to allow access to the void. 4. Remove electrical wall socket and switch covers and dust product around boxes and into voids. Do not apply product directly into electrical switch and outlet boxes. 5. Cracks or spaces between the wall and doorframes, cabinets, counter tops, molding or baseboards provide excellent hiding places for roaches and ants. Dust a small amount of this product into these areas wherever possible. 6. Apply under and behind vending machines. If access can be gained to the interior of the machine, apply around the interior base, being careful not to contaminate any foodstuffs. To Control and Kill Cockroaches, Crickets, Ants, Earwigs and Silverfish in Federally-inspected (USDA) meat and poultry plants: For application only in inedible product areas and non-processing areas as a crack and crevice treatment. Apply to cracks and crevices in areas such as around baseboards and in closets; beneath cabinets and appliances, in and around waste containers and into openings around drains, water pipes and electrical conduits. Any bait visible after application must be brushed into cracks and crevices or removed. Avoid contamination of feed and foodstuffs. Bait stations may be used. Always record the number and location of bait stations. Regularly inspect bait stations and replace bait as needed. This product is best used as a supplemental residual treatment preceded by approved spray and good sanitation practices. STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage or disposal. Pesticide Storage: Store in a dry place. Do not store where children or animals may gain access. Pesticide Disposal: Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Container Disposal: Non-refillable container; do not reuse or refill this container. Completely empty container into application equipment, then offer for recycling, if available; otherwise dispose of empty container in a sanitary landfill or by incineration. WARRANTY DISCLAIMER To the extent not prohibited by applicable law, Manufacturer warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes stated on the label when used in strict accordance with the directions, subject to the inherent risks set forth below. To the extent not prohibited by applicable law, MANUFACTURER MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. Inherent Risks of Use The directions for use are believed to be adequate and must be carefully followed. It is impossible to eliminate all risks associated with use of this product. Lack of performance or other unintended consequences may result because of such factors as use of the product contrary to label instructions, abnormal conditions, the presence of other materials, climatic conditions or the manner of application, all of which are beyond the control of the Manufacturer. To the extent not prohibited by applicable law, the buyer/user assumes all such risks. Limitation of Remedies To the extent not prohibited by applicable law the exclusive remedy for losses or damages resulting from this product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer’s election, one of the following: 1. Refund of purchase price paid by buyer or user for product bought, or 2. Replacement of amount of product used. To the extent not prohibited by applicable law: a) Manufacturer shall not be liable for losses or damages resulting from handling or use of this product unless Manufacturer is promptly notified of such loss or damage in writing; and b) TO THE EXTENT NOT PROHIBITED BY APPLICABLE LAW, IN NO CASE SHALL MANUFAC- TURER BE LIABLE FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Limitation of Remedies cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner. It is not intended that this product be used to practice any applicable patent, whether mentioned or not, without procurement of a license if necessary from the owner following investigation by the user. 100 Nisus Drive • Rockford, TN 37853 USA • 800-264-0870 Niban and Nisus Corporation are registered trademarks of Nisus Corporation. ©2016 Nisus Corporation # NB-SL-0216a-SAL020515 SAFETY DATA SHEET Health Emergencies: INFOTRAC® (800) 535-5053 1. PRODUCT AND COMPANY INFORMATION Product Identity: Niban® Granular Bait Recommended use of the chemical and restrictions on use: A weather/moisture resistant bait to kill and control ants (except fire ants), carpenter ants, cockroaches, crickets, mole crickets, earwigs, silverfish, snails, and slugs. Read and understand the entire label before using. Use only according to label directions. It is a violation of Federal law to use this product in a manner inconsistent to label directions. Manufacturer: Nisus Corporation 100 Nisus Drive Rockford, TN 37853 Telephone: Phone: (800) 264-0870 Fax: (865) 577-5825 Emergency Phone: 800-535-5053 (INFOTRAC) SDS Date of Preparation: 1/12/16 2. HAZARDS IDENTIFICATION GHS Classification: Physical Health Environment Not Hazardous Acute Toxicity Oral Category 4 Specific Target Organ Toxicity – Repeat Exposure Category 2 Aquatic Acute Toxicity Category 3 GHS Label Elements: TE None Required Statements of Hazard Precautionary Statements None Required None Required 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. Amount Boric Acid 10043-35-3 5% Non-Hazardous Ingredient Proprietary 95% The exact formulation is being withheld as a trade secret. 4. FIRST AID MEASURES Eye: Flush victim's eyes with large quantities of water, while holding the eyelids apart. Get medical attention if irritation develops or persists. Skin: Wash skin thoroughly with soap and water. Get medical attention if irritation develops. Remove and launder clothing before re-use. Ingestion: Do not induce vomiting unless directed to do so by a medical professional. Get medical attention for large ingestions or if symptoms develop or if you feel unwell. Inhalation: Remove victim to fresh air. If breathing is difficult or irritation persists, get medical attention. Most important Symptoms: May cause eye and skin irritation. Inhalation of mists may cause mild mucous membrane and respiratory irritation. Harmful if swallowed. Repeated ingestion may cause kidney damage. Indication of immediate medical attention/special treatment: Immediate medical attention is required for large ingestions. 5. FIRE FIGHTING MEASURES Suitable (and Unsuitable) Extinguishing Media: Use media appropriate for surrounding fire. Specific hazards arising from the chemical: Fine particles may present an explosion hazard if suspended in air. Burning may produce carbon monoxide and carbon dioxide. Special Protective Equipment and Precautions for Fire-Fighting Instructions: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing. Contain runoff. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures: Wear appropriate protective clothing as described in Section 8. Do not apply directly to water or contaminate water. Methods and Materials for Containment and Cleaning Up: Collect and place in appropriate containers for disposal. Avoid generating dust. Clean spill area thoroughly. Prevent spill from entering sewers and watercourses. Report releases as required by local, state and federal authorities. 7. HANDLING AND STORAGE Precautions for Safe Handling: Avoid contact with the eyes, skin and clothing. Avoid breathing dusts. Wear protective clothing and equipment as described in Section 8. Wash thoroughly with soap and water after handling. Remove contaminated clothing immediately and wash before reuse. Remove PPE immediately after handling. Wash thoroughly after using and change into clean clothing. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. Keep containers closed when not in use. Refer product label for additional information on use and handling. Nonrefillable container. Do not reuse containers. Product residues in empty containers can be hazardous. Follow all SDS precautions when handling empty containers. Conditions for Safe Storage, Including Any Incompatibilities: Store in a dry area away from incompatible materials. Do not store where children or animals may gain access. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines: Boric Acid 2 mg/m3 TWA ACGIH TLV (inhalable) 6 mg/m3 STEL ACGIH TLV (inhalable) Engineering Controls: Use with adequate ventilation to maintain exposure levels below the occupational exposure limits. Refer product label for additional information. Respiratory Protection: In operations where exposure levels are exceeded, a NIOSH approved respirator with dust/mist cartridges appropriate for the form and concentration of the contaminants should be used. Selection and use of respiratory equipment must be in accordance with OSHA 1910.134 and good industrial hygiene practice. Refer to the product label for additional information. Skin Protection: Use gloves for normal application of this product. Eye Protection: Wear safety glasses to prevent eye contact. Other: Wear long-sleeve shirts, long pants, socks and shoes when using this product. Suitable washing facilities should be available in the work area. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Brown, granular particles with no odor. Physical State: Granular particles Odor Threshold: Not established Vapor Density: Not determined Initial Boiling Point/Range: Not determined Solubility In Water: Not soluble Vapor Pressure: Negligible Relative Density: 0.62 of water Evaporation Rate: N/A Melting/Freezing Point: N/A pH: N/A Percent Volatile: Minimal Octanol/Water Coefficient: N/A Solubility: Not soluble Decomposition Temperature: N/A Viscosity: N/A Flammability (solid, gas): Fine dust may form explosive mixtures in air Flashpoint: >451°F (233°C) TOC Autoignition Temperature: None Flammable Limits: LEL: Not determined UEL: N/A 10. STABILITY AND REACTIVITY Reactivity: Not normally reactive Chemical Stability: Stable under normal storage and handling conditions. Possibility of Hazardous Reactions: None known. Conditions to Avoid: Avoid generating fine dust. Incompatible Materials: None known Hazardous Decomposition Products: When heated to decomposition emits carbon monoxide and carbon dioxide. 11. TOXICOLOGICAL INFORMATION HEALTH HAZARDS: Ingestion: May be harmful if large quantities are ingested. Inhalation: Inhalation of dust may cause irritation of the nose, throat and upper respiratory tract. Eye: May cause slight irritation. Skin: Not expected to cause irritation. Chronic: Borates have been shown to have some chronic toxicity in animals fed high doses, but this has not been found in humans. Sensitization: This material is not expected to cause sensitization. Carcinogenicity: None of the components is listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA. Germ Cell Mutagenicity: No data available Reproductive Toxicity: Borates have been found to have some reproductive toxicity in animals, but this has not been found in humans. Numerical Measures of Toxicity: Product Toxicity Data: Oral rat LD50: >5000 mg/kg; Dermal rabbit LC50: >5050 mg/kg 12. ECOLOGICAL INFORMATION This product breaks down naturally in the environment to provide organic matter and boron micro nutrients. Boron occurs naturally in sea water at an average concentration of 5 mg B/l and fresh water at 1 mg B/l or less. In dilute aqueous solutions the predominant boron species present is undissociated boric acid. Ecotoxicity: EC10 Green Algae: 24 mg B/l; LC50 Daphnia magna: 530 mg B/l/96 hr; LC50 Dab: 74 mg B/l/48hr; LC50 Rainbow Trout: 88 mg B/l/24hr; LC50 Goldfish: 71 mg B/l/72hr Persistence and Degradability: Boron is naturally occurring and ubiquitous in the environment. Niban decomposes in the environment to natural borate. Bioaccumulative Potential: Not determined. Mobility in Soil: Boric acid is soluble in water and is leachable through normal soil. Other Adverse Effects: Some plants are sensitive to boron. This product is designed to be used for certain types of insects. Use product only as directed on the label. See product label for full instructions and restrictions on use. 13. DISPOSAL CONSIDERATION Dispose in accordance with local, state and federal environmental regulations. Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high-water mark. Do not contaminate water when disposing of equipment washwaters or rinsate. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Non-refillable container: do not reuse or refill this container. Completely empty container into application equipment, then offer for recycling, if available; otherwise dispose of empty container in a sanitary landfill or by incineration. For guidance contact your state water board or regional office of the EPA. 14. TRANSPORTATION INFORMATION DOT Hazardous Materials Description: Not Regulated Sea Transport IMDG, not classified as dangerous Air Trasnport IATA/ICAO, not classified as dangerous 15. REGULATORY INFORMATION This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. FIFRA Labeling: Niban Granular Bait EPA Reg. No. 64405-2 Keep Out of Reach of Children CAUTION PRECAUTIONARY STATEMENTS Hazards to Humans & Domestic Animals Caution: Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. CERCLA: This product is not subject to reporting under CERCLA. Some states have more stringent reporting requirements. Report all spills in accordance with local, state, and federal regulations. SARA Hazard Category (311/312): Not hazardous SARA 313: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): None EPA TSCA Inventory: This product is regulated under FIFRA, thus exempt. 16. OTHER INFORMATION NFPA Rating: Health = 0 Flammability = 0 Instability = 0 HMIS Rating: Health = 1 Flammability = 0 Physical Hazard = 0 SDS Revision History: 01/07/14: New SDS 01/12/16: Revised WARRANTY DISCLAIMER The information, data and recommendations contained herein are believed to be accurate but may not be all inclusive and should only be used as a guide. The information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the product for his particular use and on condition that they assume the risk of the use thereof. With respect to this publication and the product related thereto, unless otherwise expressly provided by Manufacturer in writing, MANUFACTURER MAKES NO EXPRESS OR IMPLIED WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. Remedy/Liability Limits The exclusive remedy for losses or damages resulting from this publication or the related product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer’s sole election, one of the following: 1. Refund of purchase price paid by buyer or user for product bought, or 2. Replacement of amount of product used. Manufacturer shall not be liable for losses or damages resulting from use of this publication or handling or use of this product, IN NO CASE SHALL MANUFACTURER BE LIABLE FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Remedy/Liability Limits cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner. 100 Nisus Drive • Rockford, TN 37853 USA • (800) 264-0870 Niban and Nisus Corporation are registered trademarks of Nisus Corporation. ©2016• #NB-SDS-011216a 100 Nisus Drive • Rockford, TN 37853 800-264-0870 SAFETY DATA SHEET Issue Date:24-Jan-2019 Revision Date:24-Jan-2019 Version:2 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name:NyGuard® IGR Concentrate EPA Registration Number:1021-1603 Other means of identification Part Code:2482A Recommended use of the chemical and restrictions on use: Recommended Use:Insecticide. Details of the supplier of the safety data sheet Telephone Number: (800) 645-6466, or (763) 544-0341 e-Mail Address: mgk-sds@mgk.com Emergency telephone numbers: 24 Hour TRANSPORTATION Emergency:CHEMTREC®: (800) 424-9300 International:(703) 527-3887 24 Hour MEDICAL Emergency:SafetyCall®: (888) 740-8712, or (952) 852-9509 Comments:MGK® Hours of operation are 8:00 a.m. to 4:30 p.m. CST, 14:00 to 22:30 GMT. For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to (888) 740-8712, or (952) 852-9509. 