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Backup Documents 06/03/2015 PELICAN BAY SERVICES DIVISION Municipal Service Taxing & Benefit Unit NOTICE OF PUBLIC MEETING JUNE 3, 2015 THE PELICAN BAY SERVICES DIVISION BOARD WILL MEET ON WEDNESDAY, JUNE 3 AT 1 PM AT THE COMMUNITY CENTER AT PELICAN BAY, LOCATED AT 8960 HAMMOCK OAK DRIVE, NAPLES, FLORIDA 34108. AGENDA 1. Pledge of Allegiance 2. Roll call 3. Agenda approval 4. Approval of May 6 meeting minutes 5. Audience comments 6. * CIP Phase 3 landscaping plans 7. * Multi-way stop at North Pointe Drive & Pelican Bay Boulevard 8. * Beach renourishment 9. * Bids for Oak Lake Sanctuary lake bank work 10. * Oak Lake Sanctuary swale 11. * Bids for Oakmont lake bank work 12. *Water parameters for berm sites 13. * Clam Bay pilot oyster program 14. * Brazilian pepper removal 15. * Fiscal Year 2016 Budget 16. Administrator's report a. April financial report b. May financial report 17. Committee reports a. Beach renourishment b. Budget c. Clam Bay d. Landscape & Safety e. Water Management 18. Chair's comments a. PBSD & PBF landscaping b. Topics for future meetings 19. Unfinished business 20. New business 21. Adjournment * asterisk indicates possible Board action item ANY PERSON WISHING TO SPEAK ON AN AGENDA ITEM WILL RECEIVE UP TO THREE (3) MINUTES PER ITEM TO ADDRESS THE BOARD.THE BOARD WILL SOLICIT PUBLIC COMMENTS ON SUBJECTS NOT ON THIS AGENDA AND ANY PERSON WISHING TO SPEAK WILL RECEIVE UP TO THREE (3) MINUTES. THE BOARD ENCOURAGES YOU TO SUBMIT YOUR COMMENTS IN WRITING IN ADVANCE OF THE MEETING.ANY PERSON WHO DECIDES TO APPEAL A DECISION OF THIS BOARD WILL NEED A RECORD OF THE PROCEEDING PERTAINING THERETO, AND THEREFORE MAY NEED TO ENSURE THAT A VERBATIM RECORD IS MADE,WHICH INCLUDES THE TESTIMONY AND EVIDENCE UPON WHICH THE APPEAL IS TO BE BASED. IF YOU ARE A PERSON WITH A DISABILITY WHO NEEDS AN ACCOMMODATION IN ORDER TO PARTICIPATE IN THIS MEETING YOU ARE ENTITLED TO THE PROVISION OF CERTAIN ASSISTANCE. PLEASE CONTACT THE PELICAN BAY SERVICES DIVISION AT(239)597-1749 OR VISIT PELICANBAYSERVICESDIVISION NET. 5/29/2015 3:36:40 PM From: Jim Carr [mailto:jim.carr @abbinc.com] Sent: Wednesday, June 03, 2015 9:25 AM To: ResnickLisa; Kevin Carter Subject: Oak Lake Sanctuary- proposed swale Lisa, A proposed swale from the existing US41 culverts to the Oak Lake Sanctuary lake is approximately 350 linear feet. The swale would likely have a 10-15 foot wide bottom and be approximately 25 to 30' wide at the top to convey the peak stormwater volume from Pine Ridge contributing area. Based on this concept, attached is a preliminary opinion of cost for the earthwork grading, bahia sod, rip rap at the US41 pipes,and associated work. The unit costs are estimated higher than normal based on the recent bids received at Oak Lake. Engineering design for the runoff flow and swale capacity calculations, and prepare construction plans and permitting,the estimated budget is$8,000 to 10,000. Let me know if question. Ja 444-44'A. Carr, P.E. Agnoli,Barber&Brundage,Inc. 7400 Tamiami Trail North,Suite 200 Naples,FL 34108 239.5973111 ext 215 239.566.2203 fax Agnoli,Barber&Brundage, Inc Engineer's Preliminary Opinion of Probable Cost(Conceptual) June 2,2015 PN 15-0019 Pelican Bay-Oak Lake Sanctuary Swale Concept Item No. Description Unit Quantity Unit Total Cost Cost 1 MOBILIZATION LS 1 $10,000.00 $10,000.00 2 RIP-RAP WITH FILTER FABRIC MIRAFI 140N SY 30 $80.00 $2,400.00 3 SOD(Bahia) SY 1,200 $8.00 $9,600.00 4 GRADE SWALE and adjacent slope/bank SY 3,000 $5.00 $15,000.00 5 STAKED TURBIDITY BARRIER/EROSION CONTROL LF 100 $20.00 $2,000.00 TOTAL $39,000.00 10%CONTINGENCY $3,900.00 TOTAL 110%OF PROBABLE COST $42,900.00 Quantities based on rough estimate of swale length and width from aerial plan view r 9,° ERc0^�r CENTRAL BROWARD WATER CONTROL DISTRICT f 9 `' ° 8020 STIRLING ROAD(DAVIE) Z ' HOLLYWOOD.FLORIDA 33024 F. t www.centralbrowardwcd.org cygp�q' }20�g'`� BOARD OF COMMISSIONERS TELEPHONE (954)432-5110 -9....„7-P, MAY FAX (954)432-8603 Angie Leto.Chair E-Mail distnctmanagerCcentralbrowardwcd org Judy Ann Bunce.Vice-Chair Douglas R.Bell David Donzella Cris Fardelmann Mark Flynt May 20, 2015 Water Management Districts: Central Broward Water Control District has used Pro-Teck, purchased from Magna-Bon II, LLC, for the past 15 years. We have found it to be a cost effective algae control. If you have any questions, please call me at 954-432-5110. Sincerely, Mike Crowley, District Manager MAGNA-BON PRO-TECK CANAL OR POND USAGE WITH A HERBICIDE Magna-Bon Pro-Teck may be applied by itself on pond scum and algae, as shown on the label. If you need to use a herbicide, you can use Magna-Bon Pro-Teck with it to eliminate the algae bloom that will be created when the aquatic weeds die due to the herbicide application. Magna-Bon Pro-Teck has been used extensively by Water Control Districts in South Florida for this application for over 10 years. In a 90 gallon tank mix the following: 2 1/2 gallons Magna-Bon Pro-Teck 3/4 gallons Reward or 1/2 gallon 2-4-D (Alternate every few sprays) 1 gallon any Sinker This mixture will cover 5/8 of an acre It is applied by dragging If you can have an initial spray and then go back and spray again within 10-14 days, you can probably really knock it back for awhile. From: Adam LWDD, Aquatic Director In a 100 gallon tank mix: 2 gallons Reward 5 gallons Pro-Teck 1 gallon Any sinker Agitate. This mixture will cover approx. .4 of a mile x 30' wide x 4' deep It is applied by dragging. From: Bryon CBWCD, Aquatics BRIEF HISTORY OF MAGNA BON Magna-Bon is an Okeechobee based supplier of chemicals used in at least 17 (seventeen) states in the United States and soon South America, for the purpose of prevention and elimination of algae and aquatic plant life, as well as eliminating certain fungal and bacterial disease associated with produce, including fruits, vegetables, fish, meat and poultry. The product itself is a patented formula (U.S. Patent No. 163,709) which is modified for various uses based upon application and user requirements. Originally created by inventors and scientists Robert Cook and John Kennedy, the patent rights were ultimately sold to Frank Miele, the current president, who has been the owner of the company, since December 2004. While the possible benefits of the product were recognized by the initial owners, none had sufficient marketing or field experience to effectively present the product and its derivatives to potential buyers. Frank Miele began efforts in earnest shortly after his acquisition of the rights to the products. Since December 2004, Magna-Bon has grown from One-Hundred and Seventy Five Thousand ($175,000.00) dollars in sales to Three Million, Five- Hundred Thousand ($3,500,000.00) dollars in sales. New applications for the product are being discovered on a regular basis and have been a key factor in growth which is expected to reach Five-Million ($5,000,000.00) dollars in total sales by 2017. USES AND APPLICATION TECHNIQUES OF MAGNA BON PRODUCTS Magna Bon sells its products for a broad spectrum of uses including but not limited to post harvest wash of fresh produce, antimicrobial wash, foliar spray or water treatment for the control of various diseases in garden row, field and tree crops, on hard surface areas such as equipment from infected fields, or in hospitals, homes, etc. as well as against a wide range of human, plant and animal diseases. Additionally, the composition of the present patented formulation is approved by the FDA and EPA to coat, treat, and disinfect food products such as but not limited