06/24/2014 (CR) 011?
rtil COLLIER 24
COMPANY
June 12, 2014
The Board of County Commissioners
Attn: Chairman Tom Henning
3299 Tamiami Trail East
Suite 303
Naples, FL 34112
Dear Chairman Henning:
After carefully watching the recent Board of County Commissioners meeting, Collier Resources
Company (CRC) has decided to move forward with a plan to investigate the claims that recent
oil exploration activities in Southwest Florida has had an effect on Collier County's water
quality, specifically as it relates to the well south of Lake Trafford permitted by the Dan A.
Hughes Company.
While we are hopeful that the Board of County Commissioners and the Department of
Environmental Protection will be able to resolve any questions associated with the consent order
with the Dan A. Hughes Company, CRC will take immediate action to address the important
issue of water quality that was raised at the Commission meeting earlier this week through
groundwater modeling and water testing. And, in order to ensure total transparency, CRC will
collaborate with Collier County staff to select an independent groundwater expert to test the
water around this particular well. The results of the testing would be made available to the public.
and would be independently verifiable. CRC will pay for the testing.
For the past few months, we have been watching this debate closely and we completely
understand the public's concern. However, we have been engaged in oil exploration in
Southwest Florida for over 70 years and have an impeccable environmental record. We believe a
significant amount of misinformation has been reported in the media and by third parties, and
that the general public does not know that the deep oil producing areas are separated from the
aquifer by over 2 miles of rock. We need to set the record straight and feel this proposal will
bring closure to this issue.
Finally, as good environmental stewards and as a dedicated community partner, we have a strong
interest in ensuring that Collier County's groundwater resources are preserved and protected. To
that end,we will undertake this science based-solution to clear up any confusion.
c),_...e,
Sincerely,
Tom Jones
Sr. Vice President
2600 Golden Gate Pkwy, Suite 112 ❖ Naples, FL 34105 ❖ Tel: (239)262-0900 Fax: (239)262-7378
COLLIER ee (tif
El F50 RAIN S
COMPANY
Cc:
Commissioner Fred W. Coyle
Commissioner Donna Fiala
Commissioner Georgia Hiller, Esq.
Commissioner Tim Nance
County Manager Leo Ochs, Jr.
2600 Golden Gate Pkwy, Suite 112 ❖ Naples, FL 34105 ❖ Tel: (239) 262-0900 Fax: (239)262-7378
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6
Material Safety Data Sheet
BAKER
HUGHES
1 . Product and company identification
Product name : FRW-18
Supplier : Baker Hughes, Inc.
12645 W. Airport Blvd.
Sugar Land, TX 77478
For Product Information/MSDSs Call: 281-351-8131
Material Uses : Special: Friction Reducer.
Code : 488420
Validation date : 11/30/2011.
Print date : 11/30/2011.
Version : 1
Responsible name : Global Regulatory Affairs -Telephone 281-276-5400 or 800-231-3606
In case of emergency : CHEMTREC 800-424-9300 (U.S. 24 hour)
(001)281-276-5400
CANUTEC 613-996-6666 (Canada 24 hours)CHEMTREC Intl 01-703-527-
3887 (International 24 hour)
2 . Hazards identification
Physical state : Liquid.
Odor : oil [Slight]
Color : Milky-white.opaque
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Emergency overview : CAUTION!
MAY CAUSE RESPIRATORY TRACT AND EYE IRRITATION. PROLONGED OR
REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. HARMFUL OR
FATAL IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. ASPIRATION
HAZARD.
Do not ingest. Avoid breathing vapor or mist. Avoid contact with eyes, skin and clothing.
Use only with adequate ventilation. Keep container tightly closed and sealed until ready
for use. Wash thoroughly after handling.
Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Inhalation : Slightly irritating to the respiratory system.
Ingestion : Aspiration hazard if swallowed. Can enter lungs and cause damage. Ingestion may
cause gastrointestinal irritation and diarrhea.