2. HAZARDS IDENTIFICATION Classification: OSHA Regulatory Status: This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2B Label elements Emergency Overview Manufacturer Address: McLaughlin Gormley King Company 8810 10th Avenue North Minneapolis, MN 55427 FAX #: (763) 544-6437 WARNING Hazard statements ‡+&DXVHVVNLQLUULWDWLRQ ‡+&DXVHVH\HLUULWDWLRQ _____________________________________________________________________________________________ Page 1 / 9 _____________________________________________________________________________________________ NyGuard® IGR Concentrate Revision Date:24-Jan-2019 Precautionary Statements - Prevention: P264 - Wash face, hands and any exposed skin thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response: P321 - Specific treatment (see Section 4/ First Aid). P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/attention P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P332 + P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse Precautionary Statements - Storage: P404 - Store in a closed container Precautionary Statements - Disposal: P501 - Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC): Do not use this product in or on electrical equipment due to the possibility of shock hazard. 3. COMPOSITION/ INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% Pyriproxyfen (NYLAR®) 95737-68-1 10.0 *The exact percentage (concentration) of composition has been withheld as a trade secret Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications. 4. FIRST AID MEASURES Aspiration pneumonia hazard:‡1RWDSSOLFDEOH Description of first aid measures: Eye contact:Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin Contact:Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centeror doctor for treatment advice. Appearance:light yellow Physical state:Liquid Odor Sweet _____________________________________________________________________________________________ Page 2 / 9 _____________________________________________________________________________________________ NyGuard® IGR Concentrate Revision Date:24-Jan-2019 Ingestion:If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or a doctor. Never give anything by mouth to an unconscious person. Inhalation:Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Self-protection of the First Responder: Use personal protective equipment as required. Note to physicians: For skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroid exposure is topical application of tocopherol acetate (Vitamin E). 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media: Caution: Use of water spray when fighting fire may be inefficient. Hazardous combustion products:Carbon monoxide, Carbon dioxide (CO2). Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical Impact:None. Sensitivity to Static Discharge:None. Protective equipment and precautions for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions:Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Environmental precautions:Prevent further leakage or spillage if safe to do so. Do not allow into any sewer, on the ground or into any body of water. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment: Prevent further leakage or spillage if safe to do so. Methods for cleaning up: Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. _____________________________________________________________________________________________ Page 3 / 9 _____________________________________________________________________________________________ NyGuard® IGR Concentrate Revision Date:24-Jan-2019 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling:Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. Use with local exhaust ventilation. Do not breathe dust/fume/gas/mist/vapors/spray. For more information, see product label. Conditions for safe storage, including any incompatibilities Storage Conditions:Keep container tightly closed in a dry and well-ventilated place. Keep containers tightly closed in a cool, well-ventilated place. Keep in properly labeled containers. For more information, see product label. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Control parameters Exposure Guidelines:This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies Appropriate engineering controls Engineering Controls:Safety showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection:Wear safety glasses with side shields (or goggles). Skin and body protection:Wear protective gloves and protective clothing. Respiratory protection:If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations: When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties: Physical state:Liquid Appearance:light yellow Odor Sweet Odor threshold: No information available Color (Gardner Scale):3 Property:Values:&RPPHQW‡0HWKRG pH:5 @ 10% in H2O Melting point / freezing point:No information available Boiling point / boiling range:No information available _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ NyGuard® IGR Concentrate Revision Date:24-Jan-2019 Other Information: VOC Content (%):0 Miscibility/ Solubility: Water:Partially miscible Alcohol:Miscible Aromatic solvents:Miscible Petroleum distillates:Partially miscible 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization: Hazardous polymerization does not occur. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials: Incompatible with strong acids and bases. Incompatible with oxidizing agents. Hazardous Decomposition Products Carbon monoxide, Carbon dioxide (CO2). 11. TOXICOLOGICAL INFORMATION Numerical measures of toxicity - Product Information Oral LD50 >5,000 mg/kg (rat) Dermal LD50 >5,000 mg/kg (rabbit) Inhalation LC50 >5.05 mg/L, (rat; 4 hours) Flash point: > 93.3 °C / > 200.0 °F Tag Closed Cup; Evaporation rate:No information available Flammability (solid, gas):No information available Upper flammability limit (UEL):No information available Lower flammability limit (LEL):No information available Vapor pressure:No information available Vapor density:No information available Specific Gravity:0.939 @ 20.0 °C Water solubility:No information available Partition coefficient; n-Octanol/ Water: No information available Autoignition temperature: No information available Decomposition temperature:No information available Kinematic viscosity:No information available Dynamic viscosity:28 cPs @ 22.0 °C Refractive Index:1.4723 @ 25.0 °C No data available _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ NyGuard® IGR Concentrate Revision Date:24-Jan-2019 Eye contact:Irritation cleared within 7 days. (rabbit). Skin Contact:Slight irritation at 72 hours. (rabbit). Skin Irritation Index:2.5 Sensitization:Negative. (guinea pig). Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Reproductive toxicity:No information available. Developmental Toxicity No information available. Teratogenicity:No information available. STOT - single exposure:No information available. STOT - repeated exposure:No information available. Chronic toxicity:Avoid repeated exposure. 12. ECOLOGICAL INFORMATION Ecotoxicity: Persistence and degradability No information available. Bioaccumulation No information available. Other adverse effects:No information available Environmental hazards (EPA): Do not discharge effluent containing this product into lakes,streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes:Disposal should be in accordance with applicable regional, national and local laws and regulations. For more information, see product label. Contaminated packaging:For more information, see product label. 14. TRANSPORT INFORMATION DOT (Department of Transportation) Proper Shipping Name:Insecticides, Insect or Animal Repellent, Liquid Hazard Class:This material is not hazardous. Other DOT Shipping Information: This material is not regulated by the DOT as a hazardous material when shipped in Non-Bulk quantities (i.e., less-than 119 Gallons / 450 Liters). _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ NyGuard® IGR Concentrate Revision Date:24-Jan-2019 When shipping in Bulk-quantities (i.e., more than 119 Gallons / 450 Liters), please contact MGK® for the proper shipping description. Air (IATA/ ICAO) Proper Shipping Name: Insecticides, Insect or Animal Repellent, Liquid Hazard Class:This material is not hazardous. Vessel (IMO/ IMDG) Proper Shipping Name:Insecticides, Insect or Animal Repellent, Liquid Hazard Class:This material is not hazardous. 15. REGULATORY INFORMATION US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations: California Proposition 65: This product does not contain any intentionally added Proposition 65 chemicals U.S. EPA Label Information: EPA Registration Number:1021-1603 _____________________________________________________________________________________________ Page 7 / 9 Difference between SDS and EPA (FIFRA) Pesticide label: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria _____________________________________________________________________________________________ NyGuard® IGR Concentrate Revision Date:24-Jan-2019 and hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals. The pesticide label also includes other important information, including directions for use. The hazard information required on the pesticide label is reproduced below: Signal word:CAUTION Precautionary Statements: ‡&DXVHVPRGHUDWHH\HLUULWDWLRQ International Inventories: TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Does not comply IECSC Does not comply KECL Does not comply PICCS Does not comply AICS Does not comply Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION. Chronic Hazard Star Legend * = Chronic Health Hazard SDS Prepared By: Troy Azzivitto, MGK® Chemistry Department. e-Mail Address: mgk-sds@mgk.com Disclaimer:The information provided in this Safety Data Sheet (SDS) is provided in good faith and believed to be accurate at the time of preparation of the SDS. However, to the extent consistent with applicable law, MGK® and its subsidiaries or affiliates extend no warranties, make no representations, and assume no responsibility as to the accuracy, suitability, or completeness of such information. Additionally, to the extent consistent with applicable law, neither MGK® nor any of its subsidiaries NFPA Health hazards 2 Flammability 1 Instability 0 Physical and Chemical Properties - HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection X Issue Date: 24-Jan-2019 Revision Date: 24-Jan-2019 Revision Note: - SDS sections updated - 2 - 5 - 14 - 16 _____________________________________________________________________________________________ Page 8 / 9 _____________________________________________________________________________________________ NyGuard® IGR Concentrate Revision Date:24-Jan-2019 or affiliates represents or guarantees that this information or product may be used without infringing the intellectual property rights of others. Except to the extent a particular use and particular information are expressly stated on the product label, LWLVWKHXVHUV¶RZQUHVSRQVLELOLW\WRGHWHUPLQHWKHVXLWDELOLW\RIWKLVLQIRUPDWLRQIRU their own particular use of this product. If necessary, contact MGK® to confirm that you have the most current product label and SDS. This Safety Data Sheet (SDS) serves different purposes than and DOES NOT REPLACE OR MODIFY THE EPA-APPROVED PRODUCT LABEL (attached to and accompanying the product container). This SDS provides important health, safety, and environmental information for employers, employees, emergency responders and others handling large quantities of the product in activities generally other than product use as required by the Occupational Health and 6DIHW\$FW &)5³+D]FRP´ 7KHSURGXFWODEHOSURYLGHVLQIRUPDWLRQ specifically for product use in the ordinary course. Use, storage and disposal of pesticide products is regulated by the EPA under the authority of FIFRA through the product label. All necessary hazard classification and appropriate precautionary use, storage, and disposal information is set forth on that label or labeling accompanying the pesticide or to which reference is made on the label. It is a violation of federal law to use an EPA-registered pesticide product in any manner inconsistent with its labeling. End of Safety Data Sheet. _____________________________________________________________________________________________ Page 9 / 9 SAFETY DATA SHEET Issue Date:03-Dec-2018 Revision Date:03-Dec-2018 Version:6 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name:NyGuard® PLUS Flea & Tick Premise Spray EPA Registration Number:1021-2580 Other means of identification Part Code:29661 Recommended use of the chemical and restrictions on use: Recommended Use:A Liquefied Aerosol Insecticide Spray. Details of the supplier of the safety data sheet Telephone Number: (800) 645-6466, or (763) 544-0341 e-Mail Address: mgk-sds@mgk.com Emergency telephone numbers: 24 Hour TRANSPORTATION Emergency:CHEMTREC®: (800) 424-9300 International:(703) 527-3887 24 Hour MEDICAL Emergency:SafetyCall®: (888) 740-8712, or (952) 852-9509 Comments:MGK® Hours of operation are 8:00 a.m. to 4:30 p.m. CST, 14:00 to 22:30 GMT. For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to (888) 740-8712, or (952) 852-9509. 2. HAZARDS IDENTIFICATION Classification: OSHA Regulatory Status: This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 2 Skin sensitization Category 1 Aspiration toxicity Category 1 Label elements Emergency Overview Manufacturer Address: McLaughlin Gormley King Company 8810 10th Avenue North Minneapolis, MN 55427 FAX #: (763) 544-6437 Gases under pressure Liquefied gas DANGER _____________________________________________________________________________________________ Page 1 / 10 _____________________________________________________________________________________________ NyGuard® PLUS Flea & Tick Premise Spray Revision Date:03-Dec-2018 Precautionary Statements - Prevention: P251 - Pressurized container: Do not pierce or burn, even after use P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves Precautionary Statements - Response: P321 - Specific treatment (see Section 4/ First Aid). P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P362 - Take off contaminated clothing and wash before reuse P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 - Call a POISON CENTER or doctor/physician if you feel unwell P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P331 - Do NOT induce vomiting Precautionary Statements - Storage: P405 - Store locked up P410 + P403 - Protect from sunlight. Store in a well-ventilated place Precautionary Statements - Disposal: P501 - Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC): Do not use this product in or on electrical equipment due to the possibility of shock hazard. 3. COMPOSITION/ INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight-% d-Phenothrin (SUMITHRIN®) 26002-80-2 0.40 MGK®-264 Insecticide Synergist (n-Octyl bicycloheptene dicarboximide) 113-48-4 1.60 Pyriproxyfen (NYLAR®) 95737-68-1 0.10 Petroleum distillates, hydrotreated light 64742-47-8 10<--->20 * Hazard statements ‡+0D\EHIDWDOLIVZDOORZHGDQGHQWHUVDLUZD\V ‡++DUPIXOLILQKDOHG ‡+&DXVHVVNLQLUULWDWLRQ ‡+0D\FDXVHDQDOOHUJLFVNLQUHDFWLRQ ‡+&RQWDLQVJDVXQGHUSUHVVXUHPD\H[SORGHLIKHDWHG Appearance:Milky white / Milky yellow (Aerosol Non-volatiles) Physical state:Aerosol - Compressed liquefied gas. Odor Slight - Solvent _____________________________________________________________________________________________ Page 2 / 10 _____________________________________________________________________________________________ NyGuard® PLUS Flea & Tick Premise Spray Revision Date:03-Dec-2018 Propane 74-98-6 2.22 Isobutane 75-28-5 12.4 *The exact percentage (concentration) of composition has been withheld as a trade secret Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications. 