to fish and shellfish, meat, milk, poultry, eggs and irrigated crops (both food and nonfood crops), as well as non food products as defined in the EPA exemption from tolerance for copper and copper products. The composition may include inerts such as surfactants, detergents and buffers to adjust the pH. The composition remains soluble in water and is useful and efficacious against the spread of bacteria, viruses, fungi and other pathogens within a source of water such as a reservoir or pool. Alternatively, the composition may be in aerosolized, misted, vaporized, fogged, humidified forms to produce micronized particles which are able to remain in suspension in the air for long periods of time in order to act on air-borne fungal spores and/or pathogens. Magna Bon is approved for quality control by IS09000 and quality control is an integral part of our day to day operations. OUR UNDERSTANDING OF THE PROBLEMS FACING PELICAN BAY SERVICES DIVISION It is our understanding that Pelican Bay Service Division may be facing opposition from Board Members and unit owners of Pelican Bay and Pelican Marsh with regards to the use of copper sulfate because of a heightened level of copper sulfate being found in aquatic life in the waters of Clam Bay. Although we are unaware of the exact levels of copper sulfate being found in the aquatic life or the rate of increase, we are familiar with the problem as a symptom of using copper sulfate in salt/solid form which is merely in solution. This method of treatment leads to eventual settling out of copper sulfate as a metal salt, into the sediment of bodies of water. Over several months or even years, the level of copper sulfate now resting in the sediment increases mutifold and a strong rain event will result in a "flushing" of the sediment and associated copper sulfate in concentration levels which may be as high as 30 times the level of original application. These flushing events inundate the aquatic life in the Clam Bay area and greatly inhibits the fauna's ability to readily process the copper sulfate out of their systems simply because of the high dosage levels. The end result is that after inundation with copper sulfate, animals such as fish and shell fish are repeatedly dosed with fairly regular doses of copper sulfate with the return of every rainy season. Rather than a slow natural dissipation of copper salts, there is never sufficient time to metabolize the chemical before another round of inundation. MAGNA BON SOLUTIONS Magna Bon has been providing solutions to the South Florida Water Management District for over ten (10) years. Our product works without the settling out of metal salts by the patented formula which keeps the copper sulfate in solution as the result of the ionic charge for the five (5) water molecules bound to the copper sulfate. Testing sample of our products show that the copper sulfate is kept in solution indefinitely so that it will not settle out of solution and embed metal salts at the bottom of a body of water. This prevents buildup of copper sulfate and maintains copper sulfate levels at 1-2 ppm as opposed to sudden elevations and discharges of 30 ppm or more. Initially, Magna-Bon would propose testing a small body of water such as might be found at Pelican Bay and checking the copper sulfate in solution of the sediment so as to establish a baseline. Magna-Bon proposes that the isolated body of water be treated with one of our patented derivatives such as Cascada or Proteck, and then monitored for a certain period of time. Our goal would be to maintain the concentration of copper sulfate pentahydrate at 1-2 ppm. Although this may require the addition of chemicals after a heavy rain storm, it would be necessary in order to maintain the minimum copper sulfate level to deter algae and aquatic life from growing while avoiding "overdosing" the system. THE RIGHT MAGNA-BON PRODUCTS FOR PELICAN BAY SERVICES DIVISION Magna-Bon products such as Cascada, and Proteck which are typically used for treatment of undesirable algae and build up of aquatic life offer a viable and highly preferable alternative to the former methods of water treatment used by the Pelican Bay Services Division. The application rate is readily calculated by initially determining the cubic feet of water contained in each particular water system ( avg. length x avg. width x avg depth). This is then multiplied by 7.5 to determine the gallons of water contained in the particular body of water. The number of gallons is then divided by fifty-thousand (50,000) to determine the amount of Pro-Teck or Cascada. ADDITIONAL INFORMATION AS TO OUR PRODUCTS Magna-Bon's unique formulation is approved by the Organic Materials Review Institute for safety, reliability and minimal environmental impact. Additional information about our products can be obtained on our website at www.magnabon.com. Additional references from both governmental and commercial entities will be provided upon request. � gna-Bon® 'olm■••'• AGRICULTURAL CONTROL SOLUTIONS PRO-TECK ALGICIDE/BACTERICIDE •N ��- FOR WATER IN LAKES, PONDS, RESERVOIRS AND IRRIGATION CONVEYANCE SYSTEMS Ingredients Active Ingredient: Copper Sulfate Pentahydrate* (CAS 7758-99-8) 19.8% Other Ingredients. 80.2% Total 100.0% *Equivalent to 5.0% metallic copper A Chelated Copper Product EPA REG. NO. 66675-4 EPA EST. NO. 66675-FL-001 LOT NO. Net Contents: 1 U.S. Gallon 9.45 Liters 9.9 Lbs. Per U.S. Gallon 1.188 kg/I Manufactured by: Magna-Bon II, LLC. 1531 NW 25th Drive Okeechobee, Fl. 34972-2046 1-863-357-0400 KEEP OUT OF REACH OF CHILDREN DANGER / PELIGRO Si usted no entiende la etqueta.busque.an alguien pars que se la explique and usted en detalle.(If you do not understand this label,find someone to explain it to you in detail) FIRST AID If in Eyes • Hold eye open and rinse slowly and gently with water for 15- 20 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. • Call a poison control center or doctor for treatment. If Swallowed • Call a poison control center or doctor immediately for treatment advice. • Have a person sip a glass of water if able to do so. • Do not induce vomiting unless told to do so by a poison control center or doctor. • Do not give anything to an unconscious person. If Inhaled • Move person to fresh air. • If person is not breathing, call 911 or an ambulance, and then give artificial respiration, preferably by mouth-to-mouth, if possible. If on Skin • Take off contaminated clothing. • Rinse skin immediately with plenty of water for 15-20 minutes. • Call a poison control center or doctor for treatment advice. HOT LINE NUMBER Have the product container or label with you when calling a Poison Control Center or Doctor or going for treatment. You may also contact 1-800-424-9300 (Chemtrec) for emergency medical treatment information. DIRECTIONS FOR USE It is a violation of Federal Law to use this product in a manner inconsistent with its labeling. Waters treated with this product may be hazardous to aquatic organisms. Treatment of aquatic weeds and algae can result in oxygen loss from decomposition of dead algae and weeds. This oxygen loss can cause fish and invertebrate suffocation. To minimize this hazard, do not treat more than 1/2 of the water body to avoid depletion of oxygen due to decaying vegetation. Wait at least 10 to 14 days between treatments. Begin treatments along the shore and proceed outwards in bands to allow fish to move into untreated areas. Consult with the State or local agency with primary responsibility for regulation pesticides before applying to public waters, to determine if a permit