Agenda 02/25/2020 Item #16A21 (Expenditures for Florida International University)02/25/2020
EXECUTIVE SUMMARY
Recommendation to authorize expenditures through an exemption from the competitive process for
Florida International University for sampling, analysis and assessment of sediment and water
quality for Fiscal Year 2020.
OBJECTIVE: To provide continued sediment monitoring and assessment for Collier County waterways
and provide additional analysis for source tracking of wastewater pollutants in surface water.
CONSIDERATION: Florida International University has collected, analyzed, and assessed sediment
samples (“Sediment Study”) in Collier County waterways every five years beginning in 2002. This
Sediment Study will continue the County’s long-term monitoring efforts of the sediments in Collier
County. This monitoring is used to determine chronic pollutant loads to the waterways. It includes data
assessment with comparisons to established sediment standards/guidelines and comparisons to previous
sediment studies to measure the effectiveness of best management practices. This study costs $40,000.
Starting in fiscal year 2020, staff has added sucralose testing to the ambient surface water quality
monitoring program. Sucralose, an artificial sweetener, is ideal for tracing wastewater impacts (nutrients)
in surface because it does not naturally occur in the environment. Sucralose is not metabolized by the
body or removed by the wastewater treatment process. It is highly soluble and remains persistent in the
environment for up to three years. This makes sucralose ideal for tracing wastewater impa cts (nutrients)
in surface and groundwater. This will establish baseline data in surface water for wastewater impacts.
These sucralose laboratory analyses cost approximately $15,000 annually.
Section 8.1 of the Collier County Procurement Ordinance 2017-08, as amended, provides that purchases
from another government agency or from a nonprofit organization authorized to do business in the State
of Florida are eligible for exemption from the competitive process based upon the lack of available
competition and a determination that such an exemption is in the best interest of the County. The
approved exemption form is attached. Staff requests that the Board approve this expenditure for the
Sediment Study from Florida International University as an exemption under the Procurement Ordinance.
FISCAL IMPACT: Funding is available in the Water Pollution Control Fund (114), and consistent with,
the FY2020 Budget approved by the Board on September 19, 2019. Typically, the Sediment Study is
conducted with a budget of $40,000, well under $50,000 that requires Board approval. However, with the
addition of annual sucralose analysis, once every five years, the total cost will be $55,000 for this vendor
and therefore requires Board approval.
LEGAL CONSIDERATIONS: This item is approved as to form and legality and requires majority
vote for Board approval. -SRT
GROWTH MANAGEMENT IMPACT: This project complies with and is consistent with the
requirements of the Conservation and Coastal Management Element Objective 2.3.
RECOMMENDATION: To authorize expenditures through an exemption from the competitive process
for Florida International University to provide sucralose laboratory analyses and/or sampling, analytical
and assessment of sediment and water quality for Fiscal Year 2020.
Prepared By: Rhonda J. Watkins, Senior Operations Analyst, Capital Project Planning, Impact Fees &
Program Management Division
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02/25/2020
ATTACHMENT(S)
1. FY19 Exemption Request 166 - FL International University (PDF)
2. FY20 Exemption Request 146 - FL International University (PDF)
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02/25/2020
COLLIER COUNTY
Board of County Commissioners
Item Number: 16.A.21
Doc ID: 11430
Item Summary: Recommendation to authorize expenditures through an exemption from the
competitive process for Florida International University for sampling, analysis and assessment of
sediment and water quality for Fiscal Year 2020.
Meeting Date: 02/25/2020
Prepared by:
Title: Manager - Pollution Control – Capital Project Planning, Impact Fees, and Program Management
Name: Danette Kinaszczuk
01/22/2020 11:01 AM
Submitted by:
Title: Division Director - IF, CPP & PM – Capital Project Planning, Impact Fees, and Program
Management
Name: Amy Patterson
01/22/2020 11:01 AM
Approved By:
Review:
Growth Management Department Judy Puig Deputy Department Head Review Skipped 01/23/2020 1:04 PM
Procurement Services Opal Vann Level 1 Purchasing Gatekeeper Completed 01/22/2020 4:24 PM
Growth Management Department Judy Puig Level 1 Reviewer Completed 01/23/2020 1:04 PM
Procurement Services Sandra Herrera Additional Reviewer Completed 01/27/2020 12:38 PM
Procurement Services Sara Schneeberger Additional Reviewer Completed 01/29/2020 10:41 AM
Capital Project Planning, Impact Fees, and Program Management Amy Patterson Additional Reviewer Completed 02/03/2020 2:11 PM
Procurement Services Catherine Bigelow Additional Reviewer Completed 02/07/2020 11:56 AM
Growth Management Department Thaddeus Cohen Department Head Review Completed 02/07/2020 4:30 PM
County Attorney's Office Scott Teach Level 2 Attorney Review Completed 02/10/2020 2:29 PM
Office of Management and Budget Debra Windsor Level 3 OMB Gatekeeper Review Completed 02/10/2020 2:49 PM
County Attorney's Office Jeffrey A. Klatzkow Level 3 County Attorney's Office Review Completed 02/10/2020 3:40 PM
Office of Management and Budget Laura Zautcke Additional Reviewer Completed 02/10/2020 4:26 PM
Office of Management and Budget Susan Usher Additional Reviewer Completed 02/18/2020 3:22 PM
County Manager's Office Leo E. Ochs Level 4 County Manager Review Completed 02/18/2020 4:02 PM
Board of County Commissioners MaryJo Brock Meeting Pending 02/25/2020 9:00 AM
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Instructions
The following procurement categories may be eligible for exemption from the competitive process based upon the determination
of the County manager or Designee that approval of such an exemption is in the best interest of the County.
Purchases greater than $50,000 will require final approval by the Board of County Commissioners.
Requester Name:Vendor Name:
Division:Item / Service:
Budget Year:1RWWR([FHHG
per Fiscal Year:
One time purchase:Multiple purchases:Requested
date range:_________________
Is there an agreement
associated with this
Exemption?
Yes No
1. Government Agency/Non-
Profit
2. Registrations/dues/
training
3. Subscriptions/periodicals/
printed materials
4. Advertisements
5. Utility services –subject
to government control
6. Education/academic
programs/trainers, speakers
7. Legal services 8. Purchases required by
grants/gifts
9.Compatibility/proprietary
with current systems
10. Shop estimates on
disassembled equipment
11. Personnel/recruitment
services
2. Works of art for public
display
13. Direct purchases 14. Financial instruments 15. Entertainment services
for County sponsored events
16. Management studies as
directed by County Manager
17. Resolution/BCC direction (Indicate resolution number and approval date):
Description of Purchase:Enter a description of the item(s) items that will be purchased under this exemption.
Purpose:Describe in detail, the purpose of the requested item(s).
Requester:Signature: Date:
Division Director: Signature: Date:
Procurement Strategist: Signature: Date:
Procurement Director:
2UGHVLJQHH
Signature: Date:
For Procurement Use Only:
One time approval One year approval Multi-Year Approval: Start ____________ End ____________
Exemptions from the Competitive Process
Rhonda Watkins Florida International University
Pollution Control Sediment Study
FY19-FY20 $40,000
07/01/19 - 09/30/20
Personnel costs and testing supplies, as well as final report
This sediment study will continue the County's effort to conduct longterm
monitoring of the sediments in Collier County. This monitoring occurs every 5 years
and is used to determine chronic pollutant loads to the waterways. This project will
include sample collection, data assessment and final report. These sites include historic
sites that have previously shown an exceedance of published sediment guidelines or
criteria. Sentinel sites are also included to continue the long term monitoring.The
requested funds ($40,000.00) include all aspects of sample collection, data reduction,
data interpretation and report generation.