4. FIRST AID MEASURES Aspiration pneumonia hazard:‡0D\EHIDWDOLIVZDOORZHGDQGHQWHUVDLUZD\V Description of first aid measures: Eye contact:Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin Contact:Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centeror doctor for treatment advice. Ingestion:If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. DO NOT give any liquid to the person. Do not induce vomiting unless told to do so by a poison contol center or a doctor. Never give anything by mouth to an unconscious person. Inhalation:Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Self-protection of the First Responder: Remove all sources of ignition. Use personal protective equipment as required. Note to physicians:&RQWDLQVSHWUROHXPGLVWLOODWHV±YRPLWLQJPD\FDXVHDVSLUDWLRQSQHXPRQLD For skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroid exposure is topical application of tocopherol acetate (Vitamin E). 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media: Caution: Use of water spray when fighting fire may be inefficient. Hazardous combustion products:Carbon monoxide, Carbon dioxide (CO2). Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical Impact:None. Sensitivity to Static Discharge:None. _____________________________________________________________________________________________ Page 3 / 10 _____________________________________________________________________________________________ NyGuard® PLUS Flea & Tick Premise Spray Revision Date:03-Dec-2018 Protective equipment and precautions for firefighters: In the event of fire and/or explosion do not breathe fumes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions:Remove all sources of ignition. Evacuate personnel to safe areas. Ensure adequate ventilation, especially in confined areas. Keep people away from and upwind of spill/leak. Use personal protective equipment as required. Environmental precautions:Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment:Prevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading. Dike far ahead of liquid spill for later disposal. Methods for cleaning up:Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling:Ensure adequate ventilation, especially in confined areas. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. All equipment used when handling the product must be grounded. Use with local exhaust ventilation. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. For more information, see product label. Conditions for safe storage, including any incompatibilities Storage Conditions:Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. For more information, see product label. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Control parameters Exposure Guidelines: Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Supplier OEL Petroleum distillates, hydrotreated light 64742-47-8 - - - TWA: 100 ppm TWA: 525 mg/m3 Propane 74-98-6 : See Appendix F: Minimal Oxygen Content, explosion hazard TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 - Isobutane STEL: 1000 ppm explosion - TWA: 800 ppm - _____________________________________________________________________________________________ Page 4 / 10 _____________________________________________________________________________________________ NyGuard® PLUS Flea & Tick Premise Spray Revision Date:03-Dec-2018 75-28-5 hazard TWA: 1900 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Appropriate engineering controls Engineering Controls:Safety showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection:Protective eyewear is recommended, but is not required. Skin and body protection:Wear protective gloves and protective clothing. Respiratory protection:If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations: When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties: Physical state:Aerosol - Compressed liquefied gas. Appearance:Milky white / Milky yellow (Aerosol Non-volatiles) Odor Slight - Solvent Odor threshold: No information available Color (Gardner Scale):No information available Property:Values:&RPPHQW‡0HWKRG pH:7.5 @ 5% in H2O Test was performed on aerosol Non-Volatile's Melting point / freezing point:No information available Boiling point / boiling range:No information available Flash point:> 93.3 °C / > 200.0 °F Tag Closed Cup; Test was performed on aerosol Non-Volatile's; Evaporation rate:No information available Flammability (solid, gas): No information available Upper flammability limit (UEL):No information available Lower flammability limit (LEL):No information available Vapor pressure:No information available Vapor density:No information available Specific Gravity:No information available Water solubility:No information available Partition coefficient; n-Octanol/ Water: No information available Autoignition temperature: No information available Decomposition temperature: No information available Kinematic viscosity:No information available Dynamic viscosity:2,483.3 cPs @ 21.3 °C Test was performed on aerosol Non-Volatile's _____________________________________________________________________________________________ Page 5 / 10 _____________________________________________________________________________________________ NyGuard® PLUS Flea & Tick Premise Spray Revision Date:03-Dec-2018 Other Information: Density:0.979 g/cm3 @ 22.0 °C (Aerosol Non-volatiles) VOC Content (%):14.6 Miscibility/ Solubility: Water:Partially miscible Alcohol:Partially miscible Aromatic solvents:Partially miscible Petroleum distillates:Partially miscible 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization:Hazardous polymerization does not occur. Conditions to avoid Heat, flames and sparks. Incompatible materials: Incompatible with strong acids and bases. Incompatible with oxidizing agents. Hazardous Decomposition Products Carbon monoxide, Carbon dioxide (CO2). 11. TOXICOLOGICAL INFORMATION Numerical measures of toxicity - Product Information Oral LD50 >5,000 mg/kg (rat) Dermal LD50 >5,000 mg/kg (rabbit) Inhalation LC50 >2.08 mg/L, (rat; 4 hours) Eye contact:Non-irritating to eyes. (rabbit). Skin Contact:Causes moderate skin irritation. Irritation cleared within 7 days. (rabbit). Skin Irritation Index:3.6 Sensitization:Positive. (guinea pig). Comment:Some of the above toxicity data was bridged from the insecticide concentrate, that is used in manufacturing this end-use product. Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Reproductive toxicity: No information available. Developmental Toxicity No information available. Teratogenicity:No information available. Refractive Index:No information available No data available _____________________________________________________________________________________________ Page 6 / 10 _____________________________________________________________________________________________ NyGuard® PLUS Flea & Tick Premise Spray Revision Date:03-Dec-2018 STOT - single exposure: No information available. STOT - repeated exposure: No information available. Chronic toxicity:Avoid repeated exposure. Target Organ Effects:Central nervous system. 12. ECOLOGICAL INFORMATION Ecotoxicity: Persistence and degradability No information available. Bioaccumulation No information available. Chemical Name Partition coefficient; n-Octanol/ Water: d-Phenothrin (SUMITHRIN®) 26002-80-2 6.8 Propane 74-98-6 2.3 Isobutane 75-28-5 2.88 Other adverse effects:No information available Environmental hazards (EPA): Do not discharge effluent containing this product into lakes,streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes:Disposal should be in accordance with applicable regional, national and local laws and regulations. For more information, see product label. Contaminated packaging: For more information, see product label. 14. TRANSPORT INFORMATION DOT (Department of Transportation) UN/ID Number:UN1950 Proper Shipping Name:Aerosols, non-flammable, Limited Quantity Hazard Class:2.2 Air (IATA/ ICAO) UN/ID Number:UN1950 Proper Shipping Name:Aerosols, non-flammable Hazard Class:2.2 Vessel (IMO/ IMDG) _____________________________________________________________________________________________ Page 7 / 10 _____________________________________________________________________________________________ NyGuard® PLUS Flea & Tick Premise Spray Revision Date:03-Dec-2018 UN/ID Number:UN1950 Proper Shipping Name: Aerosols, non-flammable Hazard Class:2.2 15. REGULATORY INFORMATION US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard Yes Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations: California Proposition 65: This product does not contain any intentionally added Proposition 65 chemicals U.S. EPA Label Information: EPA Registration Number:1021-2580 Difference between SDS and EPA (FIFRA) Pesticide label: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals. The pesticide label also includes other important information, including directions for use. The hazard information required on the pesticide label is reproduced below: Signal word:CAUTION Precautionary Statements: ‡3URORQJHGRUIUHTXHQWO\UHSHDWHGVNLQFRQWDFWPD\FDXVHDOOHUJLFUHDFWLRQVLQVRPHLQGLYLGXDOV International Inventories: _____________________________________________________________________________________________ Page 8 / 10 _____________________________________________________________________________________________ NyGuard® PLUS Flea & Tick Premise Spray Revision Date:03-Dec-2018 TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Does not comply IECSC Does not comply KECL Does not comply PICCS Does not comply AICS Does not comply Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION. Chronic Hazard Star Legend * = Chronic Health Hazard SDS Prepared By: Troy Azzivitto, MGK® Chemistry Department. e-Mail Address: mgk-sds@mgk.com Disclaimer:The information provided in this Safety Data Sheet (SDS) is provided in good faith and believed to be accurate at the time of preparation of the SDS. However, to the extent consistent with applicable law, MGK® and its subsidiaries or affiliates extend no warranties, make no representations, and assume no responsibility as to the accuracy, suitability, or completeness of such information. Additionally, to the extent consistent with applicable law, neither MGK® nor any of its subsidiaries or affiliates represents or guarantees that this information or product may be used without infringing the intellectual property rights of others. Except to the extent a particular use and particular information are expressly stated on the product label, LWLVWKHXVHUV¶RZQUHVSRQVLELOLW\WRGHWHUPLQHWKHVXLWDELOLW\RIWKLVLQIRUPDWLRQIRU their own particular use of this product. If necessary, contact MGK® to confirm that you have the most current product label and SDS. This Safety Data Sheet (SDS) serves different purposes than and DOES NOT REPLACE OR MODIFY THE EPA-APPROVED PRODUCT LABEL (attached to NFPA Health hazards 2 Flammability 0 Instability 0 Physical and Chemical Properties * HMIS Health hazards 2*Flammability 0 Physical hazards 0 Personal protection X Issue Date: 03-Dec-2018 Revision Date: 03-Dec-2018 Revision Note: - SDS sections updated - 2 - 5 - 14 - 16 _____________________________________________________________________________________________ Page 9 / 10 _____________________________________________________________________________________________ NyGuard® PLUS Flea & Tick Premise Spray Revision Date:03-Dec-2018 and accompanying the product container). This SDS provides important health, safety, and environmental information for employers, employees, emergency responders and others handling large quantities of the product in activities generally other than product use as required by the Occupational Health and 6DIHW\$FW &)5³+D]FRP´ 7KHSURGXFWODEHOSURYLGHVLQIRUPDWLRQ specifically for product use in the ordinary course. Use, storage and disposal of pesticide products is regulated by the EPA under the authority of FIFRA through the product label. All necessary hazard classification and appropriate precautionary use, storage, and disposal information is set forth on that label or labeling accompanying the pesticide or to which reference is made on the label. It is a violation of federal law to use an EPA-registered pesticide product in any manner inconsistent with its labeling. End of Safety Data Sheet. _____________________________________________________________________________________________ Page 10 / 10 SAFETY DATA SHEET Issue Date:25-Aug-2017 Revision Date:25-Aug-2017 Version:2 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name:Onslaught® FastCap Spider & Scorpion Insecticide EPA Registration Number:1021-2574 Other means of identification Part Code:2964 Recommended use of the chemical and restrictions on use: Recommended Use:Insecticide. Details of the supplier of the safety data sheet Telephone Number: (800) 645-6466, or (763) 544-0341 e-Mail Address: mgk-sds@mgk.com Emergency telephone numbers: 24 Hour TRANSPORTATION Emergency:CHEMTREC®: (800) 424-9300 International:(703) 527-3887 24 Hour MEDICAL Emergency:SafetyCall®: (888) 740-8712, or (952) 852-9509 Comments:MGK® Hours of operation are 8:00 a.m. to 4:30 p.m. CST, 14:00 to 22:30 GMT. For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to (888) 740-8712, or (952) 852-9509. 2. HAZARDS IDENTIFICATION Environment:OSHA has not adopted the environmental - portion of the GHS regulations, however, this SDS may include information on environmental effects. Classification: OSHA Regulatory Status: This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Acute toxicity - Oral Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 2 Label elements Emergency Overview Manufacturer Address: McLaughlin Gormley King Company 8810 10th Avenue North Minneapolis, MN 55427 FAX #: (763) 544-6437 WARNING _____________________________________________________________________________________________ Page 1 / 9 _____________________________________________________________________________________________ Onslaught® FastCap Spider & Scorpion Insecticide Revision Date:25-Aug-2017 Precautionary Statements - Prevention: P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves Precautionary Statements - Response: P321 - Specific treatment (see Section 4/ First Aid). P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P332 + P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 - Call a POISON CENTER or doctor/physician if you feel unwell P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P330 - Rinse mouth Precautionary Statements - Storage: P404 - Store in a closed container Precautionary Statements - Disposal: P501 - Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC): Do not use this product in or on electrical equipment due to the possibility of shock hazard. 3. COMPOSITION/ INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Esfenvalerate 66230-04-4 6.40 Prallethrin (ETOC®) 23031-36-9 1.60 Piperonyl Butoxide (PBO) 51-03-6 8.00 Petroleum distillates, hydrotreated light 64742-47-8 < 10 * *The exact percentage (concentration) of composition has been withheld as a trade secret. Hazard statements ‡++DUPIXOLILQKDOHG ‡+&DXVHVVNLQLUULWDWLRQ ‡++DUPIXOLIVZDOORZHG ‡+9HU\WR[LFWRDTXDWLFOLIH ‡+9HU\WR[LFWRDTXDWLFOLIHZLWKORQJODVWLQJHIIHFWV Appearance:cream , light yellow / brown Physical state:Liquid _____________________________________________________________________________________________ Page 2 / 9 Odor Slight - Sweet _____________________________________________________________________________________________ Onslaught® FastCap Spider & Scorpion Insecticide Revision Date:25-Aug-2017 Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications. 