Skin : May cause skin dryness and irritation.
Eyes : Slightly irritating to the eyes.
Potential chronic health effects
Chronic effects : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
Over-exposure signs/symptoms
Inhalation : respiratory tract irritation, coughing
Ingestion : nausea or vomiting
Skin : irritation, dryness, cracking
Eyes : irritation, watering, redness
See toxicological information (Section 11)
11/30/2011. 488420 1/6
� .
FRW-18
3 . Composition/information on ingredients
Name CAS number
Petroleum distillates 64742-47-8 10 -30
4 . First aid measures
Eye contact : Get medical attention immediately. Immediately flush eyes with plenty of water for at
least 15 minutes, occasionally lifting the upper and lower eyelids.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar,tie, belt or waistband. Get medical attention
immediately.
Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
5 . Fire-fighting measures
Flammability of the product : In a fire or if heated, a pressure increase will occur and the container may burst.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal : carbon dioxide,carbon monoxide
decomposition products
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special remarks on : Spills produce extremely slippery surfaces.
explosion hazards
6 . Accidental release measures
Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see Section 8). Surfaces
subject to spills may become slippery.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,waterways, drains
and sewers.
Methods for cleaning up
Small spill : Stop leak if without risk. Move containers from spill area. Absorb with an inert material.
Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Dike spill area and do not allow product to reach sewage system or surface or
ground water. Notify any reportable spill to authorities. (See section 12 for environmental
risks and 13 for disposal information.) Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note:see section 1 for emergency contact
11/30/2011. 488420 2/6
1
FRW-18
6 . Accidental release measures
information and section 13 for waste disposal.
7 . Handling and storage
Handling : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist.
Use only with adequate ventilation. Empty containers retain product residue and can be
hazardous. Do not reuse container.
Storage : Store in accordance with local regulations. Store in a dry, cool and well-ventilated area,
away from incompatible materials (see Section 10). Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental contamination.
8 . Exposure controls/personal protection
Occupational exposure limits TWA(8 hours) STEL(15 mins) Ceiling
Ingredients: List name ppm mg/m3 Other ppm g/m3 Other ppm mg/m3 Other Notations
Petroleum distillates US ACGIH - 200 - - - - - - [1]
[1]Absorbed through skin.
Consult local authorities for acceptable exposure'limits.
Only components of this product with established exposure limits appear in the box above.
If OSHA permissible exposure levels are shown above they are the OSHA 1989 levels or are from subsequent
OSHA regulatory actions. Although the 1989 levels have been vacated the 11th Circuit Court of Appeals, Baker
Hughes recommends that these lower exposure levels be observed as reasonable worker protection.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere
procedures or biological monitoring may be required to determine the effectiveness of the ventilation
or other control measures and/or the necessity to use respiratory protective equipment.
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits.
Hygiene measures : Wash hands,forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Ensure that
eyewash stations and safety showers are close to the workstation location. Take off
contaminated clothing and wash before reuse.
Personal protection
Respiratory : If a risk assessment indicates it is necessary, use a properly fitted, air purifying or
supplied air respirator complying with an approved standard. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Hands : Chemical-resistant gloves.
Eyes : Wear chemical safety goggles. When transferring material wear face-shield in addition to
chemical safety goggles.
Skin : Wear long sleeves and other protective clothing to prevent repeated or prolonged skin
contact.
11/30/2011. 488420 3/6
FRW-18
9 . Physical and chemical properties
Physical state : Liquid.
Flash point : Closed cup: >93.33°C (>200°F)
Auto-ignition temperature : >215°C (>419°F)
Flammable limits : Not available.
Color : Milky-white.opaque
Odor : oil [Slight]
pH : Not available.
Boiling/condensation point : >100°C (>212°F)
Initial Boiling Point : Not available.
Melting/freezing point : <-20°C (<-4°F)
Relative density : Not available.