is required. PRODUCT USES: Magna-Bon Pro-Teck is a copper sulfate pentahydrate formulation used to control odors and algae in lakes, ponds, reservoirs and irrigation conveyance systems. Using water containing moderate to high amounts of sulfur may cause Magna-Bon Pro- Teck to neutralize. Whenever possible, use a compatibility jar test before mixing a whole tank. FOR TREATING WATER IN LAKES, PONDS AND RESERVOIRS: This product is not intended to produce water that meets drinking water standards. For suppression of bacterial odors and for control of algae, apply in late spring or early summer when algae and bacteria first appear. The dosages are variable and depend upon algae/bacteria species, water hardness, water temperature, amount of algae/bacteria present, as well as whether water is clear, turbid, flowing or static. Preferably, the water should be clear with the temperature above 60EF or 15.6EC. Higher dosages are required at lower temperatures, higher algae/bacterial concentration, and for hard waters. Application of Magna-Bon Pro-Teck may be done in a variety of ways including, but not limited to, pouring the required amount directly from the container into lakes, ponds, reservoirs or irrigation canals. It may be applied by first diluting the required amount of this product with enough water to ensure even distribution with the type of equipment being used and then applied through hand or power sprayer or underwater injection. Several application points speed up dispersal. Static water requires less chemical for algae/bacteria control than does flowing water. Use higher doses for Chara and Nitella (aquatic plants) and lower doses for filamentous algae (pond scum) and planktonic algae. If there is uncertainty about the dosages, begin with a lower dose and increase until control is achieved, or until the maximum allowable level has been reached. The application rates in the chart below are based on static or flow conditions. Identify the algae/aquatic plant growth present as one of the following: planktonic, filamentous, Chara or Nitella. # Determine the surface area and average depth treated. # Refer to the chart below to determine gallons of Magna-Bon Pro-Teck to apply per surface acre. Application Rates Gallons per Surface Acre Algae/Aquatic Plant ppm Copper Average Depth in Feet 1 2 3 4 Planktonic 0.2 1.1 2.2 3.3 4.4 Filamentous 0.2 1.1 2.2 3.3 4.4 Chara 0.4 2.2 4.4 6.6 8.8 Nitella 0.4 2.2 4.4 6.6 8.8 Odor Control 1.0 5.45 10.9 16.3 21.8 Application rates for depths greater than 4 feet may be obtained by adding the rates above to give proper depth. Do not exceed a copper concentration of 1.0 ppm copper in treated water. One acre/foot = 326,000 gallons (one acre = 43,560 square feet) Cubic feet X 7.48 = gallons Treatment of algae can result in oxygen loss from the decomposition of dead algae. This loss can cause fish suffocation. If the algae cover more than one-third (1/3) of the total water area, treat in sections. Treat one-third (1/3) to one-half (2) of the water area in a single operation and wait ten (10) to fourteen (14) days between treatments. Begin treatment along the shore and proceed outward in bands to allow fish to move to untreated areas. In regions where ponds freeze in winter, treatment should be done six (6) to eight (8) weeks before expected freeze to prevent masses of decaying algae under an ice cover. Trout and certain other species of fish may be killed at recommended application rates, especially in soft or acidic waters. Before treating bodies of water, consult proper State authorities, such as fisheries commission or conservation department to obtain any necessary permits. For algae/bacterial odor control, apply one (1) gallon Magna-Bon Pro-Teck to each sixty thousand (60,000) gallons of water. For treating waters destined to be used as potable water (after passing through a drinking water treatment plant), do not exceed one (1) gallon Magna-Bon Pro-Teck to each sixty thousand (60,000) gallons of water (1 ppm copper). IRRIGATION CONVEYANCE SYSTEMS In Irrigation Conveyance Systems: For continuous addition, add one (1) gallon Magna- Bon Pro-Teck to each sixty thousand (60,000) gallons of water. For conveyance systems longer than ten (10) miles, it is recommended that the above dosage be dispersed among injection points every ten (10) miles. However, do not exceed the total dosage of one (1) gallon Magna-Bon Pro-Teck to each sixty thousand (60,000) gallons of water. STORAGE and DISPOSAL Do not contaminate water, food or feed by storage and disposal. PESTICIDE STORAGE: • Store in a safe place away from PETS AND KEEP OUT OF THE REACH OF CHILDREN. • Store away from excessive heat. • Magna-Bon Pro-Teck will freeze. • Always keep container closed. • Store Magna-Bon Pro-Teck in its original container only. • Bulk Magna-Bon Pro-Teck shall be stored in 316 L stainless steel, fiberglass, PVC's, polypropylene or plastic equipment. • Keep away from galvanized pipe or any nylon storage equipment. PESTICIDE DISPOSAL: • Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. • If empty: Do not reuse this container. Place in trash or offer for recycling if available. • If partially filled: Call your local solid waste agency for disposal instructions. Never place unused product down any indoor or outdoor drain. • Excess Magna-Bon Pro-Teck should be disposed of through label use. • Do not contaminate lakes, rivers or streams as it may cause fish kill. • Pesticide wastes are hazardous, improper disposal of excess waste, spray mixture or rinsate is a violation of Federal law. • If these wastes cannot be disposed of by use according to the label instructions, contact your State Pesticide or Environmental Control Agency, or Hazardous Waste representative at the nearest EPA Regional Office for guidance. In the event of a spill, neutralize with limestone or baking soda before disposal. • Concentrate may deteriorate concrete. CONTAINER DISPOSAL: • Triple rinse or equivalent. • Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incineration or if allowed by state and local authorities by burning. • If burned, stay out of smoke. • Rinsing and re-use of "totes" is permissible. DANGER / PELIGRO Si usted no entiende la etqueta.busque,an alguien Para que se la explique and usted en detalle.Of you do not understand this label,find someone to explain it to you in detail) PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals DANGER Corrosive: May cause irreversible eye damage. Do not get into eyes or on clothing. Wear goggles or safety glasses. Harmful if swallowed, inhaled or absorbed through the skin. May cause allergic skin response. Avoid contact with eyes, skin or clothing. Avoid breathing vapor or spray mist. Remove contaminated clothing and wash before re-use. Wash thoroughly with soap and water after handling. Potable water sources treated with copper products may be used as drinking water only after proper additional potable water treatments. ENVIRONMENTAL HAZARDS Do not apply directly to water, except as specified on this label. Do not contaminate water by disposal of equipment washwaters or rinsate. APPLICATION AND HANDLING EQUIPMENT Application, handling or storage equipment must consist of either fiberglass, PVC=s, polypropylene, viton, most plastics or 316L stainless steel. Never use mild steel, nylon, brass, or copper around full strength Magna-Bon Pro-Teck. Always rinse equipment free and clean of Magna-Bon Pro-Teck with plenty of fresh clean water. Concentrated will destroy cotton and nylon clothing. Always store Magna-Bon Pro-Teck above 32EF. Do not allow