4. FIRST AID MEASURES Aspiration pneumonia hazard:‡1RLQIRUPDWLRQDYDLODEOH Description of first aid measures: Eye contact:Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin Contact:Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centeror doctor for treatment advice. Ingestion:If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. DO NOT give any liquid to the person. Do not induce vomiting unless told to do so by a poison contol center or a doctor. Never give anything by mouth to an unconscious person. Inhalation:Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Self-protection of the First Responder: Use personal protective equipment as required. Note to physicians: For skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroid exposure is topical application of tocopherol acetate (Vitamin E). 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media: Caution: Use of water spray when fighting fire may be inefficient. Hazardous combustion products:Carbon monoxide, Carbon dioxide (CO2), Hydrogen cyanide. Specific hazards arising from the chemical In the event of fire and/or explosion do not breathe fumes.May cause sensitization by inhalation and skin contact. Thermal decomposition can lead to release of irritating and toxic gases and vapors. Explosion data Sensitivity to Mechanical Impact:None. Sensitivity to Static Discharge:None. Protective equipment and precautions for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health hazards 2 Flammability 1 Instability 0 Physical and Chemical Properties - HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection _____________________________________________________________________________________________ Page 3 / 9 _____________________________________________________________________________________________ Onslaught® FastCap Spider & Scorpion Insecticide Revision Date:25-Aug-2017 Chronic Hazard Star Legend * = Chronic Health Hazard 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions:Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Environmental precautions:Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment: Prevent further leakage or spillage if safe to do so. Methods for cleaning up: Cover liquid spill with sand, earth or other non-combustible absorbent material. Cover powder spill with plastic sheet or tarp to minimize spreading. Pick up and transfer to properly labeled containers.Soak up with inert absorbent material. Dam up. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling:Avoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. When using do not eat, drink or smoke. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Use with local exhaust ventilation. For more information, see product label. Conditions for safe storage, including any incompatibilities Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Keep in properly labeled containers. For more information, see product label. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Control parameters Exposure Guidelines:This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Supplier OEL Petroleum distillates, hydrotreated light 64742-47-8 - - - TWA: 100 ppm TWA: 525 mg/m3 Appropriate engineering controls Engineering Controls:Safety showers Eyewash stations Ventilation systems X _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ Onslaught® FastCap Spider & Scorpion Insecticide Revision Date:25-Aug-2017 Individual protection measures, such as personal protective equipment Eye/face protection:Protective eyewear is recommended, but is not required. Skin and body protection: Wear protective gloves and protective clothing. Respiratory protection: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations: When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties: Physical state:Liquid Other Information: Density:1.011 g/cm3 @20.0°C VOC Content (%):2.5 Miscibility/ Solubility: Water:Immiscible Alcohol Immiscible Aromatic solvents:Immiscible Petroleum distillates:Immiscible Appearance:cream , light yellow / brown Odor Slight - Sweet Odor threshold:No information available Color (Gardner Scale):No information available Property:Values:&RPPHQW‡0HWKRG pH:6.9 @ 5% in H2O. . Melting point / freezing point:No information available Boiling point / boiling range:No information available Flash point: > 93.3 °C / > 200.0 °F Tag Closed Cup; Evaporation rate:No information available Flammability (solid, gas):No information available Upper flammability limit (UEL):No information available Lower flammability limit (LEL):No information available Vapor pressure:No information available Vapor density:No information available Specific Gravity:No information available Water solubility:No information available Partition coefficient; n-Octanol/ Water: No information available Autoignition temperature: No information available Decomposition temperature: No information available Kinematic viscosity:No information available Dynamic viscosity:1,446 cPs. @ 21.3 °C. Refractive Index:No information available _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ Onslaught® FastCap Spider & Scorpion Insecticide Revision Date:25-Aug-2017 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization: Hazardous polymerization does not occur. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials: Incompatible with strong acids and bases. Incompatible with oxidizing agents. Hazardous Decomposition Products Carbon monoxide, Carbon dioxide (CO2), Hydrogen cyanide. 11. TOXICOLOGICAL INFORMATION Numerical measures of toxicity - Product Information Oral LD50 1,750 mg/kg (rat) Dermal LD50 >5,000 mg/kg (rabbit) Inhalation LC50 >2.04 mg/L, (rat; 4 hours) Eye contact:Slightly irritating. Irritation clearing in 72 hours. (rabbit). Skin Contact:Moderate irritation at 72 hours. (rabbit). Skin Irritation Index: 2.4 Sensitization:Negative. (guinea pig). Piperonyl Butoxide: Carcinogenicity/ Oncogenicity: Marginally higher incidences of benign liver tumors in mice were observed following lifetime high dose exposures to PBO. The significance of these observations is questionable and under review. The doses at which tumors were observed for PBO greatly exceeded potential human exposure from labeled uses. Doses at which these effects were observed greatly exceeded anticipated human dietary intake. At anticipated dietary exposure levels, it is highly unlikely that this product will result in carcinogenic effects. Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Reproductive toxicity:No information available. Developmental Toxicity No information available. Teratogenicity:No information available. STOT - single exposure: No information available. STOT - repeated exposure: No information available. Chronic toxicity: Repeated contact may cause allergic reactions in very susceptible persons. Avoid repeated exposure. 12. ECOLOGICAL INFORMATION No data available _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ Onslaught® FastCap Spider & Scorpion Insecticide Revision Date:25-Aug-2017 Ecotoxicity: Persistence and degradability No information available. Bioaccumulation No information available. Chemical Name Partition coefficient; n-Octanol/ Water: Prallethrin (ETOC®) 23031-36-9 4.49 Other adverse effects:No information available Environmental hazards (EPA): Do not discharge effluent containing this product into lakes,streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes:Disposal should be in accordance with applicable regional, national and local laws and regulations. For more information, see product label. Contaminated packaging: For more information, see product label. 14. TRANSPORT INFORMATION DOT (Department of Transportation) Proper Shipping Name:Insecticides, Insect or Animal Repellent, Liquid Hazard Class:This material is not hazardous. Air (IATA/ ICAO) Proper Shipping Name: Insecticides, Insect or Animal Repellent, Liquid Hazard Class:This material is not hazardous. Vessel (IMO/ IMDG)Not available 15. REGULATORY INFORMATION US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % Piperonyl Butoxide (PBO) - 51-03-6 1.0 _____________________________________________________________________________________________ Page 7 / 9 _____________________________________________________________________________________________ Onslaught® FastCap Spider & Scorpion Insecticide Revision Date:25-Aug-2017 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations: California Proposition 65: This product does not contain any Proposition 65 chemicals U.S. EPA Label Information: EPA Registration Number:1021-2574 Difference between SDS and EPA (FIFRA) Pesticide label: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals. The pesticide label also includes other important information, including directions for use. The hazard information required on the pesticide label is reproduced below: Signal word:CAUTION Precautionary Statements: ‡+DUPIXOLIVZDOORZHG ‡&DXVHVPRGHUDWHH\HLUULWDWLRQ International: TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Does not comply IECSC Complies KECL Complies PICCS Does not comply AICS Does not comply Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory _____________________________________________________________________________________________ Page 8 / 9 DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List _____________________________________________________________________________________________ Onslaught® FastCap Spider & Scorpion Insecticide Revision Date:25-Aug-2017 EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION. SDS Prepared By: Troy Azzivitto, MGK® Chemistry Department. e-Mail Address: mgk-sds@mgk.com Disclaimer:The information provided in this Safety Data Sheet (SDS) is provided in good faith and believed to be accurate at the time of preparation of the SDS. However, to the extent consistent with applicable law, MGK® and its subsidiaries or affiliates extend no warranties, make no representations, and assume no responsibility as to the accuracy, suitability, or completeness of such information. Additionally, to the extent consistent with applicable law, neither MGK® nor any of its subsidiaries or affiliates represents or guarantees that this information or product may be used without infringing the intellectual property rights of others. Except to the extent a particular use and particular information are expressly stated on the product label, LWLVWKHXVHUV¶RZQUHVSRQVLELOLW\WRGHWHUPLQHWKHVXLWDELOLW\RIWKLVLQIRUPDWLRQIRU their own particular use of this product. If necessary, contact MGK® to confirm that you have the most current product label and SDS. This Safety Data Sheet (SDS) serves different purposes than and DOES NOT REPLACE OR MODIFY THE EPA-APPROVED PRODUCT LABEL (attached to and accompanying the product container). This SDS provides important health, safety, and environmental information for employers, employees, emergency responders and others handling large quantities of the product in activities generally other than product use as required by the Occupational Health and 6DIHW\$FW &)5³+D]FRP´ 7KHSURGXFWODEHOSURYLGHVLQIRUPDWLRQ specifically for product use in the ordinary course. Use, storage and disposal of pesticide products is regulated by the EPA under the authority of FIFRA through the product label. All necessary hazard classification and appropriate precautionary use, storage, and disposal information is set forth on that label or labeling accompanying the pesticide or to which reference is made on the label. It is a violation of federal law to use an EPA-registered pesticide product in any manner inconsistent with its labeling. End of Safety Data Sheet. Issue Date: 25-Aug-2017 Revision Date: 25-Aug-2017 _____________________________________________________________________________________________ Page 9 / 9 Revision Note: - SDS sections updated - 2 - 5 - 8 - 15 - 16 Safety Data Sheet 2/12/2015 6/29/2015 Replaces: Date: OPTIGARD® ANT GEL BAIT 1. PRODUCT IDENTIFICATION A15236A Use:Insecticide Product identifier on label:OPTIGARD® ANT GEL BAIT Manufacturer:Syngenta Crop Protection, LLC Post Office Box 18300 Greensboro NC 27419 Manufacturer Phone:1-800-334-9481 Emergency Phone:1-800-888-8372 Product No.: Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name ConcentrationCommon Name CAS Number Other ingredients Other ingredients Trade Secret 99.99% 3-(2-chloro-1,3-thiazol-5-ylmethyl)-5- methyl-1,3,5-oxadiazinan-4- ylidene(nitro)amine Thiamethoxam 153719-23-4 0.010% 2. HAZARDS IDENTIFICATION Not Applicable Classifications: Signal Word (OSHA): Not ApplicableHazard Statements: Not Applicable 4. FIRST AID MEASURES Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison contol center or doctor, or going for treatment. If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so after calling 800-888- Ingestion: NoneOther Hazard Statements: Precautionary Statements:Not Applicable Hazard Symbols: Page 1 of 7 Safety Data Sheet 2/12/2015 6/29/2015 Replaces: Date: OPTIGARD® ANT GEL BAIT 8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment advice. Eye Contact: Skin Contact: Inhalation: Indication of immediate medical attention and special treatment needed: Most important symptoms/effects: There is no specific antidote if this product is ingested. Treat symptomatically. Not Applicable 5. FIRE FIGHTING MEASURES Suitable (and unsuitable) extinguishing media: Specific Hazards: Special protective equipment and precautions for firefighters: Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect runoff. During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Methods and materials for containment and cleaning up: Follow exposure controls/personal protection outlined in Section 8. Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Sweep up material and place in a compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. HANDLING AND STORAGE Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Not Applicable Page 2 of 7 Safety Data Sheet 2/12/2015 6/29/2015 Replaces: Date: OPTIGARD® ANT GEL BAIT 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingestion: Eye Contact: Skin Contact: Inhalation: THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. Occupational Exposure Limits: Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures: Chemical Name OtherOSHA PEL ACGIH TLV Source Other ingredients Not Applicable Not Applicable Not Applicable Not Applicable Thiamethoxam Not Established Not Established 3 mg/m³ TWA Syngenta Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Where eye contact is likely, use dust-proof chemical goggles. Where contact is likely, wear chemical-resistant gloves (such as barrier laminate, butyl rubber, nitrile rubber, neoprene rubber, natural rubber, polyvinyl chloride [PVC] or Viton), coveralls, socks and chemical-resistant footwear. A respirator is not normally required when handling this substance. In case of emergency spills, use a NIOSH approved respirator with any N, R, P or HE filter. Odorless Colorless to clear solid 9. PHYSICAL AND CHEMICAL PROPERTIES Vapor Pressure: Solubility (ies): pH:6.6 (1% in deionized H2O @ 77°F (25°C)) Odor: Appearance: Not Applicable Not Available Initial boiling point and boiling range: Melting point/freezing point: Odor Threshold:Not Available Not Available Flammability:Not Available Not AvailableFlash Point (Test Method): Flammable Limits (% in Air): Vapor Density: Relative Density: Not AvailablePartition coefficient: n-octanol/water: 1.263 g/cm³ @ 68°F (20°C) Not Available Thiamethoxam 2 x 10(-11) mmHg @ 68°F (20°C) Thiamethoxam 4.1 g/l @ 77°F (25°C) Page 3 of 7 Safety Data Sheet 2/12/2015 6/29/2015 Replaces: Date: OPTIGARD® ANT GEL BAIT Not AvailableAutoignition Temperature: Not AvailableDecomposition Temperature: Not AvailableViscosity: NoneOther: Incompatible materials: Possibility of hazardous reactions:Will not occur. Chemical stability:Stable under normal use and storage conditions. 