Density : Not available.
Vapor density : Not available.
Volatility : 50% (w/w)
Odor threshold : Not available.
Evaporation rate : Not available.
VOC : Not available.
Viscosity : Not available.
Solubility(Water) : Soluble as inverted emulsion
Vapor pressure : Not available.
Pour Point : Not available.
Partition coefficient : Not available.
(LogKow)
10 . Stability and Reactivity
Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to avoid : No specific data.
Materials to avoid : Reactive or incompatible with the following materials:oxidizing materials.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Conditions of reactivity : Slightly flammable in the presence of the following materials or conditions: open flames,
sparks and static discharge and heat.
Spills produce extremely slippery surfaces.
11 . Toxicological information
Carcinogenicity
Classification
Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA
Petroleum distillates A3 - -
Chronic toxicity Remarks
1) Petroleum distillates
Not available.
11/30/2011. 488420 4/6
1
FRW-18
12 . Ecological information
Aquatic ecotoxicitv
Product/ingredient name Result Species Exposure
Petroleum distillates Acute LC50 2200 ug/L Fresh Fish - Bluegill - Lepomis 4 days
water macrochirus -35 to 75 mm
Conclusion/Summary : Not available.
Biodegradability
Conclusion/Summary : Not available.
13. Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Empty
containers or liners may retain some product residues. This material and its container
must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14 . Transport information
Regulatory UN number Proper shipping Classes PG* Label [Additional
information name information
DOT Classification Not - - - -
regulated.
TDG Classification Not - - - -
regulated.
IMDG Class Not - - - -
regulated.
IATA-DGR Class Not - - - -
regulated.
PG* : Packing group
DOT Reportable Not applicable.
Quantity
Marine pollutant Not applicable.
North-America NAERG : Not available.
15 . Regulatory information
HCS Classification : Irritating material
U.S. Federal regulations : United States inventory(TSCA 8b):All components are listed or exempted.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Distillates (petroleum), hydrotreated
light
SARA 311/312 MSDS distribution -chemical inventory- hazard identification:
FRW-18: Immediate (acute) health hazard
CERCLA: Hazardous substances.: No products were found.
Clean Water Act(CWA)307: No products were found.
Clean Water Act(CWA)311: No products were found.
11/30/2011. 488420 5/6
7
FRW-18
15 . Regulatory information
Clean Air Act(CAA) 112 regulated flammable substances: No products were found.
Clean Air Act(CAA) 112 regulated toxic substances: No products were found.
Clean Air Act Section 112(b) Hazardous Air Pollutants(HAPs) :
Not listed
United States inventory : All components are listed or exempted.
(TSCA 8b)
Canada
WHMIS(Canada) : Not controlled under WHMIS (Canada).
Canada(CEPA DSL): : Not determined.
16 . Other information
Label requirements : MAY CAUSE RESPIRATORY TRACT AND EYE IRRITATION. PROLONGED OR
REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. HARMFUL OR
FATAL IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. ASPIRATION
HAZARD.
Hazardous Material
Information System (U.S.A.)
Health 1
Flammability 0
Ph sical hazards. .
0
Personal protection b
Caution: HMIS®ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks,and 4
representing significant hazards or risks Although HMIS®ratings are not required on MSDSs under 29 CFR
1910.1200,the preparer may choose to provide them. HMIS®ratings are to be used with a fully implemented
HMIS®program. HMIS®is a registered mark of the National Paint &Coatings Association (NPCA). HMIS®
materials may be purchased exclusively from J.J. Keller(800)327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection
Association (U.S.A.)
Flammability
Health .40 Instability
Special
Date of printing : 11/30/2011.
V Indicates information that has changed from previously issued version.
Notice to reader
NOTE:The information on this MSDS is based on data which is considered to be accurate. Baker Hughes,
however, makes no guarantees or warranty,either expressed or implied of the accuracy or completeness of this
information.