Magna-Bon Pro-Teck to freeze. Freezing may cause separation. Seller makes no warranty for the performance of product that has been frozen. LIMITED WARRANTY AND LIMITATION OF REMEDIES Seller warrants that the product conforms to the chemical description and is reasonably fit for the purpose stated on the label for use under normal conditions, but makes no other warranties of FITNESS OR MERCHANTABILITY expressed or implied, or any other warranty if the product is used contrary to the label instructions or under abnormal conditions not foreseeable to the seller. In no case shall the seller be liable for more than the cost of the product to the buyer, and will in no event be liable for any consequential, special or indirect damages connected with the use or handling of this product. This product is offered and the buyer or user accepts its subject to the forgoing terms which may not be varied. Material Safety Data Sheet Department of Labor May be used to comply with OSHA's Hazard Communication Occupational Safety and Health Administration Standard, 29 CFR 1910.1200. This standard must be consulted (Non-Mandatory Form) for specific requirements. Form Approved OMB No. 1218-00782. IDENTITY: MAGNA-BON PRO-TECK SECTION 1 : Manufacturer: Magna-Bon II, LLC Emergency Phone Number: 800-424-9300 (Chemtrec) 1531 N.W. 25th Drive Information Phone Number: 863-357-0400 Okeechobee, Fl. 34972 Date Prepared: 9/2013 Signature of Preparer (optional): Section 2: Hazard Ingredients / Identity Information Hazardous Components: OSHA ACGIH Other limits (Specific Chemical Identity; Common Name(s) PEL TLV Recommended (optional) None Not Not Not Relevant Not Relevant Relevant Relevant Active Ingredients: Copper Sulfate Pentahydrate* (CAS 7855-99-8) 19.8% Other Ingredients. 80.2% Total. 100.0% *Equivalent to 5% metallic copper Components not precisely identified are proprietary or non hazardous Section 3: Physical / Chemical Characteristics Boiling Point: 220 °F Specific Gravity (H20=1): 1.18 Vapor Pressure (mm Hg.): 0.1 mm 68°F Melting Point: None Vapor Density (AIR=1): 1.00 Evaporation Rate (Butyl Acetate=1): None Solubility in Water: Very Soluble Appearance and odor: Clear blue liquid mild odor. Material Safety Data Sheet Department of Labor May be used to comply with OSHA's Hazard Communication Occupational Safety and Health Administration Standard, 29 CFR 1910.1200. This standard must be consulted (Non-Mandatory Form) for specific requirements. Form Approved OMB No. 1218-00782. Section 4: Fire and Explosion Hazard Data Flash Point (Method Used): None Flammable Limits: None LEL: Not Available UEL: Not Available Extinguishing Media: Non-flammable Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None Section 5: Reactivity Data Stability: Unstable: No Conditions to Avoid: Avoid mixing with strong bases and strong reducing agents. Stable: Yes Incompatibility (Materials to Avoid): Avoid mixing with strong bases and strong reducing agents. Hazardous Decomposition or Byproducts: Sulfuric acid fumes may be generated by thermal decomposition. Hazardous May Occur: No Conditions to Avoid: None Polymerization: Will not Occur: Yes Section 6: Health Hazard Data Route(s) of Entry: Inhalation?Yes Skin? Yes Ingestion? Yes Health Hazards (Acute and Chronic): Avoid breathing fumes: Products contains elemental copper. Ingesting may cause acute copper toxicity. Carcinogenicity: NTP? IARC Monographs? OSHA Regulated? Signs and Symptoms of Exposure: Allergies may occur. Skin irritation may occur. Avoid prolonged body contact. (Always use protective clothing) Medical Conditions Generally Aggravated by Exposure: Sulfur allergies may occur. Emergency and First Aid Procedures: Treat as a sulfur base reaction . Material Safety Data Sheet Department of Labor May be used to comply with OSHA's Hazard Communication Occupational Safety and Health Administration Standard, 29 CFR 1910.1200. This standard must be consulted (Non-Mandatory Form) for specific requirements. Form Approved OMB No. 1218-00782. Section 6: Health Hazard Data (cont'd) Emergency and First Aid Procedures (cont'd): Eyes: •Hold eye open and rinse slowly and gently with water for 15-20 minutes. •Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. •Call a poison control center or doctor for treatment advice. Swallowed: •Call a poison control center or doctor immediately for treatment advice. •Have a person sip a glass of water if able to swallow. •Do not induce vomiting unless told to by a poison control center or doctor. •Do not give anything to an unconscious person. Inhaled: •Move person to fresh air. •If person is not breathing, call 911 or an ambulance, and then give artificial respiration, preferably mouth-to-mouth if possible. •Call a poison control center or doctor for further treatment advice. Skin: •Take off contaminated clothing. •Rinse skin immediately with plenty of water for 15-20 minutes. •Call a poison control center or doctor for treatment advice. Section 7: Precautions for Safe Handling and Use Steps to be Taken in Case Steps to be Taken in Case Material is Released or Spilled: Flush with water into a Material is Released or Spilled: retaining tank. Contain and neutralize with bicarbonate of soda or fertilizer grade limestone. Waste Disposal Method: Neutralize with bicarbonate of soda or fertilizes grade limestone and dispose of in accordance with all Federal, State and Local Regulations. Precautions to be Taken in Avoid storage in excessive heat, expansion of container may occur creating spillage. Handling and Storage: Other Precautions: DO NOT STORE in nylon or galvanized equipment. Concentrate will destroy nylon and cotton cloth. Material Safety Data Sheet Department of Labor May be used to comply with OSHA's Hazard Communication Occupational Safety and Health Administration Standard, 29 CFR 1910.1200. This standard must be consulted (Non-Mandatory Form) for specific requirements. Form Approved OMB No. 1218-00782. Section 8: Control Measures Respiratory Protection (Specify Type): Adequate local ventilation Ventilation: Yes Local Exhaust: Yes Special: None Mechanical (General): None Other: None Protective Gloves: Yes Eye Protection: Yes Work/ Hygienic Practices: Body shower after prolong skin contact. Other Protective Clothing or Equipment: •goggles •gloves made of any waterproof material •long-sleeved shirt •long pants •shoes plus socks Disclaimer: The information set forth herein is furnished free of charge and is based on data that The New Magna-Bon Corp., Inc. believes to be reliable It is intended for use by persons having technical skill and at their own discretion and risk. Since conditions of use outside of our control, we make no warranties, express or implied, and assume no liability in connection with any use of the information. Nothing herein is to be taken as a license to operate under or a recommendation to infringe any patents. Prepared By: Magna-Bon II, LLC. Date Prepared: September 2013 Copper Sulfate Pentahydrate; Exemption from the Requirement of a Tolerance Note: EPA no longer updates this information, but it may be useful as a reference or resource. [Federal Register: November 15, 2000 (Volume 65, Number 221) ] [Rules and Regulations] [Page 68908-68912] From the Federal Register Online via GPO Access [wais.access.gpo.gov] [DOCID:frl5no00-231 ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 180 [OPP-301060; FRL-6747-3] RIN 2070-AB78 Copper Sulfate Pentahydrate; Exemption from the Requirement of a Tolerance AGENCY: Environmental Protection Agency (EPA) . ACTION: Final rule. SUMMARY: This regulation establishes an exemption from