Rhonda Watkins 7/3/2019
Amy Patterson
Sara Schneeberger
Catherine Bigelow
07/10/2019 09/30/2020
watkins_r Digitally signed by watkins_r
Date: 2019.07.03 13:08:44
-04'00'
Amy Patterson Digitally signed by Amy Patterson
Date: 2019.07.03 13:12:59 -04'00'
SchneebergerSara Digitally signed by
SchneebergerSara
Date: 2019.07.10 10:36:02 -04'00'
Cat Bigelow Digitally signed by Cat Bigelow
DN: cn=Cat Bigelow, o=Collier County
Government, ou=Procurement Services,
email=catherinebigelow@colliergov.net, c=US
Date: 2019.07.10 10:54:18 -04'00'
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Packet Pg. 1437 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
PROVIDING CONTAMINANT DATA FOR CONTINUED COASTAL MANAGEMENT:
ASSESSING THE EFFECTS OF LAND BASED SOURCES OF POLLUTION ON
COLLIER COUNTY’S WATERSHED SEDIMENTS
A proposal submitted to Collier County Pollution Control, Florida
June 15, 2019
Piero R. Gardinali, and Henry Briceño
Southeast Environmental Research Center (SERC)
Institute of Water and Environment (InWE)
Florida International University
University Park Campus
Miami, Florida 33199
In collaboration with
Pace Analytical Services
8021-6 Phillips Highway
Jacksonville, Fl 32256
Justification and Project Rationale
Appropriate management of near coastal environments and their associated watersheds
requires a careful balance between economic grow, urban development, land usage,
sustainability and resilience. Collier county watersheds (Figure 1) are influenced by
several key activities; urban development is considered a good indicator of economic
success while agriculture is still one of the major economic drivers in Southwest Florida.
In addition, restoration efforts along the Picayune Strand have or will change the water
delivery mechanisms along the Faka Union and Fakahatchee Strand watersheds. The
effects of these unique but interconnected activities may influence coastal areas in
different ways by introducing land-based sources of pollution. For example, releases of
pesticides from urban and commercial horticulture, upkeep of recreational landscape,
storm water runoff, and human derived wastewater are among the myriad of process that
contribute to the emissions of potential contaminants to Collier County’s coastal
management zones. Data summarized and generated by our previous assessment of
Collier County major watersheds revealed the existence of environmental conditions
requiring opposite courses of action for management purposes, this proposal is based on
two different key objectives; provide continued, long-term assessment of the quality of
sediments in areas where previous monitoring have showed no environmental
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degradation and increase the regional and or temporal assessment of sites that showed
impairment or that may be affected by modification of land-uses. To that extent, this
survey will collect and analyze sediments from 57 sites distributed along the main
watershed basins along Collier County. The sampling strategy includes 40 sentinel sites
established in previous surveys 2002-2014, 10 sites introduced in 2014 to address
specific sources of Copper and 7 new sites added in 2019 to extend the regional coverage
or address connections along specific water bodies. The list of parameters measured will
remain the same as the ones monitored in 2014 but specific effort will be devoted to reach
method detection limits that are relevant pristine overall environmental conditions. The
target pollutants include toxic heavy metals, legacy chlorinated pesticides, a
comprehensive list of contemporary organophosphate and organo-nitrogen pesticides
and herbicides and the 16 priority poly-aromatic hydrocarbons. In addition, ancillary
parameters related to eutrophication and accumulation of organic matter will be measured
to provide an overall assessment of the sediment quality along the county watersheds.
The sites proposed for this survey are shown in Figure 2 while the list of target analytes
is provided in Appendix 1 as provided by the performing laboratory. The final list of
compounds will be defined once the project is awarded in consultation between Collier
County Pollution Control, FIU and Pace Analytical Services.
Figure 1.- Major watersheds and draining basins in Collier County, Florida
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As in previous years the key objectives of this survey are:
a) Continue the long-term assessment of multiple urban and agricultural-derived contaminants for the
main watersheds of Collier County (Main Golden Gate Canal Basin + Gordon River Extension
Basin, Cocohatchee River Basin, Faka Union Canal Basin and Barron River Canal Basin)(Figure
1).
b) Expand the regional coverage to environmental settings with new or modified land use not sampled
in previous efforts.
c) Continue the site specific-site survey at sites recommended in the 2014 report with particular
emphasis in Copper, Arsenic and PAHs.
d) Determine the current environmental conditions and potential risks by comparing the results with
available sediment quality assessment guidelines or previously determined county-wide
background concentrations.
Scope of Work and Implementation Plan
Upon consultation with the personnel of Collier County Pollution Control, we have
formulated a sampling strategy for the project given the required regional scope, the
expected funding level available and the list of potential target analytes as follows;
Task 1
Based on the results of previous monitoring efforts and based on the objectives, available
analytical technology and method performance metrics the team decided, in consultation
with Collier County Pollution Control to use the same list of target analytes identified in
the 2014 survey as follows:
Sediment Analyses
i) Trace metals by ICP (EPA 6010/3050 or equivalent). This method will target
most of the toxic heavy metals including Copper and others that will be used
for sourcing and calculation of enrichment factors. The target list includes the
most common toxic metals such as Ag, As, Cd, Cr, Cu, Pb, Mn, Ni, and Sb but
also Al, Fe and Sr. Results will be provided in dry weight basis thus
measurements of total % solids is also required.
ii) Chlorinated Pesticides by GC or GC/MS (EPA 8081/3546 or equivalent). This
method gives the best selection of legacy and present use pesticides
containing chlorine such as DDT and its metabolites, Chlordane, Endosulfan,
etc. Since PCBs were not catalogued as contaminants of potential concern in
past studies they will not be included in the survey.
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Packet Pg. 1440 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
iii) Organophosphorous and Organonitrogen Pesticides by GC or GC/MS (EPA
8141/3546 or equivalent). This gives a comprehensive determination of most
organophosphates (including Chlorpyrifos) but also target some important
nitrogen containing herbicides such as Atrazine and Simazine.
iv) Polynuclear Aromatic Hydrocarbons by GC/MS (any method with part per
billion detection will be adequate for example EPA 8270C-SIM). This is
particularly relevant for sites identified in the previous surveys as been
contaminated with PAHs (North Naples Bay and the lower Gordon River) but
also for any area affected by heavy boat or automotive traffic and its associated
runoff. Sample sizes should be adjusted when analyses are done to assure
that MDLs are relevant for environmental monitoring in areas where low
environmental concentrations are expected. We recommend at least 30 grams
of dry sediment for this task.
v) Chlorphenoxy herbicides by GC or GC/MS (EPA8151 or equivalent). The
analytes in this group include potent herbicides such as 2,4-D that are still
heavily used in many crop, ornamental, and household applications.
vi) Ancillary parameters: Bulk sediment characterization will include % Solids,
Total nitrogen (TN), Nitrate +Nitrite (TNOX), Total phosphorous (TP) and Total
organic carbon (TOC)
Pace Analytical Services will perform all chemical analysis through a separate agreement
with Collier County. FIU will perform all the site visits, sample collections and the gathering
of environmental field data such as depth, salinity, temperature and pH of the water
present at the sampling site. Shipping of samples from the field/FIU facility will be
arranged through Collier County based on the existing analytical lab agreements.
Task II
Due to restrictions related to the Collier County Pollution Control funding mechanism, the
bulk of the collections for the 2019 effort will concentrate in inland stations that are either
long-term monitoring sites (sentinels) or areas of estuaries that have shown significant
detections in the 2002-2014 surveys. The contribution of tributaries, specific land uses
and industrial or recreational activities could be an important factor in assessing pollution
loading from multiple sources. Because of that analysis will be conducted in surface
sediments sampled along canals, drainage streams and tributaries within the four major
inland watersheds of Collier County and their coastal fringes. For this purpose a total of
57 surface sediment samples will be collected and analyzed as described in Task I. All
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locations will be distributed along the watershed to include both the undeveloped areas
at the far end of the watershed as well as the connection upstream of a major estuary.
The list of sites remains unchanged from the 2014 survey. A list of the site locations is
presented in Table 1 and Figure 2. Sediment sampling sites will be the subject of a
reconnaissance, to be conducted with a member of Collier County’s Pollution Control field
team prior to the sampling campaign. Sampling will commence within 15 days of the date
of the official award and after the reconnaissance visits with Collier County Pollution
Control field personnel to address changes in current or past sites.