The conditions or methods of handling,storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons,we do not assume responsibility and expressly disclaim
liability for loss,damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of this product.
This MSDS was prepared and is to be used for this product. If the product is used as a component in another
product,this MSDS information may not be applicable.
11/30/2011. 488420 6/6
Region USA
Ifg Baker Hughes
BAKER
HUGHES Material Safety Data Sheet
1 PRODUCT AND COMPANY IDENTIFICATION
Product Name: XLW-30G
Item Number: 488565, 488566
Product Use: Crosslinker
Supplier: Baker Hughes
11211 FM 2920
Tomball, Texas 77375
(281)351-8131
IN CASE OF EMERGENCY CALL: (800) 424-9300 for
CHEMTREC
(703) 527-3887 for
International
HMIS HAZARD INDEX
HEALTH: 2
FLAMMABILITY: 0
REACTIVITY: 0
PERSONAL PROTECTION: g
2 COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Component CAS# Percent Hazard
Borate suspension 99.8
Crystalline silica quartz 014808-60-7 <0.2 Carcinogen
3 HAZARDS IDENTIFICATION
PRIMARY ROUTES OF EXPOSURE: Eye contact. Skin contact. Inhalation.
ACUTE OVEREXPOSURE EFFECTS:
INHALATION: May cause mild respiratory irritation. Respirable crystalline silica can cause silicosis. Silicosis may
lead to disability and death.
INGESTION: Unknown
EYE CONTACT: May cause mild eye irritation.
SKIN CONTACT:May cause mild skin irritation.
EXPOSURE LIMITS:
HAZARDOUS COMPONENT ACGIH TLV OSHA PEL LC50(inhalation) LD50(oral)
Borate suspension NA NA NA NA
Crystalline silica quartz 0.025 mg/m3, 10mg/m3/%Si02+2 NA NA
respirable fraction
XLW-30G-USA-Revised 11/09/2010/Page 1 UNCONTROLLED WHEN PRINTED
4 FIRST AID MEASURES
INHALATION:
Move person to fresh air.
INGESTION:
Rinse mouth out with water. Drink plenty of water. If large quantities were ingested^seek medical advice.
EYES:
Flush eyes with plenty of water and get medical attention if irritation persists.
SKIN:
Wash with soap and water.
5 FIRE FIGHTING MEASURES
FLASHPOINT(METHOD): None
LOWER EXPLOSION LIMIT(%v/v): Not applicable
UPPER EXPLOSION LIMIT(%v/v): Not applicable
SPECIAL HAZARDS:
None.
EXTINGUISHING MEDIA:
Carbon dioxide. Dry chemical.,Water spray.Alcohol resistant foam.
SPECIAL FIREFIGHTING PROCEDURES:
Fire-fighters should wear self-contained breathing apparatus and full protective clothing when fighting chemical fires.
HAZARDOUS COMBUSTION PRODUCTS:
Oxides of carbon.
6 ACCIDENTAL RELEASE MEASURES
Cover spill with absorbent material.Scoop absorbed material into a suitable container for disposal. Prevent from
entering sewers or waterways.Caution-surfaces can become very slippery.
7 HANDLING AND STORAGE
HANDLING:
Use only in a well ventilated area.
STORAGE REQUIREMENTS:
Keep container tightly closed^in a cool^well ventilated place.Store away from sunlight.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
SPECIFIC ENGINEERING CONTROLS:
Adequate ventilation should be provided to keep concentrations below acceptable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT:
Chemical resistant gloves.Chemical resistant goggles.
9 PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
COLOR: Tan
ODOR: Slight
ODOR THRESHOLD: Not available
SPECIFIC GRAVITY: 1.42
VAPOR PRESSURE: Not available
VAPOR DENSITY(air= 1): Not available
EVAPORATION RATE: Not available
BOILING POINT: Not available
FREEZING POINT: Not available
XLW-30G-USA-Revised 11/09/2010/Page 2 UNCONTROLLED WHEN PRINTED
r 1
pH: Not available
SOLUBILITY IN WATER: Sparingly
10 STABILITY AND REACTIVITY
STABILITY:
Stable.