10. STABILITY AND REACTIVITY None known.Hazardous Decomposition Products: Reactivity:Not reactive. Conditions to Avoid:None known. None known. 11. TOXICOLOGICAL INFORMATION Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Chronic/Subchronic Toxicity Studies Carcinogenicity Ingestion: Dermal: Inhalation: Eye Contact: Skin Contact: Skin Sensitization: Oral (LD50 Female Rat) : Minimally Irritating (Rabbit) Practically Non-Irritating (Rabbit) Not a Sensitizer (Guinea Pig) Dermal (LD50 Rabbit) : Inhalation (LC50 Rat) : > 5000 mg/kg body weight > 5050 mg/kg body weight > 2.61 mg/l air - 4 hours Reproductive/Developmental Effects Likely routes of exposure: Health effects information Symptoms of exposure: Delayed, immediate and chronic effects of exposure: Thiamethoxam: Subchronic: Liver effects occurred in rodents only at high dose levels. Not neurotoxic after high acute and subchronic exposure in rats. Thiamethoxam: Developmental: Not teratogenic in rats or rabbits. Reproductive: No effects on reproduction. Minor increase in a common testis effect in rats at high doses, which did not affect reproduction. Dermal, Inhalation Not Applicable Not Applicable Page 4 of 7 Safety Data Sheet 2/12/2015 6/29/2015 Replaces: Date: OPTIGARD® ANT GEL BAIT Carcinogenicity Toxicity of Other Components Target Organs Other Toxicity Information None Active Ingredients Inert Ingredients Thiamethoxam: Classified as "not likely to be carcinogenic in humans" based on lifetime studies in mice and rats. Not Applicable Other ingredients Thiamethoxam: Liver Other ingredients: Not Applicable Chemical Name NTP/IARC/OSHA Carcinogen Other ingredients No 3-(2-chloro-1,3-thiazol-5-ylmethyl)-5-methyl- 1,3,5-oxadiazinan-4-ylidene(nitro)amine No 12. ECOLOGICAL INFORMATION Environmental Fate Eco-Acute Toxicity The information presented here is for the active ingredient, thiamethoxam. Not persistent in soil. Stable in water. Moderate mobility in soil. Floats in water (after 24 h). Thiamethoxam: Thiamethoxam: Fish (Rainbow Trout) 96-hour LC50 > 100 ppm Bird (Mallard Duck) LD50 Oral 576 mg/kg Invertebrate (Daphnia Magna) 48-hour EC50 > 106 ppm Green Algae 4-day EC50 > 97 ppm 13. DISPOSAL CONSIDERATIONS Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations. Characteristic Waste:Not Applicable Listed Waste:Not Applicable Disposal: 14. TRANSPORT INFORMATION DOT Classification Ground Transport - NAFTA Not regulated Comments Water Transport - International Page 5 of 7 Safety Data Sheet 2/12/2015 6/29/2015 Replaces: Date: OPTIGARD® ANT GEL BAIT Not regulated. Air Transport - International Not regulated. 15. REGULATORY INFORMATION RCRA Hazardous Waste Classification (40 CFR 261): Not Applicable TSCA Status: Exempt from TSCA, subject to FIFRA EPCRA SARA Title III Classification: Section 311/312 Hazard Classes: Section 313 Toxic Chemicals: CERCLA/SARA 304 Reportable Quantity (RQ): None Pesticide Registration: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Registration Number(s): 100-1260 None Acute Health Hazard Caution: Keep out of reach of children. 1 00 1 1 16. OTHER INFORMATION NFPA Hazard Ratings 12/7/2006 2/12/20156/29/2015 Health: Flammability: Instability: Replaces: Original Issued Date: Revision Date: HMIS Hazard Ratings Health: Flammability: Reactivity: 0 Minimal 1 Slight 2 Moderate 3 Serious 4 Extreme ASyngenta Hazard Category: 2, 4, 11, 16Section(s) Revised: * Chronic 1 For non-emergency questions about this product call: 1-800-334-9481 Page 6 of 7 Safety Data Sheet 2/12/2015 6/29/2015 Replaces: Date: OPTIGARD® ANT GEL BAIT The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. Page 7 of 7 Safety Data Sheet 3/31/2017 4/12/2017 Replaces: Date: OPTIGARD® COCKROACH GEL BAIT 1. PRODUCT IDENTIFICATION A15276C Use:Insecticide Product identifier on label:OPTIGARD® COCKROACH GEL BAIT Manufacturer:Syngenta Crop Protection, LLC Post Office Box 18300 Greensboro NC 27419 Manufacturer Phone:1-800-334-9481 Emergency Phone:1-800-888-8372 Product No.: Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name ConcentrationCommon Name CAS Number Other ingredients Other ingredients Trade Secret 99.9% Avermectin B1, 4"-deoxy-4"- (methylamino)-,(4"R)-, benzoate (salt) Emamectin Benzoate 155569-91-8 0.1% 2. HAZARDS IDENTIFICATION Not Applicable Classifications: Signal Word (OSHA): Not ApplicableHazard Statements: Not Applicable 4. FIRST AID MEASURES Have the product container, label or Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison control center or doctor, or going for treatment. If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so after calling 800-888- 8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Ingestion: NoneOther Hazard Statements: Precautionary Statements:Not Applicable Hazard Symbols: Page 1 of 7 Safety Data Sheet 3/31/2017 4/12/2017 Replaces: Date: OPTIGARD® COCKROACH GEL BAIT If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta (800-888-8372), a poison control center or doctor for further treatment advice. Eye Contact: Skin Contact: Inhalation: Indication of immediate medical attention and special treatment needed: Most important symptoms/effects: Early signs of intoxication include dilation of pupils, muscular incoordination and muscular tremors. Vomiting within one- half hour of exposure can minimize toxicity following accidental ingestion of the product; rapidly after exposure (<15 minutes) administer repeatedly medical charcoal in a large quantity of water or ipecac. If toxicity from exposure has progressed to cause severe vomiting, the extent of resultant fluid and electrolyte imbalance should be gauged. Appropriate supportive parental fluid replacement therapy should be given, along with other required supportive measures (such as maintenance of blood pressure levels and proper respiratory functionality) as indicated by clinical signs, symptoms and measurements. In severe cases, observations should continue for at least several days until clinical condition is stable and normal. Since emamectin benzoate is believed to enhance GABA activity in animals, it is probably wise to avoid drugs that enhance GABA activity (barbiturates, benzodiazepines, valproic acid) in patients with potentially toxic emamectin benzoate exposure. Not Applicable 5. FIRE FIGHTING MEASURES Suitable (and unsuitable) extinguishing media: Specific Hazards: Special protective equipment and precautions for firefighters: Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect runoff. During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Methods and materials for containment and cleaning up: Follow exposure controls/personal protection outlined in Section 8. Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Sweep up material and place in a compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. HANDLING AND STORAGE Precautions for safe handling: Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Page 2 of 7 Safety Data Sheet 3/31/2017 4/12/2017 Replaces: Date: OPTIGARD® COCKROACH GEL BAIT Conditions for safe storage, including any incompatibilities: Not Applicable 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingestion: Eye Contact: Skin Contact: Inhalation: THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. Occupational Exposure Limits: Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures: Chemical Name OtherOSHA PEL ACGIH TLV Source Other ingredients Not Established Not Established Not Established Not Applicable Emamectin Benzoate Not Established Not Established 0.02 mg/m³ TWA Syngenta Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Where eye contact is likely, use dust-proof chemical goggles. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Where contact is likely, wear chemical-resistant gloves (such as barrier laminate, butyl rubber, nitrile rubber, neoprene rubber, natural rubber, polyethylene, polyvinyl chloride [PVC] or Viton), coveralls, socks and chemical-resistant footwear. A particulate filter respirator may be necessary until effective engineering controls are installed to comply with occupational exposure limits. Use a NIOSH certified respirator with any R, P or HE filter. Use a self-contained breathing apparatus in cases of emergency spills, when exposure levels are unknown, or under any circumstances where air-purifying respirators may not provide adequate protection. Peanut-like Light brown to dark brown solid 9. PHYSICAL AND CHEMICAL PROPERTIES pH:3 - 7 (1% in deionized water) Odor: Appearance: Not Available Not Applicable Initial boiling point and boiling range: Melting point/freezing point: Odor Threshold:Not Available Flammability:Not Available Not AvailableFlash Point (Test Method): Flammable Limits (% in Air): Page 3 of 7 Safety Data Sheet 3/31/2017 4/12/2017 Replaces: Date: OPTIGARD® COCKROACH GEL BAIT Vapor Pressure: Solubility (ies): Not AvailableAutoignition Temperature: Vapor Density: Relative Density: Not AvailableDecomposition Temperature: Not AvailableViscosity: Partition coefficient: n-octanol/water: Other: 1.097 g/cm³ @ 77°F (25°C) Not Available Emamectin Benzoate 3 x 10(-8) mmHg @ 70°F (21°C) Emamectin Benzoate 30 - 50 ppm (pH 7) Incompatible materials: Possibility of hazardous reactions:Will not occur. Chemical stability:Stable under normal use and storage conditions. 10. STABILITY AND REACTIVITY None known.Hazardous Decomposition Products: Reactivity:Not reactive. Conditions to Avoid:None known. None known. 11. TOXICOLOGICAL INFORMATION Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Ingestion: Dermal: Inhalation: Eye Contact: Skin Contact: Skin Sensitization: Oral (LD50 Female Rat) : Moderately Irritating (Rabbit) (based on a substantially similar formulation) Practically Non-Irritating (Rabbit) (based on a substantially similar formulation) Not a Sensitizer (Guinea Pig) (based on a substantially similar formulation) Dermal (LD50 Rat) : Inhalation (LC50 Female Rat) : > 5000 mg/kg body weight (based on a substantially similar formulation) > 5050 mg/kg body weight (based on a substantially similar formulation) > 5 mg/l air - 4 hours (based on a substantially similar formulation) Likely routes of exposure: Health effects information Symptoms of exposure: Delayed, immediate and chronic effects of exposure: Dermal, Inhalation Not Applicable Not Applicable Page 4 of 7 Safety Data Sheet 3/31/2017 4/12/2017 Replaces: Date: OPTIGARD® COCKROACH GEL BAIT Chronic/Subchronic Toxicity Studies Carcinogenicity Toxicity of Other Components Target Organs Other Toxicity Information None Reproductive/Developmental Effects Active Ingredients Inert Ingredients Emamectin Benzoate: Tremors and nerve lesions observed at lowest dose tested in rabbits. Bladder changes reported in rats. Emamectin Benzoate: None observed. Not Established Other ingredients Emamectin Benzoate: Developmental and reproductive toxicity observed in dosages that are toxic to mature animals. Emamectin Benzoate: Central nervous system, bladder Other ingredients: Not Established Chemical Name NTP/IARC/OSHA Carcinogen Other ingredients No Avermectin B1, 4"-deoxy-4"-(methylamino)- ,(4"R)-, benzoate (salt) No 12. ECOLOGICAL INFORMATION Environmental Fate Eco-Acute Toxicity The information presented here is for the active ingredient, emamectin benzoate. Low bioaccumulation potential. Persistent in soil. Stable in water. Immobile in soil. Sinks in water (after 24 h). Emamectin Benzoate: Emamectin Benzoate: Fish (Rainbow Trout) 96-hour LC50 174 ppb Green Algae 5-day EC50 > 3.9 ppb Invertebrate (Water Flea) Daphnia Magna 48-hour EC50 1.0 ppb Bird (Mallard Duck) 14-day LD50 46 mg/kg 13. DISPOSAL CONSIDERATIONS Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations. Characteristic Waste:Not Applicable Listed Waste:Not Applicable Disposal: Page 5 of 7 Safety Data Sheet 3/31/2017 4/12/2017 Replaces: Date: OPTIGARD® COCKROACH GEL BAIT 14. TRANSPORT INFORMATION DOT Classification Ground Transport - NAFTA Not regulated Comments Water Transport - International Proper Shipping Name: Environmentally Hazardous Substance, Solid, N.O.S. (Emamectin Benzoate), Marine Pollutant Hazard Class: Class 9 Identification Number: UN 3077 Packing Group: PG III Air Transport Proper Shipping Name: Environmentally Hazardous Substance, Solid, N.O.S. (Emamectin Benzoate) Hazard Class: Class 9 Identification Number: UN 3077 Packing Group: PG III 15. REGULATORY INFORMATION RCRA Hazardous Waste Classification (40 CFR 261): Not Applicable TSCA Status: Exempt from TSCA, subject to FIFRA EPCRA SARA Title III Classification: Section 311/312 Hazard Classes: Section 313 Toxic Chemicals: CERCLA/SARA 304 Reportable Quantity (RQ): None Pesticide Registration: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: EPA Registration Number(s): 100-1290 None Acute Health Hazard Caution: Causes moderate eye irritation. Avoid contact with eyes or clothing . Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco. Page 6 of 7 Safety Data Sheet 3/31/2017 4/12/2017 Replaces: Date: OPTIGARD® COCKROACH GEL BAIT 1 00 1 1 16. OTHER INFORMATION NFPA Hazard Ratings 5/18/2011 3/31/20174/12/2017 Health: Flammability: Instability: Replaces: Original Issued Date: Revision Date: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. HMIS Hazard Ratings Health: Flammability: Physical Hazard: 0 Minimal 1 Slight 2 Moderate 3 Serious 4 Extreme ASyngenta Hazard Category: 1-16Section(s) Revised: * Chronic 1 For non-emergency questions about this product call: 1-800-334-9481 Page 7 of 7 SAFETY DATA SHEET Issue Date: 17-Oct-2017 Revision Date: 17-Oct-2017 Version: 4 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name:VENDETTA® Plus Cockroach Gel Bait EPA Registration Number:1021-2593 Other means of identification Part Code:2976 Recommended use of the chemical and restrictions on use: Recommended Use:Insecticide. Details of the supplier of the safety data sheet Telephone Number:(800) 645-6466, or (763) 544-0341 e-Mail Address: mgk-sds@mgk.com Emergency telephone numbers: 24 Hour TRANSPORTATION Emergency: CHEMTREC®: (800) 424-9300 International:(703) 527-3887 24 Hour MEDICAL Emergency:SafetyCall®: (888) 740-8712, or (952) 852-9509 Comments:MGK® Hours of operation are 8:00 a.m. to 4:30 p.m. CST, 14:00 to 22:30 GMT. For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to (888) 740-8712, or (952) 852-9509. 2. HAZARDS IDENTIFICATION Environment: OSHA has not adopted the environmental - portion of the GHS regulations, however, this SDS may include information on environmental effects. Classification: OSHA Regulatory Status: This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Skin sensitization Category 1 Label elements Emergency Overview Manufacturer Address: McLaughlin Gormley King Company 8810 10th Avenue North Minneapolis, MN 55427 FAX #: (763) 544-6437 WARNING _____________________________________________________________________________________________ Page 1 / 9 Hazard statements • H317 - May cause an allergic skin reaction _____________________________________________________________________________________________ VENDETTA® Plus Cockroach Gel Bait Revision Date: 17-Oct-2017 Precautionary Statements - Prevention: P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves Precautionary Statements - Response: P321 - Specific treatment (see Section 4/ First Aid). P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P363 - Wash contaminated clothing before reuse Precautionary Statements - Storage: P404 - Store in a closed container Precautionary Statements - Disposal: P501 - Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC): Do not use this product in or on electrical equipment due to the possibility of shock hazard. 