Figure 2 Proposed collection sites for the 2019 Collier County Sediment Quality Survey.
Task III
As in previous efforts, FIU will produce a comprehensive sediment quality survey report
that summarizes the environmental status and any trends observed in the sediment
contamination along the county watersheds. If detections are observed, a comparison
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with available sediment quality guidelines will be provided and the extent of any potential
contamination assessed with respect to trends, geographical distribution and
identification of potential sources. As in previous reports, the FIU team will provide
appropriate recommendations for future studies as needed. The duration of this task is
approximately 45 days after the receipt of the validated analytical data from the
performing laboratory in the corresponding electronic form. The target completion for the
project is October 31, 2019.
Project Logistics
The FIU team is in charge of the project management and general oversight. Collier
County has selected Pace Analytical Services as the performing laboratory for all
chemical analyses. Our team is responsible to collect all samples, transfer them under
the appropriate chain of custody documentation to the subcontractor by overnight
shipping or hand delivery and coordinate all the aspects of data review, interpretation and
reporting.
Implementation Plan
Since this scope of work/cost proposal needs to be approved by both Collier County and
Florida International University, sample collection and analyses will begin within 15-days
of the receipt of a properly executed contract. Because sample collection will be an on-
going activity depending on the site access, logistic coordination, delivery of data
packages etc., the estimated completion of all tasks will be four months from the contract
start date (7/15/2019) or 45 days from the availability of a complete validated analytical
dataset. An updated project timeline will be provided within 15 days of the award date
once the performing lab has been contacted and the turnaround times established.
Collection Method
Sites will be accessed by road, and where necessary (water deeper than 2 ft) a
small boat, kayak or paddle board will be used to navigate to the sampling site.
Samples will be collected using an Ekman style grab sampler or equivalent to
sample the top layer of sediment. If sediments are exposed to surface, samples
will be scoop-out directly with a stainless-steel (or plastic) spoon. Samples will be
placed in the appropriate sample container containing the required preservatives
(if any) as supplied by the analytical contractor, PACE Analytical Services.
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Packet Pg. 1443 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
Preservation of samples
Samples will be placed in ice immediately following collection and preserved under
refrigeration until relinquished to the analytical facility. In the event that the samples
could not be delivered within 48 hour of collection they will be shipped to the
preforming lab via overnight shipping.
Shipment
Samples will be hand delivered or shipped at the end of the day to the designated
PACE Analytical Service facility closest to the sampling area with the appropriate
chain of custody (Table 2 ).
Quality Assessment/Quality Control
Sampling and decontamination protocols will follow FDEP SOP FS4000 and the
SOPs referenced therein. Six replicate samples will be collected at six different
sites with a known history of contamination. A duplicate sample should be from a
separate grab sample and repeat the entire sample acquisition technique that was
used to obtain the first sample. Care will be taken not to collect the duplicate in an
area impacted from the first grab deployment.
Chain of Custody
Sample control and chain-of-custody procedures are extremely important for
establishing that sample integrity was maintained from the time of collection
through the time of analysis. Chain-of-custody forms (provided by either FIU or
Pace Analytical Services) will be used for tracking the samples from the time of
collection in the field through the time of shipment to the analytical laboratory.
The chain-of-custody form contains the following information (Table 2):
x Project identification
x Sampler's name
x Monitoring Location ID
x Date and time of sample collection for each sample
x Sampling site Latitude/Longitude coordinates
x Activity type: Sample of Field Duplicate
x Sample Collection Type
x Sample Collection Equipment
x Sample Matrix
x Activity depth
x Preservation method
x Destination - Laboratory name and address
x Requested analyses
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Packet Pg. 1444 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
x Printed name and signature of person relinquishing custody, and date
and time when custody relinquished
x Printed name and signature of person receiving custody, and date and
time when custody received. Given that shipping companies do not
sign the chain-of-custody form, the form will contain the shipping
company name and the package track number
x Relevant comments
Data Assessment, Interpretation and Final Report
The report format will follow previously submitted reports. Data will be assessed
using FDEP’s Interpretive Tool for Assessment of Metal Enrichment in Florida
Freshwater Sediment; Sediment Quality Assessment Guidelines for Florida Inland
Waters; the sediment quality guidelines provided in MacDonald’s (1994)
“Approach to the Assessment of Sediment Quality in Florida Coastal Waters
Florida Coastal Waters” and any other relevant peer reviewed published sediment
assessment tools. Comparisons to previous study results where changes in
sediment chemistry are evident would be noted. Electronic versions of the draft
final report will be provided to Collier Pollution Control by the end of the project
(10/31/19) for comments. The teams will have a conference meeting to address
changes, recommendations and conclusions before a final report is generated.
Cost Proposal
A cost proposal is included in the appendix. The budget includes all personnel, field, data
interpretation and reporting activities. All analytical costs, sample container/preservative
and sample shipping costs are excluded from the proposal. The requested funds
($39,998.01) include all aspects of sample collection, data reduction, data interpretation
and generation of the appropriate deliverables requested by Collier County. In addition, a
small in-state travel allowance is included to attend meetings or presentations related to
the project. A budget summary and a justification is included in Appendix II
The budget assumes that the negotiated indirect cost will be 26% since at least than 51%
of the work will be conducted outside the FIU campus.
Deliverables
Because of the nature of the project deliverables are separated in three sections:
a) Sediment samples, chain of custody documents and field notes will be
delivered to Pace Analytical Services at the end of each sampling date.
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b) Analytical results will be obtained by FIU from Pace Analytical Services
through Collier County Pollution Control, compiled as electronic spreadsheets
and tabulated for interpretation as needed.
c) Results from the study will be provided to the agency as a final interpretation
report that will be generated at the conclusion of the project and delivered
before the 10/31/19 end date. Electronic editable versions of the final reports
will be transmitted to Collier Pollution Control upon completion of the study.