INCOMPATIBILITY/CONDITIONS OF REACTIVITY:
Contact with acids.Contact with oxidizing agents.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
Oxides of carbon.
HAZARDOUS POLYMERIZATION:
Will not occur.
11 TOXICOLOGICAL PROPERTIES
CHRONIC EFFECTS:
Chronic inhalation of crystalline silica(present at<1%in this product)may result in shortness of breath^dyspnea
(difficult breathing)and dry cough.These symptoms are generally a first sign of a pulmonary disease called Silicosis.
SENSITIZATION:
Not known.
CARCINOGENICITY:
Free crystalline silica(<1%in this product)is listed as a Group 1 carcinogen(carcinogenic to humans)by IARC.This
classification applies to the inhalation of respirable crystalline silica(IARC-International Agency for Research on
Cancer)
MUTAGENICITY:
Not known.
REPRODUCTIVE TOXICITY:
Not known.
12 ECOLOGICAL INFORMATION
This product is biodegradable., Low acute toxicity
Base component of product-72-hr EC50 algae 2500 mg/L;48-hr LC50 daphnia 500 mg/L;96-hr LC50 fish 1600
mg/L;96-hr LC50 crustaceans 2500 mg/L
13 DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
Disposal should be made in accordance with national and local regulations
14 TRANSPORT INFORMATION
LAND TRANSPORT(DOT)
Proper Shipping Name: NOT RESTRICTED
UN/ID No.: NA
Hazard Class - Primary:
Hazard Class -Secondary:
Packing Group:
Reportable Quantity(RQ):
Emergency Response Guide#:
AIR TRANSPORT(ICAO/IATA)
Proper Shipping Name: NOT RESTRICTED
UN/ID No.: NA
Hazard Class-Primary:
Hazard Class -Secondary:
XLW-30G-USA-Revised 11/09/2010/Page 3 UNCONTROLLED WHEN PRINTED
Packing Group:
MARINE TRANSPORT(IMDG/IMO)
Proper Shipping Name: NOT RESTRICTED
UN No.: NA
Hazard Class -Primary:
Hazard Class - Secondary:
Packing Group:
EmS:
15 REGULATORY INFORMATION
SARA TITLE III:
SECTION 302/304 This product does not contain substances listed in Appendix A and B as an Extremely
Hazardous Substance.
SECTION 311/312 None
SECTION 313 This product does not contain ingredients(at a level of 1%or greater)on the List of Toxic
Chemicals.
TSCA INVENTORY: The substances in this product are included on or exempted from the TSCA 8(b)Inventory
(40 CFR 710).
CALIFORNIA PROP 65: This product may contain trace quantities of substances that
are regulated under California Proposition 65., Crystalline silica
PRIORITY POLLUTANTS:
16 OTHER INFORMATION
ISSUE DATE: 11/09/2010
PREPARED BY: Baker Hughes
REFERENCES:
Supplier's Literature.
The information contained herein is based on data considered accurate. However, no warranty is expressed or
implied regarding the accuracy of these data or the results to be obtained from the use thereof. Vendor assumes
no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety
procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for
injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety
procedures are followed. Furthermore,vendee assumes the risk in his use of the material.
XLW-30G-USA-Revised 11/09/2010/Page 4 UNCONTROLLED WHEN PRINTED
H2O GeoSolutions LLC
➢ Conduct groundwater flow modeling to simulate fracking-like activity undertaken
(especially in the absence of actual measurements during the procedure), to understand
the potential extent to which geologic and hydrological impacts may result.
➢ Conduct groundwater flow modeling and tracer-dye testing to analyze the risk of
potential migration down-gradient to existing private wells, the Orangetree utility wells,
East Golden Gate utility wells and the proposed northeast Collier County Brackish Water
wellfield.