the requirement of a tolerance for residues of copper sulfate pentahydrate when applied as a fungicide to raw agricultural commodities after harvest. Magna Bon Corporation submitted a petition to EPA under the Federal Food, Drug, and Cosmetic Act, as amended by the Food Quality Protection Act of 1996 requesting an exemption from the requirement of a tolerance. This regulation eliminates the need to establish a maximum permissible level for residues of copper sulfate pentahydrate. In this final rule, the Agency is also reordering the structure of 40 CFR 180.1001(b) (1) and 180.1021 to group most of the copper exemptions together. The reordering does not change the regulatory status of these chemicals. DATES: This regulation is effective November 15, 2000. Objections and requests for hearings, identified by docket control number OPP-301060 must be received by EPA on or before January 16, 2001. ADDRESSES: Written objections and hearing requests may be submitted by mail, in person, or by courier. Please follow the detailed instructions for each method as provided in Unit VIII. of the SUPPLEMENTARY INFORMATION. To ensure proper receipt by EPA, your objections and hearing requests must identify docket control number OPP-301060 in the subject line on the first page of your response. FOR FURTHER INFORMATION CONTACT: By mail: Treva Alston, Registration Division (7505C) , Office of Pesticide Programs, Environmental Protection Agency, 1200 Pennsylvania Ave., NW., Washington, DC 20460; telephone number: (703) 308-8373; and e-mail address: aiston.trevaaepa.gov. SUPPLEMENTARY INFORMATION: I. General Information A. Does this Action Apply to Me? You may be affected by this action if you are an agricultural producer, food manufacturer, or pesticide manufacturer. Potentially affected categories and entities may include, but are not limited to: Examples of Categories NAICS Potentially Affected Entities Industry 111 Crop production 112 Animal production 311 Food manufacturing 32532 Pesticide manufacturing This listing is not intended to be exhaustive, but rather provides a guide for readers regarding entities likely to be affected by this action. Other types of entities not listed in the table could also be affected. The North American Industrial Classification System (NAICS) codes have been provided to assist you and others in determining whether or not this action might apply to certain entities. If you have questions regarding the applicability of this action to a particular entity, consult the person listed under FOR FURTHER INFORMATION CONTACT. [ [Page 68909] ] B. How Can I Get Additional Information, Including Copies of this Document and Other Related Documents? 1. Electronically. You may obtain electronic copies of this document, and certain other related documents that might be available electronically, from the EPA Internet Home Page at http://www.epa.gov/. To access this document, on the Home Page select "Laws and Regulations, " "Regulations and Proposed Rules, " and then look up the entry for this document under the "Federal Register--Environmental Documents. " You can also go directly to the Federal Register listings at http://www.epa.gov/fedrgstr/. 2. In person. The Agency has established an official record for this action under docket control number OPP-301060. The official record consists of the documents specifically referenced in this action, and other information related to this action, including any information claimed as Confidential Business Information (CBI) . This official record includes the documents that are physically located in the docket, as well as the documents that are referenced in those documents. The public version of the official record does not include any information claimed as CBI. The public version of the official record, which includes printed, paper versions of any electronic comments submitted during an applicable comment period is available for inspection in the Public Information and Records Integrity Branch (PIRIB) , Rm. 119, Crystal Mall #2, 1921 Jefferson Davis Hwy., Arlington, VA, from 8:30 a.m. to 4 p.m., Monday through Friday, excluding legal holidays. The PIRIB telephone number is (703) 305-5805. II. Background and Statutory Findings In the Federal Register of July 14, 1999 (64 FR 37972) (FRL -6085- 5) , EPA issued a notice pursuant to section 408 of the Federal Food, Drug, and Cosmetic Act (FFDCA) , 21 U.S.C. 346a, as amended by the Food Quality Protection Act (FQPA) (Public Law 104-170) announcing the filing of a pesticide petition (PP 8F4982) by Magna Bon Corporation, 3213 Ocean Drive, Vero Beach, Florida 32963. This notice included a summary of the petition prepared by the petitioner. There were no comments received in response to the notice of filing. Various copper containing substances have been exempted from tolerance requirements for numerous uses. 40 CFR 180.1001 (b) (1) exempts the listed copper compounds when applied to growing crops. However, these substances are not exempted from the requirement of a tolerance when applied to a crop at the time of or after harvest. Other exempted uses of copper include harvested fish and shellfish, meat, milk, poultry, eggs, and irrigated crops as specified in 40 CFR 180.1021. The petition requested that copper sulfate pentahydrate be exempted from the requirement of a tolerance when applied to raw agricultural commodities at 0.050 ppm. The Agency does not generally grant an exemption from the requirement of tolerance with a numerical limitation. Section 408 (b) (2) (A) (i) of the FFDCA allows EPA to establish an exemption from the requirement for a tolerance (the legal limit for a pesticide chemical residue in or on a food) only if EPA determines that the tolerance is "safe. " Section 408(b) (2) (A) (ii) defines "safe " to mean that "there is a reasonable certainty that no harm will result from aggregate exposure to the pesticide chemical residue, including all anticipated dietary exposures and all other exposures for which there is reliable information. " This includes exposure through drinking water and in residential settings, but does not include occupational exposure. Section 408(b) (2) (C) requires EPA to give special consideration to exposure of infants and children to the pesticide chemical residue in establishing a tolerance and to "ensure that there is a reasonable certainty that no harm will result to infants and children from aggregate exposure to the pesticide chemical residue. . . . " EPA performs a number of analyses to determine the risks from aggregate exposure to pesticide residues. First, EPA determines the toxicity of pesticides. Second, EPA examines exposure to the pesticide through food, drinking water, and through other exposures that occur as a result of pesticide use in residential settings. III. Toxicological Profile Consistent with section 408(b) (2) (D) of FFDCA, EPA has reviewed the available scientific data and other relevant information in support of this action and considered its validity, completeness and reliability and the relationship of this information to human risk. EPA has also considered available information concerning the variability of the sensitivities of major identifiable subgroups of consumers, including infants and children. The nature of the toxic effects caused by copper sulfate pentahydrate are discussed in this unit. There is adequate information available to characterize the toxicity of the copper ion. Copper is ubiquitous in nature and is a necessary nutritional element for both animals (including humans) , and plants. Copper is found