Table 1. Proposed Station Locations for the 2019 Sediment Monitoring Survey
STATION
NAME Latitude Longitude Designation Surface Water Station
Name or Location
CC001 26.13532 -81.79078 Sentinel BC1
CC004 26.14220 -81.78850 Sentinel NBAY, North of US41
CC014 26.14549 -81.76620 Sentinel ROCKCRK
CC016 26.16328 -81.78654 Sentinel BC3
CC018 26.16801 -81.76677 Sentinel GGCAT31
CC020 26.12524 -81.77338 Sentinel
Haldeman Creek at Naples
Bay Marina outlet canal
(Modified BC5)
CC027 26.42189 -81.30499 Sentinel OKALA846
CC028 25.96871 -81.50995 Sentinel FAKA
CC031 26.15314 -81.52340 Sentinel BC10
CC032 26.00599 -81.60958 Sentinel TAMTOM
CC035 26.29298 -81.56184 Sentinel GGC@858
CC036 26.21121 -81.78470 Sentinel GRE896
CC038 26.24648 -81.58662 Sentinel Cypress Canal upstream of
CYPR13NW
CC043 26.16947 -81.70534 Sentinel Outfall of Lake Sapphire
CC047 26.27256 -81.77896 Sentinel BC14
CC048 26.28233 -81.80217 Sentinel COCAT41
CC052 26.27780 -81.77806 Sentinel COCPALM
CC057 26.29362 -81.47939 Sentinel KEAISS
CC059 26.04579 -81.70829 Sentinel Henderson Creek by
Rookery Bay
CC063 26.05711 -81.68955 Sentinel BC22
CC064 26.10511 -81.74562 Sentinel LELY
CC065 26.09456 -81.74034 Sentinel Downstream of LMB00
CC066 26.23021 -81.81342 Sentinel Clam Bay Outfall
CC067 26.27242 -81.68936 Sentinel BC26
CC069 26.27758 -81.60144 Sentinel CORK@846
CC070 26.24392 -81.65736 Sentinel
Cypress Canal
downstream of
CYPR13NW
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Packet Pg. 1446 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
Table 1. Proposed Station Locations for the 2019 Sediment Monitoring Survey
STATION
NAME Latitude Longitude Designation Surface Water Station
Name or Location
CC072 26.21333 -81.73465 Sentinel I75 Canal at Pine Ridge
CC074 26.19744 -81.71936 Sentinel Green Canal and Santa
Barbara
CC076 26.29333 -81.52965 Sentinel FAKA858
CC078 26.49581 -81.52881 Sentinel CORKSCRD
CC079 26.43337 -81.46260 Sentinel IMKFSHCK
CC080 26.30328 -81.34243 Sentinel IMKBRN
CC082 25.90977 -81.36348 Sentinel BARRIVN
CC085 26.40906 -81.39782 Sentinel BRN
CC086 26.20352 -81.34646 Sentinel BC24
CC090 26.40632 -81.42966 Sentinel IMKSLGH
CC101 26.29435 -81.81007 Sentinel WIGGINSBY
CC102 26.12714 -81.75893 Copper-specific Glades
CC103 26.11403 -81.76221 Copper-specific Lake Avalon
CC105 26.17532 -81.78729 Copper-specific Freedom Park
CC106 26.17372 -81.78422 Sentinel GORDONRIV
CC107 26.24105 -81.68871 Copper-specific 7th Ave Pond on CR951
CC108 26.22832 -81.68893 Copper-specific Control Pond onCR951
CC109 26.13520 -81.77399 Copper-specific Gateway Triangle Lake
CC111 26.19822 -81.80569 Copper-specific Swan Lake
CC113 26.19800 -81.80900 Copper-specific Moorings Bay
CC114 26.19827 -81.77419 Copper-specific Pine Woods
CC115 26.20037 -81.77571 Copper-specific Pine Woods Outfall
CC116 26.32140 -81.83161 Sentinel Little Hickory Bay
CC117 26.25591 -81.81995 Sentinel VBILT
CC118 26.15609 -81.66956 New HEC245
CC119 26.03073 -81.67079 New SANDPIPE
CC120 26.06465 -81.70555 New EAGLECRK
CC121 26.36667 -81.48457 New KEAISN
CC122 26.30495 -81.29252 New OKALA858
CC123 26.12790 -81.76110 New WINPARK
CC124 26.12230 -81.75810 New HALDUP
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Table 2. Chain of Custody Documents - Field Notes Format
DESTINATION:SAMPLEACTIVITY COLLECTIONDEPTHBOTTLE ID DATE TIME LAT LONSAMPLE or DUPEQUIPMENTMATRIX m TSS Metals Pesticide Herbicide PAH TKN TP TOC PRESERVE COMMENTSCUSTODY CHAIN:Until Date:COLLECTIONCOORDINATESANALYSIS REQUESTEDCOURIER:TRACKING #:DATEPRESERVATION:Pace Analytics 6175 NW 153rd St #101, Miami Lakes, FL 3301SOUTHEAST ENVIRONMENTAL RESEARCH CENTEROE 148 (office), University Park, Miami, FL 33199, 305-348-3095Chain of Custody Record/Sample LogCLIENT/PROJECT NAME: Collier County, FloridaACCOUNT NO.:COLLECTOR:16.A.21.aPacket Pg. 1448Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International
APPENDIX I
Pace Analytical Services
Method Detection, Quantitation and Reporting Limits
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Method Detection Limits for Organophosphate Pesticides by EPA 8141
(Sediments/Soils)
Analyte Cas No. PQL units MDL Units
FENTHION 55-38-9 0.1 mg/kg 0.00608 mg/kg
AZINPHOS-METHYL 86-50-0 0.1 mg/kg 0.00378 mg/kg
CHLORPYRIFOS 2921-88-2 0.1 mg/kg 0.00923 mg/kg
COUMAPHOS 56-72-4 0.1 mg/kg 0.0068 mg/kg
DEMETON,-O AND -S 8065-48-3 0.07 mg/kg 0.00339 mg/kg
DIAZINON 333-41-5 0.1 mg/kg 0.00447 mg/kg
DICHLORVOS 62-73-7 0.1 mg/kg 0.00969 mg/kg
DIMETHOATE 60-51-5 0.1 mg/kg 0.0198 mg/kg
DISULFOTON 298-04-4 0.1 mg/kg 0.00498 mg/kg
EPN 2104-64-5 0.1 mg/kg 0.00512 mg/kg
ETHOPROP 13194-48-4 0.1 mg/kg 0.00465 mg/kg
ETHYL PARATHION 56-38-2 0.1 mg/kg 0.00571 mg/kg
FENSULFOTHION 115-90-2 0.1 mg/kg 0.0169 mg/kg
BOLSTAR (SULPPROFOS) 35400-43-2 0.1 mg/kg 0.00554 mg/kg
MALATHION 121-75-5 0.1 mg/kg 0.007 mg/kg
MERPHOS 150-50-5 0.1 mg/kg 0.00539 mg/kg
METHYL PARATHION 298-00-0 0.1 mg/kg 0.00669 mg/kg
MEVINPHOS 7786-34-7 0.1 mg/kg 0.0102 mg/kg
NALED 300-76-5 0.1 mg/kg 0.00418 mg/kg
PHORATE 298-02-2 0.1 mg/kg 0.00471 mg/kg
RONNEL 299-84-3 0.1 mg/kg 0.00437 mg/kg
STIROPHOS 22248-79-9 0.1 mg/kg 0.00537 mg/kg
SULFOTEP 3689-24-5 0.1 mg/kg 0.00386 mg/kg
TEPP 21646-99-1 1 mg/kg 0.157 mg/kg
TOKUTHION (PROTHOTHIOFOS) 34643-46-4 0.1 mg/kg 0.00604 mg/kg
TRICHLORONATE 327-98-0 0.1 mg/kg 0.00664 mg/kg
Description
Matrix SS
Dep.SemiVolatile Organics
16.A.21.a
Packet Pg. 1450 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
Method Detection Limits for Chlorophenoxy Herbicides by EPA 8151 (Water and Soils)
LJ LISTTYPE PARM_STORED TYPE UNITS MDL RDL METHODR
LJ1329627 SV8151 2,4-D REG mg/kg 0.00702 0.07000 8151
LJ1329627 SV8151 DALAPON REG mg/kg 0.01130 0.07000 8151