3. COMPOSITION/ INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Abamectin 71751-41-2 0.050 NYLAR® (Pyriproxyfen)95737-68-1 0.50 *The exact percentage (concentration) of composition has been withheld as a trade secret. Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications. 4. FIRST AID MEASURES Aspiration pneumonia hazard:• No information available Description of first aid measures: Eye contact:Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin Contact:Take off contaminated clothing. Rinse skin immediately with plenty of water for • H400 - Very toxic to aquatic life • H410 - Very toxic to aquatic life with long lasting effects Appearance: brown Physical state: Paste/Gel _____________________________________________________________________________________________ Page 2 / 9 Odor Odor of dog food. _____________________________________________________________________________________________ VENDETTA® Plus Cockroach Gel Bait Revision Date: 17-Oct-2017 15-20 minutes. Call a poison control centeror doctor for treatment advice. Ingestion:If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or a doctor. Never give anything by mouth to an unconscious person. Inhalation:Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Note to physicians:For skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroid exposure is topical application of tocopherol acetate (Vitamin E). 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media: Caution: Use of water spray when fighting fire may be inefficient. Hazardous combustion products: Carbon monoxide, Carbon dioxide (CO2). Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: None. Protective equipment and precautions for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Chronic Hazard Star Legend * = Chronic Health Hazard 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions:Use personal protective equipment as required. Environmental precautions:Prevent further leakage or spillage if safe to do so. Do not allow into any sewer, on the ground or into any body of water. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment:Prevent further leakage or spillage if safe to do so. Methods for cleaning up:Dam up. Soak up with inert absorbent material. Pick up and transfer to properly NFPA Health hazards 2 Flammability 1 Instability 0 Physical and Chemical Properties - HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection X _____________________________________________________________________________________________ Page 3 / 9 _____________________________________________________________________________________________ VENDETTA® Plus Cockroach Gel Bait Revision Date: 17-Oct-2017 labeled containers. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling:Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. For more information, see product label. Conditions for safe storage, including any incompatibilities Storage Conditions:Keep container tightly closed in a dry and well-ventilated place. For more information, see product label. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Control parameters Exposure Guidelines:This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Appropriate engineering controls Engineering Controls:Safety showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection:Protective eyewear is recommended, but is not required. Skin and body protection:Wear protective gloves and protective clothing. Respiratory protection:No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General Hygiene Considerations: When using do not eat, drink or smoke. Wash contaminated clothing before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties: Physical state:Paste/Gel Appearance:brown Odor Odor of dog food. Odor threshold:No information available Color (Gardner Scale):No information available Property: Values: Comment: • Method pH:5.1 @ 5% in H2O. . Melting point / freezing point:No information available Boiling point / boiling range:No information available Flash point:> 93.3 °C / > 200.0 °F Tag Closed Cup; _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ VENDETTA® Plus Cockroach Gel Bait Revision Date: 17-Oct-2017 Other Information: Density:1.36 g/cm3 @ 20.0 °C VOC Content (%):0.3 Miscibility/ Solubility: Water:Partially miscible Alcohol Partially miscible Aromatic solvents:Immiscible Petroleum distillates:Immiscible 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization:Hazardous polymerization does not occur. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials: Incompatible with strong acids and bases. Incompatible with oxidizing agents. Hazardous Decomposition Products Carbon monoxide, Carbon dioxide (CO2). 11. TOXICOLOGICAL INFORMATION Numerical measures of toxicity - Product Information Oral LD50 >5,000 mg/kg (rat) Dermal LD50 >5,000 mg/kg (rabbit) Inhalation LC50 No data required. Eye contact:Irritation clearing in 24 hours. (rabbit). Evaporation rate:No information available Flammability (solid, gas):No information available Upper flammability limit (UEL):No information available Lower flammability limit (LEL):No information available Vapor pressure:No information available Vapor density:No information available Specific Gravity:No information available Water solubility:No information available Partition coefficient; n-Octanol/ Water: No information available Autoignition temperature:No information available Decomposition temperature:No information available Kinematic viscosity:No information available Dynamic viscosity:3,450 cPs.@ 54.8 °C. . Refractive Index:No information available No data available _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ VENDETTA® Plus Cockroach Gel Bait Revision Date: 17-Oct-2017 Skin Contact:Non-irritating to the skin. (rabbit). Skin Irritation Index:0.1 Sensitization:Positive. (guinea pig). Comment:Toxicology data was bridged from a similar formula. Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Reproductive toxicity:No information available. Developmental Toxicity No information available. Teratogenicity:No information available. STOT - single exposure:No information available. STOT - repeated exposure:No information available. Target Organ Effects:Eyes, Respiratory system, Skin. 12. ECOLOGICAL INFORMATION Ecotoxicity: Persistence and degradability No information available. Bioaccumulation No information available. Other adverse effects: No information available Environmental hazards (EPA): Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes:Disposal should be in accordance with applicable regional, national and local laws and regulations. For more information, see product label. Contaminated packaging:For more information, see product label. 14. TRANSPORT INFORMATION DOT (Department of Transportation) Proper Shipping Name:Insecticides, Insect or Animal Repellent, Solid Hazard Class:This material is not hazardous. Air (IATA/ ICAO) Proper Shipping Name:Insecticides, Insect or Animal Repellent, Solid _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ VENDETTA® Plus Cockroach Gel Bait Revision Date: 17-Oct-2017 Hazard Class:This material is not hazardous. Vessel (IMO/ IMDG) Proper Shipping Name:Insecticides, Insect or Animal Repellent, Solid Hazard Class:This material is not hazardous. 15. REGULATORY INFORMATION US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations: California Proposition 65: This product does not contain any Proposition 65 chemicals U.S. EPA Label Information: EPA Registration Number: 1021-2593 Difference between SDS and EPA (FIFRA) Pesticide label: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals. The pesticide label also includes other important information, including directions for use. The hazard information required on the pesticide label is reproduced below: Signal word: CAUTION _____________________________________________________________________________________________ Page 7 / 9 Precautionary Statements: _____________________________________________________________________________________________ VENDETTA® Plus Cockroach Gel Bait Revision Date: 17-Oct-2017 • Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. International: TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Does not comply IECSC Does not comply KECL Does not comply PICCS Does not comply AICS Does not comply Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION. SDS Prepared By: Troy Azzivitto, MGK® Chemistry Department. e-Mail Address:mgk-sds@mgk.com Disclaimer: The information provided in this Safety Data Sheet (SDS) is provided in good faith and believed to be accurate at the time of preparation of the SDS. However, to the extent consistent with applicable law, MGK® and its subsidiaries or affiliates extend no warranties, make no representations, and assume no responsibility as to the accuracy, suitability, or completeness of such information. Additionally, to the extent consistent with applicable law, neither MGK® nor any of its subsidiaries or affiliates represents or guarantees that this information or product may be used without infringing the intellectual property rights of others. Except to the extent a particular use and particular information are expressly stated on the product label, it is the users’ own responsibility to determine the suitability of this information for their own particular use of this product. If necessary, contact MGK® to confirm that you have the most current product label and SDS. This Safety Data Sheet (SDS) serves different purposes than and DOES NOT REPLACE OR MODIFY THE EPA-APPROVED PRODUCT LABEL (attached to and accompanying the product container). This SDS provides important health, safety, and environmental information for employers, employees, emergency Issue Date: 17-Oct-2017 Revision Date: 17-Oct-2017 Revision Note: - SDS sections updated - 2 - 3 - 8 - 9 - 14 - 15 - 16 _____________________________________________________________________________________________ Page 8 / 9 _____________________________________________________________________________________________ VENDETTA® Plus Cockroach Gel Bait Revision Date: 17-Oct-2017 responders and others handling large quantities of the product in activities generally other than product use as required by the Occupational Health and Safety Act (29 CFR 1910.1200, “Hazcom”). The product label provides information specifically for product use in the ordinary course. Use, storage and disposal of pesticide products is regulated by the EPA under the authority of FIFRA through the product label. All necessary hazard classification and appropriate precautionary use, storage, and disposal information is set forth on that label or labeling accompanying the pesticide or to which reference is made on the label. It is a violation of federal law to use an EPA-registered pesticide product in any manner inconsistent with its labeling. End of Safety Data Sheet. _____________________________________________________________________________________________ Page 9 / 9 Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 1/12 Version: 4.0 (30599963/SDS_CPA_US/EN) 1. Identification Product identifier used on the label PT WASP-FREEZE II WASP & HORNET INSECTICIDE Recommended use of the chemical and restriction on use Recommended use*: insecticide * The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA Telephone: +1 973 245-6000 Emergency telephone number CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP (4357) Other means of identification Substance number: 597802 EPA Registration number: 499-550 Synonyms: Prallethrin 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Classification of the product Asp. Tox. 1 Aspiration hazard Label elements Pictogram: Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 2/12 Version: 4.0 (30599963/SDS_CPA_US/EN) Signal Word: Danger Hazard Statement: H304 May be fatal if swallowed and enters airways. Precautionary Statements (Response): P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 Do NOT induce vomiting. Precautionary Statements (Storage): P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Weight %Chemical name 23031-36-9 0.1 % Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1- propen-1-yl)-, 2-methyl-4-oxo-3-(2-propyn-1-yl)-2- cyclopenten-1-yl ester 64742-47-8 75.0 - 100.0% Distillates, petroleum 124-38-9 3.0 - 5.0% carbon dioxide 4. First-Aid Measures Description of first aid measures General advice: First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Immediately remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air, seek medical attention. If on skin: Immediately wash thoroughly with soap and water, seek medical attention. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 3/12 Version: 4.0 (30599963/SDS_CPA_US/EN) If swallowed: Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention. Do not induce vomiting due to aspiration hazard. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, dry powder, foam, carbon dioxide Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon monoxide, carbon dioxide, nitrogen oxides The substances/groups of substances mentioned can be released in case of fire. Aerosol container contains flammable gas under pressure. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Keep containers cool by spraying with water if exposed to fire. In case of fire and/or explosion do not breathe fumes. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. A spill of or in excess of the reportable quantity requires notification to state, local and national emergency authorities. This product is not regulated by CERCLA ('Superfund'). Methods and material for containment and cleaning up Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 4/12 Version: 4.0 (30599963/SDS_CPA_US/EN) Dike spillage. Pick up with suitable absorbent material. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal. 7. Handling and Storage Precautions for safe handling RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect against heat. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Provide means for controlling leaks and spills. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: Aerosol container contains flammable gas under pressure. The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition. Conditions for safe storage, including any incompatibilities Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Segregate from foods and animal feeds. Further information on storage conditions: Protect from direct sunlight. Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. Storage stability: May be kept indefinitely if stored properly. If an expiry date is mentioned on the packaging/label this takes priority over the statements on storage duration in this safety data sheet. Protect from temperatures above: 130 °F Explosive at or above indicated temperature. 8. Exposure Controls/Personal Protection Users of a pesticidal product should refer to the product label for personal protective equipment requirements. Components with occupational exposure limits carbon dioxide OSHA PEL PEL 5,000 ppm 9,000 mg/m3 ; STEL value 30,000 ppm 54,000 mg/m3 ; TWA value 10,000 ppm 18,000 mg/m3 ; ACGIH TLV STEL value 30,000 ppm ; TWA value 5,000 ppm ; Distillates, petroleum Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 5/12 Version: 4.0 (30599963/SDS_CPA_US/EN) ACGIH TLV TWA value 200 mg/m3 Non-aerosol (total hydrocarbon vapor); Application restricted to conditions in which there are negligible aerosol exposures. Skin Designation Non-aerosol (total hydrocarbon vapor); The substance can be absorbed through the skin. Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment. Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS: Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Store work clothing separately. Keep away from food, drink and animal feeding stuffs. 9. Physical and Chemical Properties Form: aerosol Odour: characteristic, of petroleum distillate (e.g. gasoline, kerosene) Odour threshold: Not determined due to potential health hazard by inhalation. Colour: colourless pH value: approx. 4.5 - 6.5 ( 23.7 °C) Melting point: < -30 °C Information applies to the solvent. Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 6/12 Version: 4.0 (30599963/SDS_CPA_US/EN) Boiling point: approx. 193 - 245 °C Information applies to the solvent. Flash point: 73 °C Information applies to the solvent. Flammability of Aerosol Products: > 18 in no flashback (ASTM D 3065) NFPA 30B flammability: Level 3 Aerosol Lower explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Upper explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. Autoignition: 220 - 250 °C Information applies to the solvent. Vapour pressure: approx. 0.19 - 0.25 hPa ( 20 °C) Information applies to the solvent. Density: approx. 0.8 g/cm3 ( 20 °C) Vapour density: not applicable Partitioning coefficient n- octanol/water (log Pow): approx. 4.49 ( 25 °C) The values mentioned are those of the active ingredient. Thermal decomposition: carbon monoxide, carbon dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat. No decomposition if stored and handled as prescribed/indicated. Viscosity, dynamic: approx. 2.32 cps ( 21.6 °C) Solubility in water: dispersible Evaporation rate: not applicable Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: not fire-propagating Chemical stability The product is stable if stored and handled as prescribed/indicated. Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 7/12 Version: 4.0 (30599963/SDS_CPA_US/EN) Possibility of hazardous reactions The product is chemically stable. No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures. Incompatible materials strong oxidizing agents, alkali or alkaline-earth metal strong acids, strong bases, strong oxidizing agents Hazardous decomposition products Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat. No decomposition if stored and handled as prescribed/indicated. 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Relatively nontoxic after single ingestion. Relatively nontoxic after short-term skin contact. Relatively nontoxic after short-term inhalation. Virtually nontoxic by inhalation. Virtually nontoxic after a single skin contact. Virtually nontoxic after a single ingestion. Oral Type of value: LD50 Species: rat (female) Value: > 5,000 mg/kg Inhalation Type of value: LC50 Species: rat (male/female) Value: > 2.08 mg/l Exposure time: 4 h Dermal Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 8/12 Version: 4.0 (30599963/SDS_CPA_US/EN) Type of value: LD50 Species: rat (male/female) Value: > 5,000 mg/kg Assessment other acute effects Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. The product has not been tested. The statement has been derived from the properties of the individual components. Irritation / corrosion Assessment of irritating effects: May cause slight but temporary irritation to the eyes. May cause moderate irritation to the skin. Skin Species: rabbit Result: Irritant. Eye Species: rabbit Result: non-irritant Sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. There is no evidence of a skin-sensitizing potential. Buehler test Species: guinea pig Result: Skin sensitizing effects were not observed in animal studies. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: carbon dioxide Assessment of repeated dose toxicity: The substance may cause damage to the lung after repeated inhalation of high doses. The substance may cause damage to the heart after repeated inhalation of high doses, as shown in animal studies. ---------------------------------- Genetic toxicity Assessment of mutagenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Mutagenicity tests revealed no genotoxic potential. Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect. Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 9/12 Version: 4.0 (30599963/SDS_CPA_US/EN) Teratogenicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: carbon dioxide Assessment of teratogenicity: The potential to cause toxicity to development cannot be excluded at maternally toxic doses. ---------------------------------- Other Information Misuse can be harmful to health. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Toxic to aquatic life with long lasting effects. The product has not been tested. The statement has been derived from the properties of the individual components. Toxicity to fish Information on: Prallethrin LC50 (96 h) 0.012 mg/l, Oncorhynchus mykiss The ecological data given are those of the active ingredient. ---------------------------------- Aquatic invertebrates Information on: Prallethrin EC50 (48 h) 0.0062 mg/l, daphnia ---------------------------------- Aquatic plants Information on: Prallethrin EC50 (72 h) 2 mg/l, algae ---------------------------------- Persistence and degradability Assessment biodegradation and elimination (H2O) The product has not been tested. The statement has been derived from the properties of the individual components. Assessment biodegradation and elimination (H2O) Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 10/12 Version: 4.0 (30599963/SDS_CPA_US/EN) Information on: Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, 2-methyl-4- oxo-3-(2-propyn-1-yl)-2-cyclopenten-1-yl ester Not readily biodegradable (by OECD criteria). ---------------------------------- Bioaccumulative potential Assessment bioaccumulation potential The product has not been tested. The statement has been derived from the properties of the individual components. Assessment bioaccumulation potential Information on: Prallethrin Information on: Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, <2% aromatics Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is possible. Accumulation in organisms is expected. ---------------------------------- Mobility in soil Assessment transport between environmental compartments No data available. Additional information Other ecotoxicological advice: Do not discharge product into the environment without control. 13. Disposal considerations Waste disposal of substance: Pesticide wastes are regulated. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container disposal: Do not cut, puncture, crush, or incinerate empty aerosol containers. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Empty aerosol cans may meet the definition of RCRA D003. Consult local and/or regional EPA for further guidance. 14. Transport Information Land transport USDOT Hazard class: 2.1 ID number: UN 1950 Hazard label: 2.1 Proper shipping name: AEROSOLS Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 11/12 Version: 4.0 (30599963/SDS_CPA_US/EN) Sea transport IMDG Hazard class: 2.1 ID number: UN 1950 Hazard label: 2.1, EHSM Marine pollutant: YES Proper shipping name: AEROSOLS (contains HYDROTREATED LIGHT DISTILLATES (PETROLEUM), PRALLETHRIN) Air transport IATA/ICAO Hazard class: 2.1 ID number: UN 1950 Hazard label: 2.1 Proper shipping name: AEROSOLS, FLAMMABLE Further information DOT: This product may be classified as ORM-D (Consumer Commodity) or Limited Quantity. After 12/31/2020, ORM-D will not apply. 15. Regulatory Information Federal Regulations Registration status: Chemical TSCA, US blocked / not listed Crop Protection TSCA, US released / exempt EPCRA 311/312 (Hazard categories): Acute; Chronic; Fire; Sudden release of pressure State regulations State RTK CAS Number Chemical name PA 124-38-9 64742-47-8 carbon dioxide Distillates, petroleum MA 64742-47-8 124-38-9 Distillates, petroleum carbon dioxide NJ 124-38-9 64742-47-8 carbon dioxide Distillates, petroleum Labeling requirements under FIFRA This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label. CAUTION: KEEP OUT OF REACH OF CHILDREN. May cause moderate but temporary irritation to the eyes. Avoid contact with the skin, eyes and clothing. Safety Data Sheet PT WASP-FREEZE II WASP & HORNET INSECTICIDE Revision date : 2017/06/19 Page: 12/12 Version: 4.0 (30599963/SDS_CPA_US/EN) Wash thoroughly after handling. Aerosol container contains flammable gas under pressure. Flammable Liquid 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2017/06/19 We support worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET Zoecon Zenprox EC Safety Data Sheet Date of issue: 11/25/2015 Revision date: 12/08/2017 12/08/2017 EN (English US)Page 1 SECTION 1: Identification 1.1.Identification Product form :Mixture Trade name :Zoecon Zenprox EC Synonyms :100506231,100532780, EPA Reg. No.: 2724-804, RF2129EC 1.2.Recommended use and restrictions on use Recommended use :Insecticide. Restrictions on use :Avoid contact with skin and eyes. Keep out of reach of children. Do NOT take internally. 1.3.Supplier Wellmark International 1501 E. Woodfield Road, Suite 200W Schaumburg, IL 60173 - United States www.zoecon.com 1.4.Emergency telephone number 1-800-248-7763Emergency number : 1-800-424-9300 - CHEMTREC 1-703-527-3887 - CHEMTREC - Outside North America - Collect Calls Accepted SECTION 2: Hazard(s) identification 2.1.Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 2 Causes skin irritation Serious eye damage/eye irritation Category 2B Causes eye irritation Acute toxicity (oral) Category 4 Harmful if swallowed 2.2.GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US): GHS07 Signal word (GHS-US):Warning Hazard statements (GHS-US):Harmful if swallowed Causes skin irritation Causes eye irritation Precautionary statements (GHS-US):Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: Call a poison center or doctor if you feel unwell If on skin: Wash with plenty of water If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Dispose of contents/container to in accordance with local/regional/national/international regulations 2.3.Other hazards which do not result in classification Other hazards not contributing to the classification :Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Zoecon Zenprox EC Safety Data Sheet 12/08/2017 EN (English US)2/6 2.4.Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1.Substances Not applicable 3.2.Mixtures Name Product identifier % Etofenprox (CAS-No.) 80844-07-1 16.2 Piperonyl butoxide (CAS-No.) 51-03-6 64.8 2-ethyl hexanol (CAS-No.) 104-76-7 2.31 - 2.97 Other ingredients (CAS-No.) N/A Balance SECTION 4: First-aid measures 4.1.Description of first aid measures First-aid measures general :Call a poison center/doctor/physician if you feel unwell. First-aid measures after inhalation :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact :IF ON SKIN: Wash with plenty of soap and water. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice and attention. First-aid measures after ingestion :IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Call a poison center/doctor/physician if you feel unwell. Do NOT induce vomiting unless directed to do so by medical personnel. 4.2.Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact :Causes skin irritation. Symptoms/effects after eye contact :Mild eye irritation. Symptoms/effects after ingestion :Harmful if swallowed. 4.3.Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1.Suitable (and unsuitable) extinguishing media Suitable extinguishing media :Water spray. Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media :Avoid heavy hose streams. 5.2.Specific hazards arising from the chemical Reactivity :The product is non-reactive under normal conditions of use, storage and transport. 5.3.Special protective equipment and precautions for fire-fighters Protection during firefighting :Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1.Personal precautions, protective equipment and emergency procedures 6.1.1.For non-emergency personnel Emergency procedures :Ventilate spillage area. Avoid contact with skin and eyes. 6.1.2.For emergency responders Protective equipment :Do not attempt to take action without suitable protective equipment. For further information refer to section 8: Exposure controls/personal protection. Emergency procedures :Evacuate unnecessary personnel. Stop leak if safe to do so. Ventilate area. 6.2.Environmental precautions Avoid release to the environment. 6.3.Methods and material for containment and cleaning up Methods for cleaning up :Absorb spills with an inert material, clay granules or other inert absorbent material and put in container for disposal. Wear appropriate personal protective equipment, avoid direct contact. Zoecon Zenprox EC Safety Data Sheet 12/08/2017 EN (English US)3/6 SECTION 7: Handling and storage 7.1.Precautions for safe handling Precautions for safe handling :Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. Hygiene measures :Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2.Conditions for safe storage, including any incompatibilities Storage conditions :Store in a well-ventilated place. Keep cool. Keep container tightly closed. Keep only in original container. Keep from freezing. Do not store near heat or open flame. Incompatible materials :Strong oxidizers. SECTION 8: Exposure controls/personal protection 8.1.Control parameters No additional information available 8.2.Appropriate engineering controls Appropriate engineering controls :Adequate ventilation systems as needed to control concentrations of airborne contaminants below applicable threshold limit values. Environmental exposure controls :Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. 8.3.Individual protection measures/Personal protective equipment Hand protection: Protective gloves Eye protection: Chemical goggles or face shield Skin and body protection: It is recommended for handlers to wear appropriate clothing to prevent skin contact including long sleeves, long pants, socks and shoes. Respiratory protection: In case of insufficient ventilation, use NIOSH approved respiratory protection. SECTION 9: Physical and chemical properties 9.1.Information on basic physical and chemical properties Physical state :Liquid Appearance :Straw-colored liquid Color :Straw-colored Odor :Faint petroleum Odor threshold :No data available pH :5.09 (25 °C) Melting point :Not applicable Freezing point :No data available Boiling point :No data available Flash point :112 °C PMCC (Pensky-Martins Closed Cup) Relative evaporation rate (butyl acetate=1):No data available Flammability (solid, gas):Not applicable Vapor pressure :No data available Zoecon Zenprox EC Safety Data Sheet 12/08/2017 EN (English US)4/6 Relative vapor density at 20 °C :No data available Relative density :1.03 (20 °C) Solubility :No data available Log Pow :No data available Auto-ignition temperature :No data available Decomposition temperature :No data available Viscosity, kinematic :No data available Viscosity, dynamic :< 100 cP (20 °C) Explosion limits :No data available Explosive properties :Not explosive Oxidizing properties :Not applicable 9.2.Other information No additional information available SECTION 10: Stability and reactivity 10.1.Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2.Chemical stability Stable under normal conditions. 10.3.Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4.Conditions to avoid Excessive heat and freezing conditions. Direct sunlight. 10.5.Incompatible materials Strong oxidizing agents. 10.6.Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. May decompose upon heating to produce toxic vapors which may include oxides of carbon. SECTION 11: Toxicological information 11.1.Information on toxicological effects Zoecon Zenprox EC LD50 oral rat 1750 mg/kg LD50 dermal rat > 5000 mg/kg LC50 inhalation rat (mg/l)> 2.07 mg/l/4h pH 5.09 (25 °C) GHS-US Properties Classification Acute toxicity Oral: Harmful if swallowed. Skin corrosion/irritation Causes skin irritation. Serious eye damage/irritation Causes eye irritation. Respiratory or skin sensitization Not classified Germ cells mutagen Not classified Carcinogenicity Not classified Reproductive toxicity Not classified Specific target organ toxicant (single exposure) Not classified Specific target organ toxicant (repeated exposure) Not classified Aspiration hazard Not classified Potential health effects Inhalation Acute :Under normal conditions of use, no health effects are expected. Zoecon Zenprox EC Safety Data Sheet 12/08/2017 EN (English US)5/6 Skin Acute :Causes skin irritation. Chronic :Prolonged and repeated exposure to Etofenprox can cause skin irritation. Eye Acute :Causes eye irritation. Ingestion Acute :Harmful if swallowed. Mutagenicity :Piperonyl butoxide was not mutagenic in a battery of tests, Etofenprox has been found negative for mutagenicity potential using the Ames test, chromosomal aberration and micronucleus test methods. Carcinogenicity :Piperonyl butoxide is not classified as carcinogen by NTP, IARC and OSHA, Etofenprox is not classified as carcinogen by NTP, IARC and OSHA. Reproductive Effects :Piperonyl butoxide did not produce any birth defects or adverse effects on reproductive parameters in tests with rats and rabbits, Etofenprox did not produce teratogenic or reproductive effects in laboratory experiments. SECTION 12: Ecological information 12.1.Toxicity Etofenprox (80844-07-1) LC50 Acute fish 1 0.0027 mg/l (Exposure time: 96h - Rainbow trout) LC50 Acute fish 2 > 0.0165 (Exposure time: 96h - Sheepshead minnow) LC50 Acute crustacea 1 0.0000188 mg/l (Exposure time: 96h - Mysid shrimp) LC50 Acute crustacea 2 0.0008 mg/l (Exposure time: 48 hours - Daphnia magna) NOEC Chronic crustacea 1 0.00017 mg/l (Daphnia magna) Piperonyl butoxide (51-03-6) LC50 Acute fish 1 1.9 mg/l (Exposure time: na - Rainbow trout) LC50 Acute fish 2 3.94 mg/l (Exposure time: na - Sheepshead minnow) LC50 Acute crustacea 1 0.49 mg/l (Exposure time: na - Mysid shrimp) LC50 Acute crustacea 2 0.51 mg/l (Exposure time: na - Gammarus fasciatus (amphipod)) NOEC Chronic fish 1 0.04 mg/l (Fathead minnow) NOEC Chronic crustacea 1 0.03 mg/l (Daphnia magna) 12.2.Persistence and degradability No additional information available 12.3.Bioaccumulative potential No additional information available 12.4.Mobility in soil No additional information available 12.5.Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1.Disposal methods Product/Packaging disposal recommendations :Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. SECTION 14: Transport information UN number Proper Shipping Name Transport hazard class(es) Packing group Environmental hazards DOT Not regulated Not regulated Not regulated Not regulated Not regulated IMDG UN3082 Packaging > 5L: Environmentally Hazardous Substance, Liquid, n.o.s. (Etofenprox, Piperonyl butoxide) 9 III Marine pollutant Zoecon Zenprox EC Safety Data Sheet 12/08/2017 EN (English US)6/6 IATA UN3082 Packaging > 5L: Environmentally Hazardous Substance, Liquid, n.o.s. (Etofenprox, Piperonyl butoxide) 9 III Acute aquatic toxicity SECTION 15: Regulatory information 15.1. US Federal regulations Piperonyl butoxide (51-03-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 SARA Section 313 - Emission Reporting 1 % 15.2. US State regulations No additional information available SECTION 16: Other information Date of issue :25 November 2015 Revision date :08 December 2017 SDS US (GHS HazCom 2012) - CGP The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. FIFRA Labelling EPA Registration Number 2724-804 This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. FIFRA Signal word Caution FIFRA Precautionary Statement KEEP OUT OF REACH OF CHILDREN. FIFRA Hazards to Humans and Domestic Animals Harmful if swallowed. Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Repeated exposure to etofenprox can cause skin irritation. FIFRA First Aid Call a poison control center or doctor immediately for treatment advice. If swallowed: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything mouth to an unconscious person. If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Trade Name: Contrac All-Weather Blox Date Created: February 2017 Supplier: Bell Laboratories, Inc. Page 1 of 4 CONTRAC®ALL-WEATHER BLOX SAFETY DATA SHEET ACCORDING TO REGULATION: OSHA Hazard Communication Standard 29 CFR 1910.1200 DATE OF ISSUE: February 2017 PREPARED BY: CAR SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier: CONTRAC® ALL-WEATHER BLOX EPA Registration Number: 12455-79 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Anticoagulant Rodenticide - Ready to use Uses advised against: Use only for the purpose described above MANUFACTURER/SUPPLIER: Bell Laboratories, Inc. 3699 Kinsman Blvd. Madison, WI 53704, USA Email: sds@belllabs.com Phone: 608-241-0202 Medical or Vet Emergency: 877-854-2494 or 952-852-4636 Spill or Transportation Emergency: 800-424-9300 (CHEMTREC) SECTION 2. HAZARDS IDENTIFICATION Classification according to Regulation OSHA 1910.1200(d): Not classified Signal Word: None See Section 15 for information on FIFRA applicable safety, health, and environmental classifications. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. % By weight Bromadiolone [3-[3-(4’-Bromo-[1,1’-biphenyl]-4-yl)-3-hydroxy-1- phenylpropyl]-4-hydroxy-2H-1-benzopyran-2-one] 28772-56-7 0.005% Inert and Non-Hazardous Ingredients (Unlisted components are non-hazardous) Proprietary 99.995% SECTION 4. FIRST AID MEASURES Description of first aid measures Ingestion: Call physician or emergency number immediately. Have person sip a glass of water if able to swallow. Do not induce vomiting unless instructed by physician. Inhalation: Not applicable. Eye contact: Hold eye open and rinse slowly with water for 15 – 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If irritation develops, obtain medical assistance. Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 - 20 minutes. If irritation develops, obtain medical assistance. Most important symptoms and effects, both acute and delayed Ingestion of excessive quantities may cause nausea, vomiting, loss of appetite, extreme thirst, lethargy, diarrhea, bleeding. Advice to physician: If ingested, administer Vitamin K1 intramuscularly or orally as indicated for bishydroxycoumarin overdoses. Repeat as necessary as based upon monitoring of prothrombin times. Advice to Veterinarian: For animals ingesting bait and/or showing poisoning signs (bleeding or elevated prothrombin times), give Vitamin K1. If needed, check prothrombin times every 3 days until values return to normal (up to 30 days). In severe cases, blood transfusions may be needed. Trade Name: Contrac All-Weather Blox Date Created: February 2017 Supplier: Bell Laboratories, Inc. Page 2 of 4 SECTION 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Extinguishing Media: water, foam or inert gas. Unsuitable Extinguishing Media: None known. Special hazards arising from the mixture: High temperature decomposition or burning in air can result in the formation of toxic gases, which may include carbon monoxide and traces of bromine and hydrogen bromide. Advice for firefighters: Wear protective clothing and self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Gloves should be worn when handling the bait. Collect spillage without creating dust. Environmental precautions: Do not allow bait to enter drains or water courses. Where there is contamination of streams, rivers or lakes contact the appropriate environment agency. Methods and materials for containment and cleaning up For Containment: Sweep up spilled material immediately. Place in properly labeled container for disposal or re-use. For Cleaning Up: Wash contaminated surfaces with detergent. Dispose of all wastes in accordance with all local, regional and national regulations. Reference to other sections: Refer to Sections 7, 8 & 13 for further details of personal precautions, personal protective equipment and disposal considerations. SECTION 7. HANDLING AND STORAGE Precautions for safe handling: Do not handle the product near food, animal foodstuffs or drinking water. Keep out of reach of children. Do not use near heat sources, open flame, or hot surfaces. As soon as possible, wash hands thoroughly after applying bait and before eating, drinking, chewing gum, using tobacco, or using the toilet. Conditions for safe storage, including any incompatibilities: Store only in original container in a cool, dry place, inaccessible to pets and wildlife. Do not contaminate water, food or feed by storage or disposal. Keep containers closed and away from other chemicals. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Established Limits Component OSHA ACGIH Other Limits Bromadiolone Not Established Not Established Not Established Appropriate Engineering Controls: Not required Occupational exposure limits: Not established Personal Protective Equipment: Respiratory protection: Not required Eye protection: Not required Skin protection: Shoes plus socks, and waterproof gloves. Hygiene recommendations: Wash thoroughly with soap and water after handling. Trade Name: Contrac All-Weather Blox Date Created: February 2017 Supplier: Bell Laboratories, Inc. Page 3 of 4 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance/Color: Blue wax block Odor: Sweet grain-like Odor Threshold: No Data pH: No Data Melting point: No Data Boiling point: No Data Flash point: No Data Evaporation rate: No Data Flammability: No Data Upper/lower flammability or explosive limits: No Data Vapor Pressure: Vapor Density: No Data No Data Relative Density: 1.13 g/mL @ 20°C Solubility (water): Negligible Solubility (solvents): No Data Partition coefficient: n-octanol/water: No Data Auto-ignition temperature: No Data Decomposition temperature: No Data Viscosity: No Data SECTION 10. STABILITY AND REACTIVITY Reactivity: Stable when stored in original container in a cool, dry location. Chemical stability: Stable when stored in original container in a cool, dry location. Possibility of hazardous reactions: Refer to Hazardous decomposition products Conditions to avoid: Avoid extreme temperatures (below 0°C or above 40°C). Incompatible materials: Avoid strongly alkaline materials. Hazardous decomposition products: High temperature decomposition or burning in air can result in the formation of toxic gases, which may include carbon monoxide and traces of bromine and hydrogen bromide. SECTION 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity LD50, oral (ingestion): >5000 mg/kg (rats) (Bromadiolone Rat LD50 oral: 0.70 mg/kg bw). LD50, dermal (skin contact): > 5001 mg/kg (rats) (Bromadiolone rabbit LD50 dermal: 1.71 mg/kg bw). LC50, inhalation: Product is a wax block and therefore exposure by inhalation is not relevant. Skin corrosion/irritation: Not irritating to skin. Serious eye damage/Irritation: Not irritating to eyes. Respiratory or skin sensitization: Dermal sensitization: Not a Sensitizer (Guinea pig maximization test). Germ cell mutagenicity: Contains no components known to have a mutagenetic effect. Carcinogenicity: Contains no components known to have a carcinogenetic effect. Components NTP IARC OSHA Bromadiolone Not listed Not listed Not listed Reproductive Toxicity: No data Aspiration Hazard: Not applicable. Product is a wax block. Target Organ Effects: Reduced blood clotting ability. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Effects: This product is extremely toxic to fish, birds and other wildlife. Dogs and predatory and scavenging mammals and birds might be poisoned if they feed upon animals that have eaten this bait. Do not apply this product directly to water or to areas where surface water is present or to intertidal areas below the mean high water mark. Runoff also may be hazardous to aquatic organisms in water adjacent to treated areas. Do not contaminate water when disposing of equipment wash water or rinsate. Persistence and degradability: Product is inherently biodegradable. Bioaccumulative potential: Not determined. Bromadiolone water solubility is extremely low (< 0.1mg/l). Mobility in Soil: Not determined. Mobility of bromadiolone in soil is considered to be limited. Other adverse effects: None. Trade Name: Contrac All-Weather Blox Date Created: February 2017 Supplier: Bell Laboratories, Inc. Page 4 of 4 SECTION 13. DISPOSAL CONSIDERATIONS Do not contaminate water, food or feed by storage or disposal. Pesticide Storage: Store only in original container in a cool, dry place inaccessible to children and pets. Keep containers closed and away from other chemicals. Pesticide Disposal: Wastes resulting from the use of this product may be placed in trash or delivered to an approved waste disposal facility. All wastes must be disposed of as specified on the product label. State and local regulations may affect the disposal of this product. Container Handling: Non-refillable container. Do not reuse or refill this container. [Plastic:] Offer for recycling or reconditioning; or puncture and dispose of in a sanitary landfill; or by incineration. In most states, burning is not allowed. [Paper:] Dispose of empty container by placing in trash, at an approved waste disposal facility or by incineration. In most states, burning is not allowed. RCRA Waste Status: This product is not regulated as a hazardous waste under Federal law. SECTION 14. TRANSPORT INFORMATION UN number: Not regulated UN proper shipping name: Not regulated Transport hazard class(es): Not regulated Packing group : Not regulated Environmental Hazards DOT Road/Rail: Not considered hazardous for transportation via road/rail. DOT Maritime: Not considered hazardous for transportation by vessel. DOT Air: Not considered hazardous for transportation by air. Freight Classification: LTL Class 60 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable Special precautions for user: None SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: FIFRA: This pesticide product is regulated by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The safety, health, environmental, and hazard information required on the pesticide label is listed below and reflected throughout this SDS. The pesticide label also includes other important information, including directions for use. Signal Word: CAUTION Precautionary Statements: Contains the anticoagulant Bromadiolone which may cause bleeding if ingested. Harmful if swallowed or absorbed through the skin. Keep away from children, domestic animals and pets. Do not get in eyes, on skin or on clothing. Potential Health Effects: Eye Contact: May cause irritation Skin Contact: Non-irritating to the skin Ingestion: Harmful if swallowed TSCA: All components are listed on the TSCA Inventory or are not subject to TSCA requirements CERCLA/SARA 313: Not listed CERCLA/SARA 302: Not listed SECTION 16. OTHER INFORMATION For additional information, please contact the manufacturer noted in Section 1. NFPA Health: 1 (caution) Flammability: 1 (slight) Reactivity: 0 (stable) Specific Hazard: None HMIS Health: 2 (moderate) Flammability: 1 (slight) Reactivity: 0 (minimal) Protective Equipment: B Disclaimer: The information provided in this Safety Data Sheet has been obtained from sources believed to be reliable. Bell Laboratories, Inc. provides no warranties; either expressed or implied, and assumes no responsibility for the accuracy or completeness of the data contained herein. This information is offered for your consideration and investigation. 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