naturally in the food we eat, in the water we drink, in the air we breathe and in our bodies themselves. Some of the environmental copper is due to direct modification of the environment by man such as mining and smelting of the natural ore. It is one of 26 elements found essential to life. The copper ion is present in the adult human body at levels of 80-150 mg. Oral ingestion of excessive amounts of the copper ion from pesticidal uses is unlikely. Copper compounds are irritating to the gastric mucosa. Ingestion of large amounts of copper results in prompt emesis. This protective reflex reduces the amount of copper ion available for absorption into the human body. Additionally, at high levels humans are also sensitive to the taste of copper. Because of this organoleptic property, oral ingestion would also serve to limit high doses. Only a small percentage of ingested copper is absorbed, and most of the absorbed copper is excreted. The copper ion occurs naturally in many foods and the metabolism of copper is well understood. The Agency published a registration standard for copper sulfate in 1985. As indicated in the registration standard, there are several factors unique to copper which indicate that specific studies to fulfill the usual data requirements are not necessary to regulate copper sulfate as a pesticide. One of the foremost of these is the fact that copper is a required nutritional element for both plants and animals. It appears that more evidence is available to define the adverse effects of a deficiency in the diet than to show the toxic effects of an excess intake; in fact, no account has been found in the literature reviewed which describes a toxic effect to normal humans from ingestion of common foodstuffs containing copper. Because copper toxicity to man through the diet has not been shown in normal persons, little is known about the minimum levels of dietary copper necessary to cause evidence of adverse effects. This situation is likely due, to an effective homeostatic mechanism that is involved in the dietary intake of copper and that protects man from excess body copper. This complex mechanism integrates absorption, retention, and excretion to stabilize the copper body burden. Given that copper is ubiquitous and is routinely consumed as part of the daily diet, it is unlikely that with current exposure patterns there would be any long term adverse effects. [ (Page 68910] ] Sulfate has little toxic effect and is routinely used in medicine as a cathartic when combined with magnesium or sodium, the only adverse manifestation from this use being dehydration if water intake is concurrently limited. IV. Aggregate Exposures In examining aggregate exposure, FFDCA section 408 directs EPA to consider available information concerning exposures from the pesticide residue in food and all other nonoccupational exposures, including drinking water from ground water or surface water and exposure through pesticide use in gardens, lawns, or buildings (residential and other indoor uses) . EPA establishes exemptions from the requirement of a tolerance only in those cases where it can be clearly demonstrated that the risks from aggregate exposure to pesticide chemical residues under reasonably foreseeable circumstances will pose no appreciable risks to human health. In order to determine the risks from aggregate exposure to pesticide chemicals, the Agency considers the toxicity of the chemical in conjunction with possible exposure to residues of the chemical through food, drinking water, and through other exposures that occur as a result of pesticide use in residential settings. If EPA is able to determine that a finite tolerance is not necessary to ensure that there is a reasonable certainty that no harm will result from aggregate exposure, an exemption from the requirement of a tolerance may be established. A. Dietary Exposure Copper is ubiquitous in nature and is a necessary nutritional element for both animals (including humans) and plants. It is one of 26 elements found essential to life. The human body must have copper to stay healthy. In fact, for a variety of biochemical processes in the body to operate normally, copper must be part of our diet. Copper is needed for certain critical enzymes to function in the body. Too little copper in the body can actually lead to disease. 1. Food. The main source of copper for infants, children, and adults, regardless of age, is the diet. Copper is typically present in mineral rich foods like vegetables (potato, legumes (beans and peas) , nuts (peanuts and pecans) , grains (wheat and rye) , fruits (peach and raisins) , and chocolate in levels ranging from 0.3 to 3.9 ppm. A single day's diet may contain 10 mg or more of copper. The daily recommended allowance of copper for adults nutritional needs is 2 mg. It is not likely that the approval of this petition would significantly increase exposure over that of the existing levels of copper. 2. Drinking water exposure. Copper is a natural element found in the earth's crust. As a result, most of the world's surface water and ground water that is used for drinking purposes contains copper. The actual amount varies from region to region, depending on how much is present in the earth, but in almost all cases the amount of copper in water is extremely low. Naturally occurring copper in drinking water is safe for human consumption, even in rare instances where it is at levels high enough to impart a metallic taste to the water. The Agency has set a maximum contaminant level for copper at 1.3 ppm because the Agency believes that this level of protection would not cause any potential health problems, i.e. stomach and intestinal distress, liver and kidney damage, and anemia. It is not likely that the approval of this petition would significantly increase exposure over that of the existing levels of copper. B. Other Non-Occupational Exposure Copper compounds have many uses on crops (food as well as non food) and ornamentals as a fungicide. 1. Dermal exposure. Given the prevalence of copper in the environment, no significant increase above current levels would be expected from the dermal non-occupational use of copper sulfate pentahydrate. 2. Inhalation exposure. Air concentrations of copper are relatively low. A study based on several thousand samples assembled by EPA's Environmental Monitoring Systems Laboratory showed copper levels ranging from 0.003 to 7.32 micrograms per cubic meter. Other studies indicate that air levels of copper are much lower. The Agency does not expect the air concentration of copper to be significantly affected by the use of copper sulfate pentahydrate. V. Cumulative Effects The Agency believes that copper has no significant toxicity to humans and that no cumulative adverse effects are expected from long- term exposure to copper salts including copper sulfate pentahydrate. EPA does not have, at this time, available data to determine whether copper compounds have a common mechanism of toxicity with other substances or how to include this inert ingredient in a cumulative risk assessment. For the purposes of this tolerance action, EPA has not assumed that copper compounds have a common mechanism of toxicity with other substances. VI. Determination of Safety for U.S. Population, Infants and Children Copper sulfate pentahydrate is considered as Generally Recognized as Safe (GRAS) by the Food and Drug Administration. EPA has exempted various copper compounds from the requirement of a tolerance when used as aquatic herbicides (40 CFR 180.1021) . Copper compounds are also exempt from the requirements of a tolerance when applied to growing crops when used as a plant fungicide in accordance with good agricultural practices (40 CFR 180.1001 (b) (1) ) . 