LJ1329627 SV8151 2,4-DB REG mg/kg 0.02970 0.07000 8151
LJ1329627 SV8151 DICAMBA REG mg/kg 0.01570 0.07000 8151
LJ1329627 SV8151 DICHLOROPROP REG mg/kg 0.02450 0.07000 8151
LJ1329627 SV8151 DINOSEB REG mg/kg 0.00697 0.07000 8151
LJ1329627 SV8151 MCPA REG mg/kg 0.44300 6.50000 8151
LJ1329627 SV8151 MCPP REG mg/kg 0.36700 6.50000 8151
LJ1329627 SV8151 2,4,5-T REG mg/kg 0.00852 0.07000 8151
LJ1329627 SV8151 2,4,5-TP (SILVEX) REG mg/kg 0.01070 0.07000 8151
LJ1329627 SV8151 2,4-DICHLOROPHENYL ACETIC ACID SURR % Rec. 8151
LJ1331417 SV8151 2,4-D REG mg/l 0.00074 0.00200 8151
LJ1331417 SV8151 DALAPON REG mg/l 0.00104 0.00200 8151
LJ1331417 SV8151 2,4-DB REG mg/l 0.00078 0.00400 8151
LJ1331417 SV8151 DICAMBA REG mg/l 0.00081 0.00200 8151
LJ1331417 SV8151 DICHLOROPROP REG mg/l 0.00078 0.00200 8151
LJ1331417 SV8151 DINOSEB REG mg/l 0.00080 0.00200 8151
LJ1331417 SV8151 MCPA REG mg/l 0.01310 0.20000 8151
LJ1331417 SV8151 MCPP REG mg/l 0.00715 0.20000 8151
LJ1331417 SV8151 2,4,5-T REG mg/l 0.00084 0.00200 8151
LJ1331417 SV8151 2,4,5-TP (SILVEX) REG mg/l 0.00085 0.00200 8151
LJ1331417 SV8151 2,4-DICHLOROPHENYL ACETIC ACID SURR % Rec. 8151
16.A.21.a
Packet Pg. 1451 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 2540GS
Detection Limits
PASI Ormond Beach Laboratory
2540G Total Solids
32781 SM 2540G 6/3/2017PRL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte PRL UnitsCAS Number
1 Total Solids 10 mg/kg
Page 1 of 2Thursday, April 11, 2019 3:58:41 PM
16.A.21.a
Packet Pg. 1452 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 2540GS
Detection Limits
PASI Ormond Beach Laboratory
2540G Total Solids
32780 SM 2540G 6/3/2017MDL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte MDL UnitsCAS Number
1 Total Solids 10 mg/kg
Page 2 of 2Thursday, April 11, 2019 3:58:41 PM
16.A.21.a
Packet Pg. 1453 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 6010 S
Detection Limits
PASI Ormond Beach Laboratory
6010 MET ICP
32804 EPA 6010 EPA 3050 1/24/2018PRL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte PRL UnitsCAS Number
1 Aluminum 5 mg/kg7429-90-5
2 Antimony 0.75 mg/kg7440-36-0
3 Arsenic 0.5 mg/kg7440-38-2
4 Barium 0.5 mg/kg7440-39-3
5 Beryllium 0.05 mg/kg7440-41-7
6 Boron 2.5 mg/kg7440-42-8
7 Cadmium 0.05 mg/kg7440-43-9
8 Chromium 0.25 mg/kg7440-47-3
9 Cobalt 0.5 mg/kg7440-48-4
10 Copper 0.25 mg/kg7440-50-8
11 Iron 2 mg/kg7439-89-6
12 Lead 0.5 mg/kg7439-92-1
13 Manganese 0.25 mg/kg7439-96-5
14 Molybdenum 0.5 mg/kg7439-98-7
15 Nickel 0.25 mg/kg7440-02-0
16 Selenium 0.75 mg/kg7782-49-2
17 Silver 0.25 mg/kg7440-22-4
18 Thallium 0.75 mg/kg7440-28-0
19 Vanadium 0.5 mg/kg7440-62-2
20 Zinc 1 mg/kg7440-66-6
21 Titanium 0.5 mg/kg7440-32-6
22 Calcium 25 mg/kg7440-70-2
23 Magnesium 25 mg/kg7439-95-4
24 Tin 2.5 mg/kg7440-31-5
25 Sodium 50 mg/kg7440-23-5
26 Potassium 50 mg/kg7440-09-7
27 Lithium 25 mg/kg7439-93-2
28 Phosphorus 50 mg/kg7723-14-0
29 Silicon 50 mg/kg7440-21-3
30 Strontium 0.5 mg/kg7440-24-6
31 Silica 50 mg/kg7631-86-9
32 Sulfur 50 mg/kg
Page 1 of 4Thursday, April 11, 2019 4:00:46 PM
16.A.21.a
Packet Pg. 1454 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 6010 S
Detection Limits
PASI Ormond Beach Laboratory
6010 MET ICP
32804 EPA 6010 EPA 3050 1/24/2018MDL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte MDL UnitsCAS Number
1 Aluminum 2.5 mg/kg7429-90-5
2 Antimony 0.375 mg/kg7440-36-0
3 Arsenic 0.25 mg/kg7440-38-2
4 Barium 0.25 mg/kg7440-39-3
5 Beryllium 0.025 mg/kg7440-41-7
6 Boron 1.25 mg/kg7440-42-8
7 Cadmium 0.025 mg/kg7440-43-9
8 Chromium 0.125 mg/kg7440-47-3
9 Cobalt 0.25 mg/kg7440-48-4
10 Copper 0.125 mg/kg7440-50-8
11 Iron 1 mg/kg7439-89-6
12 Lead 0.25 mg/kg7439-92-1
13 Manganese 0.125 mg/kg7439-96-5
14 Molybdenum 0.25 mg/kg7439-98-7
15 Nickel 0.125 mg/kg7440-02-0
16 Selenium 0.375 mg/kg7782-49-2
17 Silver 0.125 mg/kg7440-22-4
18 Thallium 0.375 mg/kg7440-28-0
19 Vanadium 0.25 mg/kg7440-62-2
20 Zinc 0.5 mg/kg7440-66-6
21 Titanium 0.1 mg/kg7440-32-6
22 Calcium 12.5 mg/kg7440-70-2
23 Magnesium 12.5 mg/kg7439-95-4
24 Tin 1.25 mg/kg7440-31-5
25 Sodium 25 mg/kg7440-23-5
26 Potassium 25 mg/kg7440-09-7
27 Lithium 3.2 mg/kg7439-93-2
28 Phosphorus 25 mg/kg7723-14-0
29 Silicon 25 mg/kg7440-21-3
30 Strontium 0.25 mg/kg7440-24-6
31 Silica 25 mg/kg7631-86-9
32 Sulfur 25 mg/kg
Page 2 of 4Thursday, April 11, 2019 4:00:46 PM
16.A.21.a
Packet Pg. 1455 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 6010 S
Detection Limits
PASI Ormond Beach Laboratory
6010 MET ICP
32861 EPA 6010 8/29/2018PRL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte PRL UnitsCAS Number
1 Aluminum 100 ug/L7429-90-5
2 Antimony 15 ug/L7440-36-0
3 Arsenic 10 ug/L7440-38-2
4 Barium 10 ug/L7440-39-3
5 Beryllium 4 ug/L7440-41-7
6 Boron 50 ug/L7440-42-8
7 Cadmium 1 ug/L7440-43-9
8 Chromium 5 ug/L7440-47-3
9 Cobalt 10 ug/L7440-48-4
10 Copper 5 ug/L7440-50-8
11 Iron 40 ug/L7439-89-6
12 Lead 10 ug/L7439-92-1
13 Manganese 5 ug/L7439-96-5
14 Molybdenum 10 ug/L7439-98-7
15 Nickel 5 ug/L7440-02-0
16 Selenium 15 ug/L7782-49-2
17 Silver 5 ug/L7440-22-4
18 Thallium 15 ug/L7440-28-0
19 Vanadium 10 ug/L7440-62-2
20 Zinc 20 ug/L7440-66-6
21 Titanium 100 ug/L7440-32-6
22 Calcium 500 ug/L7440-70-2
23 Magnesium 500 ug/L7439-95-4
24 Tin 50 ug/L7440-31-5
25 Sodium 2000 ug/L7440-23-5
26 Potassium 1000 ug/L7440-09-7
27 Silicon 100 ug/L7440-21-3
28 Strontium 10 ug/L7440-24-6
29 Silica 214 ug/L7631-86-9
30 Sulfur 200 ug/L
Page 3 of 4Thursday, April 11, 2019 4:00:46 PM
16.A.21.a
Packet Pg. 1456 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 6010 S
Detection Limits
PASI Ormond Beach Laboratory
6010 MET ICP
32850 EPA 6010 7/6/2018 7/6/2019MDL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte MDL UnitsCAS Number
1 Aluminum 30.7 ug/L7429-90-5
2 Antimony 5.5 ug/L7440-36-0
3 Arsenic 7.1 ug/L7440-38-2
4 Barium 0.84 ug/L7440-39-3
5 Beryllium 1.6 ug/L7440-41-7
6 Boron 12.4 ug/L7440-42-8
7 Cadmium 0.33 ug/L7440-43-9
8 Chromium 1.7 ug/L7440-47-3
9 Cobalt 0.96 ug/L7440-48-4
10 Copper 2.6 ug/L7440-50-8
11 Iron 9.2 ug/L7439-89-6
12 Lead 4.6 ug/L7439-92-1
13 Manganese 0.42 ug/L7439-96-5
14 Molybdenum 1.6 ug/L7439-98-7
15 Nickel 2.1 ug/L7440-02-0
16 Selenium 8.5 ug/L7782-49-2
17 Silver 1 ug/L7440-22-4
18 Thallium 6.6 ug/L7440-28-0
19 Vanadium 1 ug/L7440-62-2
20 Zinc 11 ug/L7440-66-6
21 Titanium 38.4 ug/L7440-32-6
22 Calcium 64.1 ug/L7440-70-2
23 Magnesium 84 ug/L7439-95-4
24 Tin 40.1 ug/L7440-31-5
25 Sodium 272.7 ug/L7440-23-5
26 Potassium 150.4 ug/L7440-09-7
27 Lithium 99.9 ug/L7439-93-2
28 Phosphorus 14 ug/L7723-14-0
29 Silicon 45.7 ug/L7440-21-3
30 Strontium 0.73 ug/L7440-24-6
31 Silica 97.8 ug/L7631-86-9
32 Sulfur 16.7 ug/L
Page 4 of 4Thursday, April 11, 2019 4:00:46 PM
16.A.21.a
Packet Pg. 1457 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 8270 SSMW
Detection Limits
PASI Ormond Beach Laboratory
8270 MSSV Short List Microwave
32909 EPA 8270 EPA 3546 4/3/2019 4/3/2020MDL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte MDL UnitsCAS Number
1 Benzo(a)anthracene 9.68 ug/kg56-55-3
2 Benzo(a)pyrene 8.4 ug/kg50-32-8
3 Chrysene 10.72 ug/kg218-01-9
4 Dibenz(a,h)anthracene 7.79 ug/kg53-70-3
5 Indeno(1,2,3-cd)pyrene 7.74 ug/kg193-39-5
6 Acenaphthene 11.69 ug/kg83-32-9
7 Acenaphthylene 10.59 ug/kg208-96-8
8 Anthracene 11.96 ug/kg120-12-7
9 Benzo(g,h,i)perylene 8.5 ug/kg191-24-2
10 Fluoranthene 11.1 ug/kg206-44-0
11 Fluorene 12.09 ug/kg86-73-7
12 Naphthalene 11.63 ug/kg91-20-3
13 Phenanthrene 11.11 ug/kg85-01-8
14 Pyrene 10.68 ug/kg129-00-0
15 1-Methylnaphthalene 13.29 ug/kg90-12-0
16 2-Methylnaphthalene 12.88 ug/kg91-57-6
17 Benzo(k)fluoranthene 9.05 ug/kg207-08-9
18 Benzo(b)fluoranthene 9.03 ug/kg205-99-2
Page 1 of 2Thursday, April 11, 2019 4:01:26 PM
16.A.21.a
Packet Pg. 1458 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 8270 SSMW
Detection Limits
PASI Ormond Beach Laboratory
8270 MSSV Short List Microwave
32847 EPA 8270 EPA 3546 6/26/2018PRL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte PRL UnitsCAS Number
1 Benzo(a)anthracene 34 ug/kg56-55-3
2 Benzo(a)pyrene 34 ug/kg50-32-8
3 Chrysene 34 ug/kg218-01-9
4 Dibenz(a,h)anthracene 34 ug/kg53-70-3
5 Indeno(1,2,3-cd)pyrene 34 ug/kg193-39-5
6 Acenaphthene 36 ug/kg83-32-9
7 Acenaphthylene 34 ug/kg208-96-8
8 Anthracene 36 ug/kg120-12-7
9 Benzo(g,h,i)perylene 34 ug/kg191-24-2
10 Fluoranthene 34 ug/kg206-44-0
11 Fluorene 37 ug/kg86-73-7
12 Naphthalene 35 ug/kg91-20-3
13 Phenanthrene 34 ug/kg85-01-8
14 Pyrene 34 ug/kg129-00-0
15 1-Methylnaphthalene 40 ug/kg90-12-0
16 2-Methylnaphthalene 39 ug/kg91-57-6
17 Benzo(k)fluoranthene 34 ug/kg207-08-9
18 Benzo(b)fluoranthene 34 ug/kg205-99-2
Page 2 of 2Thursday, April 11, 2019 4:01:26 PM
16.A.21.a
Packet Pg. 1459 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: TOTAL SN2
Detection Limits
PASI Ormond Beach Laboratory
Total Nitrogen Calculation
357 Solid TKN+NOx 9/1/2009PRL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte PRL UnitsCAS Number
1 Total Nitrogen Soil 5 mg/kg
Page 1 of 4Thursday, April 11, 2019 4:04:05 PM
16.A.21.a
Packet Pg. 1460 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: TOTAL SN2
Detection Limits
PASI Ormond Beach Laboratory
Total Nitrogen Calculation
356 Solid TKN+NOx 9/1/2009MDL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte MDL UnitsCAS Number
1 Total Nitrogen Soil 2.5 mg/kg
Page 2 of 4Thursday, April 11, 2019 4:04:06 PM
16.A.21.a
Packet Pg. 1461 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: TOTAL SN2
Detection Limits
PASI Ormond Beach Laboratory
Total Nitrogen Calculation
32473 TKN+NOx 2/9/2015MDL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte Limit UnitsCAS Number
Page 3 of 4Thursday, April 11, 2019 4:04:06 PM
16.A.21.a
Packet Pg. 1462 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: TOTAL SN2
Detection Limits
PASI Ormond Beach Laboratory
Total Nitrogen Calculation
349 TKN+NOx 8/21/2009PRL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte Limit UnitsCAS Number
Page 4 of 4Thursday, April 11, 2019 4:04:06 PM
16.A.21.a
Packet Pg. 1463 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 3654 S
Detection Limits
PASI Ormond Beach Laboratory
365.4 Phosphorus, Total
288 Solid EPA 365.4 7/17/2009MDL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte MDL UnitsCAS Number
1 Phosphorus, Total (as P) 2 mg/kg7723-14-0
Page 1 of 4Thursday, April 11, 2019 4:04:28 PM
16.A.21.a
Packet Pg. 1464 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 3654 S
Detection Limits
PASI Ormond Beach Laboratory
365.4 Phosphorus, Total
287 Solid EPA 365.4 7/17/2009PRL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte PRL UnitsCAS Number
1 Phosphorus, Total (as P) 4 mg/kg7723-14-0
Page 2 of 4Thursday, April 11, 2019 4:04:28 PM
16.A.21.a
Packet Pg. 1465 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 3654 S
Detection Limits
PASI Ormond Beach Laboratory
365.4 Phosphorus, Total
48 EPA 365.4 6/10/2009PRL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte PRL UnitsCAS Number
1 Phosphorus, Total (as P) 0.1 mg/L7723-14-0
Page 3 of 4Thursday, April 11, 2019 4:04:29 PM
16.A.21.a
Packet Pg. 1466 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
For Acode: 3654 S
Detection Limits
PASI Ormond Beach Laboratory
365.4 Phosphorus, Total
47 EPA 365.4 6/10/2009MDL
ID Matrix
Analytical
Method
Preparation
Method
Effective
Date
Stop
Date
Limits
Type Other Criteria
Instr.