1. U.S. population. Copper is a component of the human diet and an essential element. Use of copper sulfate pentahydrate is not expected to increase the amount of copper in the diet as a result of its use on growing crops and post harvest use. 2. Infants and children. Copper is also a component of the diet of infants and children and also an essential element of their diet. Because of copper's low toxicity, EPA has not used a safety factor approach to analyze the safety of copper sulfate pentahydrate used in growing crops as well as post harvest. For similar reasons, an additional ten-fold margin of safety is not necessary for the protection of infants and children. Based on the information in this preamble, EPA concludes that there is a reasonable certainty of no harm to the general population, including infants and children, from aggregate exposure to copper sulfate pentahydrate residues. VII. Other Considerations A. Analytical Method(s) An analytical method is not required for enforcement purposes since the Agency is establishing an exemption from the requirement of a tolerance without any numerical limitation. B. Existing Tolerance Exemptions Copper sulfate pentahydrate has been exempted from the requirement of a tolerance under 40 CFR 180.1001(b) (1) when applied to growing crops. C. International Tolerances The Agency is not aware of any country requiring a tolerance for copper sulfate pentahydrate nor have any CODEX Maximum Residue Levels (MRLs) been established for any food crops at this time. VIII. Conclusions Based on the information in this preamble, EPA concludes that there is a reasonable certainty of no harm from [ [Page 68911] ] aggregate exposure to residues of copper sulfate pentahydrate. Accordingly, EPA finds that exempting post harvest uses of copper sulfate pentahydrate from the requirement of a tolerance will be safe. Although the petitioner requested an exemption with a maximum residue limit, the Agency does not generally grant an exemption from the requirement of a tolerance with a numerical limitation. Given the lack of toxicity of this compound, EPA is following its general practice of not establishing a numerical limitation with this exemption. In examining the existing tolerance exemptions for copper compounds, it was observed that the exemptions from the requirement of a tolerance are in two places in the Code of Federal Regulations, 40 CFR 180.1001 (b) (1) and 40 CFR 180.1021. For ease of use, all of these exemptions from the requirement of a tolerance are being placed in 180.1021. While reordering of the structure of the CFR is occurring, there have not been any changes with respect to the exemptions from the requirement of a tolerance of these copper compounds. However, copper sulfate pentahydrate is now exempt from the requirement of a tolerance when applied as a fungicide to growing crops or to raw agricultural commodities after harvest. IX. Objections and Hearing Requests Under section 408 (g) of the FFDCA, as amended by the FQPA, any person may file an objection to any aspect of this regulation and may also request a hearing on those objections. The EPA procedural regulations which govern the submission of objections and requests for hearings appear in 40 CFR part 178. Although the procedures in those regulations require some modification to reflect the amendments made to the FFDCA by the FQPA of 1996, EPA will continue to use those procedures, with appropriate adjustments, until the necessary modifications can be made. The new section 408 (g) provides essentially the same process for persons to "object" to a regulation for an exemption from the requirement of a tolerance issued by EPA under new section 408 (d) , as was provided in the old FFDCA sections 408 and 409. However, the period for filing objections is now 60 days, rather than 30 days. A. What Do I Need to Do to File an Objection or Request a Hearing? You must file your objection or request a hearing on this regulation in accordance with the instructions provided in this unit and in 40 CFR part 178. To ensure proper receipt by EPA, you must identify docket control number OPP-301060 in the subject line on the first page of your submission. All requests must be in writing, and must be mailed or delivered to the Hearing Clerk on or before January 16, 2001. 1. Filing the request. Your objection must specify the specific provisions in the regulation that you object to, and the grounds for the objections (40 CFR 178.25) . If a hearing is requested, the objections must include a statement of the factual issues(s) on which a hearing is requested, the requestor's contentions on such issues, and a summary of any evidence relied upon by the objector (40 CFR 178.27) . Information submitted in connection with an objection or hearing request may be claimed confidential by marking any part or all of that information as CBI. Information so marked will not be disclosed except in accordance with procedures set forth in 40 CFR part 2. A copy of the information that does not contain CBI must be submitted for inclusion in the public record. Information not marked confidential may be disclosed publicly by EPA without prior notice. Mail your written request to: Office of the Hearing Clerk (1900) , Environmental Protection Agency, 1200 Pennsylvania Ave., NW., Washington, DC 20460. You may also deliver your request to the Office of the Hearing Clerk in Rm. C400, Waterside Mall, 401 M St., SW., Washington, DC 20460. The Office of the Hearing Clerk is open from 8 a.m. to 4 p.m., Monday through Friday, excluding legal holidays. The telephone number for the Office of the Hearing Clerk is (202) 260-4865. 2. Tolerance fee payment. If you file an objection or request a hearing, you must also pay the fee prescribed by 40 CFR 180.33(i) or request a waiver of that fee pursuant to 40 CFR 180.33(m) . You must mail the fee to: EPA Headquarters Accounting Operations Branch, Office of Pesticide Programs, P.O. Box 360277M, Pittsburgh, PA 15251. Please identify the fee submission by labeling it "Tolerance Petition Fees. " EPA is authorized to waive any fee requirement "when in the judgement of the Administrator such a waiver or refund is equitable and not contrary to the purpose of this subsection. " For additional information regarding the waiver of these fees, you may contact James Tompkins by phone at (703) 305-5697, by email at tompkins. im @epa.gov, or by mailing a request for information to Mr. Tompkins at Registration Division (7505C) , Office of Pesticide Programs, Environmental Protection Agency, 1200 Pennsylvania Ave. , NW., Washington, DC 20460. If you would like to request a waiver of the tolerance objection fees, you must mail your request for such a waiver to: James Hollins, Information Resources and Services Division (7502C) , Office of Pesticide Programs, Environmental Protection Agency, 1200 Pennsylvania Ave., NW., Washington, DC 20460. 