Name
Sample
Type
# Analyte MDL UnitsCAS Number
1 Phosphorus, Total (as P) 0.05 mg/L7723-14-0
Page 4 of 4Thursday, April 11, 2019 4:04:29 PM
16.A.21.a
Packet Pg. 1467 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
APPENDIX II
FIU Budget Form – Year 1
16.A.21.a
Packet Pg. 1468 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
Agency:
1
Level 3
Budgetary Account
Level 4
Budgetary Account Account Code Base Salary
% Effort
CY
% Effort
AY
% Effort
Summer 12 month 9 month Summer Total
(F) = Faculty
(A) = Administrative New Exists
771001-771139 (F)
771140-771149 (A)1.0 0 161,809.72$ 7%-$ 10,517.63$ -$ 10,517.63$
771600-771649
771700-771999 0.00 0.59 0.00 -$ 3,577.05$ -$ 3,577.05$
771001-771139 (F)
771140-771149 (A)2.0 0 108,197.76$ 2%2,077.40$ -$ -$ 2,077.40$
771600-771649
771700-771999 0.23 0.00 0.00 706.52$ -$ -$ 706.52$
771001-771139 (F)
771140-771149 (A)3.00 -$ -$ -$ -$ -$
771600-771649
771700-771999 0.00 0.00 0.00 -$ -$ -$ -$
771001-771139 (F)
771140-771149 (A)4.00 -$ -$ -$ -$ -$
771600-771649
771700-771999 0.00 0.00 0.00 -$ -$ -$ -$
771001-771139 (F)
771140-771149 (A)5.00 -$ -$ -$ -$ -$
771600-771649
771700-771999 0.00 0.00 0.00 -$ -$ -$ -$
(S) = Staff
771150-771159 (S)1.0 0 59,012.85$ 4%2,266.09$ -$ -$ 2,266.09$
771600-771649
771700-771999 0.46 0.00 0.00 1,074.58$ -$ -$ 1,074.58$
771150-771159 (S)2.00 -$ -$ -$ -$ -$
771600-771649
771700-771999 0.00 0.00 0.00 -$ -$ -$ -$
00
14,861.12$
5,358.15$
Object Code
771500-771549 1 1,163.57$
771500-771549 0 -$
771500-771549 0 -$
771500-771549 N/A -$
771500-771549 N/A -$
0 1,163.57$
771660-771669 49.92$
16,024.70$
P77156 - Fringe 5,408.07$
21,432.76$
Object Code
P71121 - Domestic Travel 711211-711226
711251-711286 4,500.00$
P71123 - Foreign Travel 711230-711239 -$
P71119 - Long Distance Telephone Calls 711190-711199 -$
773600-773699 1,020.00$
773500-773599 -$
773900-773910
773912 -773999 993.27$
773911 3,300.00$
773100-773199 -$
711021-711031 500.00$
711360-711399 -$
Specify -$
711902
-$
P71100 - Participant Payments 711991 -$
P71150 - Patient Care Cost 711510 -$
P77200 - Professional Fees
772101-772102
772104-772126
772131-772132
772141
772151-772157
772301-772303 -$
P77210 - Consultants 772103 -$
P71140 - Rent Expense Other Than Buildings 711401-711406 -$
P76100 - Repairs and Maintenance 761001-761006 -$
P76800 - Scholarships 768201-768211 -$
P76830 - Stipends 768301 -$
10,313.27$
$0.00 -$
$0.00 -$
S76840 - Tuition P76840 - Tuition 768400-768409
$0.00
P77220 - Advertising Services 772201-772204 -$
P72110 - Books & Film 721101-721103 -$
P77320 - Building and Construction 773201-773212 -$
P71117 - Cellular Phones 711171 -$
P77218 - Construction Services 772181-772185 -$
P77382 - Data Processing Supplies 773821 -$
P77381 - Hazar dous Chemicals/Waste 773810 -$
P77380 - Food Products 773801 -$
P71116 - Local Telephone Calls 711196 -$
P71145 - Memberships & Subscriptions 711451-711454 -$
P71130 - Moving Expenses 711301-711304 -$
P77330 - Office Supplies 773301-773305 -$
P71101 - Postage 711011-711013 -$
P71144 - Rent Expense Buildings 711440 -$
P71118-Telephone Equipment 711180-711189 -$
-$
-$
$0.00
31,746.03$
31,746.03$
8,253.97
$8,253.97 8,253.97$
40,000.00$
Piero R. Gardinali
Henry Briceño
0
0
0
Total Head Count
Graduate Student Assistants
4. Secretarial-Clerical (SECRETARIAL-CLERICAL WILL REQUIRE A DIRECT CHARGE EXEMPTION FORM AT PROPOSAL TIME)
3.
7 Recharge Center Charges - SERC FOC Truck+mileage/Boat+gas
TOTAL OTHER PERSONNEL FRINGE BENEFITS (SECTION B):
TOTAL SALARIES & WAGES (A+B):
TOTAL FRINGE BENEFITS:
TOTAL SALARIES, WAGES, AND FRINGE BENEFITS (S77100):
TOTAL SENIOR PERSONNEL SALARIES & WAGES (SECTION A):
TOTAL SENIOR PERSONNEL FRINGE BENEFITS (SECTION A):
P77150-OPS
Head Count B. OTHER PERSONNEL - FRINGE AT 4.29% EXCEPT FOR GRADUATE STUDENTS AT 8.79%, OPS STUDENTS AT 0.00%
1.Other Professionals - Field Crew Specialist (10 days)
Student OPS
Jeff Absten
0
Total New & Existing Positions:
6 Other Materials & Supplies
2.
TOTAL INDIRECT COSTS (S75700):
G. TOTAL DIRECT AND INDIRECT COSTS
PERSON MONTHS & FRINGE BENEFITS FOR PERSONNEL ABOVE
PERSON MONTHS & FRINGE BENEFITS FOR PERSONNEL ABOVE
PERSON MONTHS & FRINGE BENEFITS FOR PERSONNEL ABOVE
PERSON MONTHS & FRINGE BENEFITS FOR PERSONNEL ABOVE
PERSON MONTHS & FRINGE BENEFITS FOR PERSONNEL ABOVE
>51% off campus
Type:MTDC - Modified Total Direct Cost Indirect Cost:
C.
TOTAL DIRECT COSTS (A through D):
S75700 - Facilities &
Administrative
Expense
E. INDIRECT COSTS
S72120 - Equipment &
Other Capital Exp
(Equipment/OCO)
D. PERMANENT EQUIPMENT & BOOKS OR OTHER LIBRARY RESOURCES (list item and dollar)
P72100 - Other Capital Outlay 721200-721999
amount for each item exceeding $5,000
P75700 - Indirect Costs 757003 Rate:26.00%
A.
B.Total Permanent Equipment (S72120):
$0.00 34 Moving Expenses
35 Office Supplies/Computer Supplies
36 Postage
37 Rent Expense Buildings
38 Telephone Equipment
TOTAL RESTRICTED OPERATING EXPENSES (S7710R):
Construction Services
29 Data Processing Supplies
31 Food Products
32 Local Telephone Calls
S7710R - Restricted
Operating Expenses
(Restricted Items)
24 Advertising Services
25 Books & Films
26 Building & Construction
27 Cellular Phones
28
33 Membership & Subscriptions
30 Hazardous Chemicals/Waste
23 Tuition Payments
Restricted Expenses - In alphabetical order by budget category.
RED Items are part of F&A and are normally not allowed on Federal Grants. RED items will require a DIRECT CHARGE EXEMPTION FORM.
S7729U -
Subcontractors < $25K P7729U - Subcontractor Amounts under $25K 772951
22
*** Subcontractor Budgets Must Be Entered in The 'Project Subcontractor Budgets' Worksheet ***
Subcontractor Amounts UNDER 25K:
20 Stipends
TOTAL OPERATING EXPENSES (S71100):
S77295 -
Subcontractors > $25K P77295 - Subcontractor Am ounts over $25K 772952
21
*** Subcontractor Budgets Must Be Entered in The 'Project Subcontractor Budgets' Worksheet ***
Subcontractor Amounts OVER 25K:
$10,313.27
17 Rent Expense Other Than Buildings
18 Repairs & Maintenance
19 Scholarships
13 Participant Payments
14 Patient Care Costs
Participant Support Costs Total "MUST BE ENTERED IN THE PARTICIPANT SUPPORT WORKSHEET"
15 Professional Fees
16 Consulting Services/Agreements
Printing & Reproduction
9 Freight
10 Insurance
773001-773002
711075-711077
711900-711989 11
Miscellaneous Expenses (Other)
*** Must Provide Amount & Associated Details Below ***
(List each separately with title)
S77100 - Salaries &
Wages
(Salary & Fringe)
P77100 - Salaries & Wages
TOTAL OTHER PERSONNEL SALARIES & WAGES(SECTION B):
5. Other
PERSON MONTHS & FRINGE BENEFITS FOR PERSONNEL ABOVE
PERSON MONTHS & FRINGE BENEFITS FOR PERSONNEL ABOVE
A.2 - Staff Salary (fringe at 47.42%)
FLORIDA INTERNATIONAL UNIVERSITY PROPOSAL BUDGET SHEET
Principal Investigator/Project Director:Piero R. Gardinali Collier County Pollution Control
Budget Period Start Date:07/15/19 Budget Period End Date:10/31/19 Period/Year #:
A.1. - FACULTY / ADMINISTRATIVE SALARY (fringe at 34.01%)
Position
$21,432.76
P71190 - Other Operating Expenses
12 Software License (requires a direct charge exemption form)S71100 - Operating
Expenses
(Unrestricted Items)
C. EXPENSES - IN ALPHABETICAL ORDER BY BUDGET CATEGORY.
1 Travel - Domestic - Hotel + Per diem +private vehicle
2 Travel - Foreign
3 Long Distance Telephone Calls
P77300 - Materials and Supplies
4 Educational & Lab Supplies
5 Motor Fuel & Lubricants
8
16.A.21.a
Packet Pg. 1469 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
Budget Justification
A. Senior Personnel:
Dr. Piero R. Gardinali, the project’s PI, is requesting 0.64 month of academic year salary
(9-month contract, totaling $10,517.63) in Year 1 to compile the field and analytical data,
conduct the statistical interpretation and write the technical report. Dr. Gardinali oversees
the entire project operations.