3. Copies for the Docket. In addition to filing an objection or hearing request with the Hearing Clerk as described in Unit VIII.A., you should also send a copy of your request to the PIRIB for its inclusion in the official record that is described in Unit I.B.2. Mail your copies, identified by docket control number OPP-301060, to: Public Information and Records Integrity Branch, Information Resources and Services Division (7502C) , Office of Pesticide Programs, Environmental Protection Agency, 1200 Pennsylvania Ave., NW., Washington, DC 20460. In person or by courier, bring a copy to the location of the PIRIB described in Unit I.B.2. You may also send an electronic copy of your request via e-mail to: opp-docket @epa.gov. Please use an ASCII file format and avoid the use of special characters and any form of encryption. Copies of electronic objections and hearing requests will also be accepted on disks in WordPerfect 6.1/8.0 file format or ASCII file format. Do not include any CBI in your electronic copy. You may also submit an electronic copy of your request at many Federal Depository Libraries. B. When Will the Agency Grant a Request for a Hearing? A request for a hearing will be granted if the Administrator determines that the material submitted shows the following: There is a genuine and substantial issue of fact; there is a reasonable possibility that available evidence identified by the requestor would, if established resolve one or more of such issues in favor of the requestor, taking into account uncontested claims or facts to the contrary; and resolution of the factual issues(s) in the manner sought by the requestor would be adequate to justify the action requested (40 CFR 178.32) . X. Regulatory Assessment Requirements This final rule establishes an exemption from the tolerance requirement under FFDCA section 408 (d) in response to a petition submitted to the Agency. The Office of Management and Budget (OMB) has exempted these types of actions from review under Executive Order 12866, entitled Regulatory Planning and Review (58 FR 51735, October 4, 1993) . This final rule does not contain any information collections subject to OMB approval under the Paperwork [ [Page 68912] ] Reduction Act (PRA) , 44 U.S.C. 3501 et seq., or impose any enforceable duty or contain any unfunded mandate as described under Title II of the Unfunded Mandates Reform Act of 1995 (UMRA) (Public Law 104-4) . Nor does it require any prior consultation as specified by Executive Order 13084, entitled Consultation and Coordination with Indian Tribal Governments (63 FR 27655, May 19, 1998) ; special considerations as required by Executive Order 12898, entitled Federal Actions to Address Environmental Justice in Minority Populations and Low Income Populations (59 FR 7629, February 16, 1994) ; or require OMB review or any Agency action under Executive Order 13045, entitled Protection of Children from Environmental Health Risks and Safety Risks (62 FR 19885, April 23, 1997) . This action does not involve any technical standards that would require Agency consideration of voluntary consensus standards pursuant to section 12(d) of the National Technology Transfer and Advancement Act of 1995 (NTTAA) , Public Law 104 -113, section 12 (d) (15 U.S.C. 272 note) . Since tolerances and exemptions that are established on the basis of a petition under FFDCA section 408 (d) , such as the exemption in this final rule, do not require the issuance of a proposed rule, the requirements of the Regulatory Flexibility Act (RFA) (5 U.S.C. 601 et seq. ) do not apply. In addition, the Agency has determined that this action will not have a substantial direct effect on States, on the relationship between the national government and the States, or on the distribution of power and responsibilities among the various levels of government, as specified in Executive Order 13132, entitled Federalism (64 FR 43255, August 10, 1999) . Executive Order 13132 requires EPA to develop an accountable process to ensure meaningful and timely input by State and local officials in the development of regulatory policies that have federalism implications. " "Policies that have federalism implications" is defined in the Executive Order to include regulations that have "substantial direct effects on the States, on the relationship between the national government and the States, or on the distribution of power and responsibilities among the various levels of government. " This final rule directly regulates growers, food processors, food handlers and food retailers, not States. This action does not alter the relationships or distribution of power and responsibilities established by Congress in the preemption provisions of FFDCA section 408(n) (4) . XI. Submission to Congress and the Comptroller General The Congressional Review Act, 5 U.S.C. 801 et seq., as added by the Small Business Regulatory Enforcement Fairness Act of 1996, generally provides that before a rule may take effect, the agency promulgating the rule must submit a rule report, which includes a copy of the rule, to each House of the Congress and to the Comptroller General of the United States. EPA will submit a report containing this rule and other required information to the U.S. Senate, the U.S. House of Representatives, and the Comptroller General of the United States prior to publication of this final rule in the Federal Register. This final rule is not a "major rule" as defined by 5 U.S.C. 804 (2) . List of Subjects in 40 CFR Part 180 Environmental protection, Administrative practice and procedure, Agricultural commodities, Pesticides and pests, Reporting and recordkeeping requirements. Dated:October 31, 2000. James Jones, Director, Registration Division, Office of Pesticide Programs. Therefore, 40 CFR chapter I is amended as follows: PART 180--[AMENDED] 1. The authority citation for part 180 continues to read as follows: Authority: 21 U.S.C. 321(q) , 346(a) and 371. Sec. 180.1001 fAmendedl 2. Section 180.1001 is amended by removing and reserving the text of paragraph (b) (1) . 3. Section 180.1021 is revised to read as follows: Sec. 180.1021 Copper; exemption from the requirement of a tolerance. (a) Copper is exempted from the requirement of a tolerance in meat, milk, poultry, eggs, fish, shellfish, and irrigated crops when it results from the use of: (1) Copper sulfate as an algicide or herbicide in irrigation conveyance systems and lakes, ponds, reservoirs, or bodies of water in which fish or shellfish are cultivated. (2) Basic copper carbonate (malachite) as an algicide or herbicide in impounded and stagnant bodies of water (3) Copper triethanolamine and copper monoethanolamine as an algicide or herbicide in fish hatcheries, lakes, ponds, and reservoirs (4) Cuprous oxide bearing antifouling coatings for control of algae or other coatings for control of algae or other organisms on submerged concrete or other (irrigation) structures. (b) The following copper compounds are exempt from the requirement of a tolerance when applied (primarily) as a fungicide to growing crops using good agricultural practices: Bordeaux mixture, basic copper carbonate (malachite) (CAS Reg. No. 1184-64-1) , copper ethylenediamine complex, copper hydroxide (CAS Reg. No. 20427-59-2) , copper lime mixtures, copper linoleate (CAS Reg. No. 7721-15-5) , copper octanoate (CAS Reg. No. 20543-04-8) , copper oleate (CAS Reg. No. 10402-16-1) , copper oxychloride (CAS Reg. No. 1332-40-7) , copper sulfate basic (CAS Reg. No. 1344-73-6) , cupric oxide (CAS Req. No. 1317-38-0) , and cuprous oxide (CAS Reg. No. 1317-19-1) . (c) Copper sulfate pentahydrate (CAS Reg. No. 7758-99-8) is exempt from the requirement of a tolerance when applied as a fungicide to growing crops or to raw agricultural commodities after harvest. (FR Doc. 00-28715 Filed 11-14-00; 8:45 am] BILLING CODE 6560-50-S FR Home About the Site FR Listsery FR Search Selected Electronic Dockets Regulatory Agenda Executive Orders Current Laws and Re.ulations EPA Home Privac and Securit Notice Contact Us http://www.epa.gov/fedrgstr/EPA-PEST/2000/November/Day-15/p28715.htm