Dr. Henry Briceño, the project Co-PI is requesting 0.25 month of calendar year salary
(12-month contract, totaling $2,077.40) in Year 1 to oversee the field operations,
coordinate the sample collection and transfer to the analytical laboratory. Dr. Briceño
oversees the field personal and coordinates the site visits and vehicle operations.
B. Other Personnel:
Mr. Jeff Absten, the Field Coordinator is budgeted for 10 days of field work (totaling
$2,266.09) to coordinate and conduct the sediment sample collections. He also supervises
the work of the Field Crew Specialist (FCS). The FCS is budgeted for 10 days of field
work (totaling $1,163.57) to assist the Field Coordinator in operating boats, vehicles and
sampling equipment to collect the samples at the 57 designated sampling sites in Collier
County.
C. Fringe Benefits ($5,408.07):
FIU is currently using a fringe benefit rate of 34.01% for full time employees (faculty and
administrative), 23.93% for College of Medicine faculty, 47.42% for staff employees,
4.29% for Other OPS and Temporary Faculty (except students), 8.79% for Graduate
Student assistants, and 0.0% for Student OPS. This rate is proposed at proposal
submission and is an estimate for budgeting purposes only.
D. Educational Materials and Lab Supplies ($1,020.00):
A total of $1,020 is requested to purchase an additional Ekman dredge, extension handles
and to purchase the materials needed for the calibration and upkeep of the field collection
equipment (EXO2 probes)
E. Travel:
Domestic Travel ($4,500.00):
Travel funds are requested to cover the cost of lodging and per-diem for the field crew to
stay overnight in the vicinity of Naples, FL during the sampling dates that require longer
than 8 hours field work. In addition funds are requested for one project management visit
with Collier Pollution Control at the beginning of the project and one at report time to
discuss the sampling site selection and work on the team recommendations for the final
report.
Foreign Travel: (N/A)
16.A.21.a
Packet Pg. 1470 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
F. Participant Support: Not Applicable
G. Other Direct Costs ($4,793.27):
1. Materials/Supplies ($993.27): Funding will be needed to purchase materials and
supplies to assist in collection of samples, field protective equipment, maintaining
statistical software packages licenses and to purchase sample transporting and
preservation consumables.
2. Recharge Center Charges ($3,300.00): a total of $3,300 is budgeted for truck and
vessel rental through SERC’s Field operation Center as recharge costs.
4. Freight ($500.00): A modest $500 budget is included to cover incidental
overnight shipping needs when samples can’t be delivered to the analytical lab
within 48 hours of collection.
H. Total Direct Costs: $31,746.03
I. Facilities and Administration Costs ($8,253.97): F & A costs at Florida International
University are calculated at 47.5% of the modified total direct cost which excludes
equipment, capital expenditures, charges for patient care, tuition remission, rental costs of
off-site facilities, scholarships and fellowships, participant support costs and the portion
of each subcontract and/or subgrant in excess of $25,000 regardless of the period
covered. Equipment means an article of nonexpendable tangible personal property having
a useful life of more than one year, and an acquisition cost of $5,000 or more per unit.
The F&A costs for this proposal however, are calculated at the reduced rate of 26% since
more than 51% of the work described in the statement of work is to be conducted off-
campus.
J. Total Budget Requested: $40,000.00
16.A.21.a
Packet Pg. 1471 Attachment: FY19 Exemption Request 166 - FL International University (11430 : Florida International University Exemption)
Instructions
The following procurement categories may be eligible for exemption from the competitive process based upon the determination
of the County manager or Designee that approval of such an exemption is in the best interest of the County.
Purchases greater than $50,000 will require final approval by the Board of County Commissioners.
Requester Name:Vendor Name:
Division:Item / Service:
Budget Year:1RWWR([FHHG
per Fiscal Year:
One time purchase:Multiple purchases:Requested
date range:_________________
Is there an agreement
associated with this
Exemption?
Yes No
1. Government Agency/Non-
Profit
2. Registrations/dues/
training
3. Subscriptions/periodicals/
printed materials
4. Advertisements
5. Utility services –subject
to government control
6. Education/academic
programs/trainers, speakers
7. Legal services 8. Purchases required by
grants/gifts
9.Compatibility/proprietary
with current systems
10. Shop estimates on
disassembled equipment
11. Personnel/recruitment
services
2. Works of art for public
display
13. Direct purchases 14. Financial instruments 15. Entertainment services
for County sponsored events
16. Management studies as
directed by County Manager
17. Resolution/BCC direction (Indicate resolution number and approval date):
Description of Purchase:Enter a description of the item(s) items that will be purchased under this exemption.
Purpose:Describe in detail, the purpose of the requested item(s).
Requester:Signature: Date:
Division Director: Signature: Date:
Procurement Strategist: Signature: Date:
Procurement Director:
2UGHVLJQHH
Signature: Date:
For Procurement Use Only:
One time approval One year approval Multi-Year Approval: Start ____________ End ____________
Exemptions from the Competitive Process
Rhonda Watkins Florida International University
Pollution Control Sucralose Analysis
FY20 $15,000
12/1/2019-9/30/2020
Analysis of sucralose in surface water
Sucralose, artificial sweetener, does not naturally occur in the environment. Sucralose is not metabolized by the body or removed by
the wastewater treatment process. It is highly soluble and remains persistent in the environment with a half-life of over one year. This
makes sucralose ideal for tracing wastewater impacts (nutrients) in surface and groundwater. However, sucralose is known to be
present in reuse irrigation water making it ubiquitous in surface and groundwater resources influenced by reuse irrigation. Some
preliminary monitoring done by FDEP and Collier County Pollution Control have shown the presence of sucralose in various water
resources. In order to establish a baseline of sucralose in surface water in Collier County, the County’s trend network will be sample
and analyzed for sucralose during each quarter of FY20, even in areas with known reuse irrigation. This baseline sucralose data will
help establish evidence of existing and future wastewater impacts, while providing comparative data to track the success of any
remediation projects. FIU has previously analyzed sucralose in groundwater for Collier County Pollution Control.
Rhonda Watkins 12/6/2019
Amy Patterson
Sara Schneeberger
Catherine Bigelow
01/03/2020 09/30/2020
watkins_r Digitally signed by watkins_r
Date: 2019.12.06 15:31:10
-05'00'
Amy Patterson Digitally signed by Amy Patterson
Date: 2019.12.11 12:37:44 -05'00'
SchneebergerSara Digitally signed by
SchneebergerSara
Date: 2020.01.03 13:02:11 -05'00'
Cat Bigelow Digitally signed by Cat Bigelow
DN: cn=Cat Bigelow, o=Collier County
Government, ou=Procurement Services,
email=catherinebigelow@colliergov.net, c=US
Date: 2020.01.09 09:33:26 -05'00'
16.A.21.b
Packet Pg. 1472 Attachment: FY20 Exemption Request 146 - FL International University (11430 : Florida International University Exemption)