➢ Deeper groundwater monitoring wells should be installed around the oil well and
proposed Class II well pad in a limited zone between the base of the boulder zone
(approximately 2300 feet bls) and the USDW delineation (approximately 1,850 feet bls)
to best detect potential upward migration prior to entering the USDW.
Respectfully,
Noah B. Kugler, P.G.
H2O GeoSolutions LLC
June 24, 2014
RE: DEP Groundwater Monitoring of Hogan Well Site
The sampling DEP is undertaking is only sufficient to detecting surface contamination. It is not
effective for accurately detecting groundwater contamination as a result of the migration of
drilling fluids from the use of high pressure injection of chemicals and silica to prop open
fractures in horizontal oil wells. Additionally, potential groundwater contamination could ensue
with continued drilling activities being undertaken at the Hogan well.
Testing should include adequate independent professional oversight of the assessment plan,
protocols including testing locations, depths and protocols including redundant samples for all
testing and analysis to be sent to separate laboratories. Monitoring well depths should cover a
variety of potentially exposed aquifers, including deep aquifers down to the base of the USDW
that occur within the middle confining unit.
Therefore in order to effectively sample for potential contamination as a result of the horizontal
drilling activity by Dan A. Hughes, the following additional sampling and analysis is needed:
➢ Allow Collier County and independent consultant(s) to be present and allowed to
independently take water samples at the same time and location that FDEP collects
samples.
➢ Conduct a tracer dry study between the horizontal Hughes well and the two nearby dry
bore holes.
➢ Conduct a mechanical integrity test of the well casing at the drill well, testing of the
cement and tracer dye studies to determine upward movement of fluid around casing.
➢ Disclose the complete list of chemicals used by Dan A Hughes (as well as their Material
Safety Data Sheets) to the public prior to initiating sampling.
➢ Disclose DEP groundwater monitoring assessment plan and allow it to be reviewed by
independent consultants prior to well installation and testing —to independently verify
that the proper monitoring intervals, locations and techniques are being used.
➢ Install deep groundwater monitoring wells below the defined Underground Source of
Drinking Water(USDW)at 1,800+ feet deep to detect if there is upwelling of chemicals
from where fracking-like activity took place towards the aquifers used for public water
supply in Collier County
➢ Gather grab samples from as deep as possible within Wells 86 and 103 to include
samples just above the USDW (approx.. 1,800 feet)just above the boulder zone
(approx. 2,200 feet), and just below the boulder zone at approximately 3,500 feet, to
detect for potential upward movement of contaminants into these abandoned wells. This
should be done under static conditions (no pumping). Once sampling is complete, wells
86 and 103 should be properly plugged and abandoned applying today's best industry
practices and current regulations, especially if oil recovery activities continue at the
Collier Hogan site.
1
UPDATED CONSERVANCY OF SOUTHWEST FLORIDA'S 6/24/14
RECOMMENDATIONS REGARDING HOGAN WELL AND POTENTIAL
GROUNDWATER CONTAMINATION
What Department of Environmental Protection (DEP) Should Have Done for
Meaningful Enforcement
• Immediately issue a stop work order for all work (not just "new" activities which
allow existing production to continue). DEP should revoke the Hogan Oil Drilling
permit to the Dan A. Hughes Company, which they should have done prior as
enforcement in response to the applicant proceeding without authorization even
after receiving a cease and desist order from DEP.
• Immediately conduct a mechanical integrity test of the well casing at the drill well,
testing of the cement and tracer dye studies to evaluate potential upward
movement of fluid around casing.
• Immediately disclose all chemicals (not just formulation names without their
chemical components) that were utilized by the Dan A. Hughes Company, as
well as their material safety data sheets. This is necessary to truly be able to
independently verify if DEP is sampling for all chemicals of concerns using
proper methods for their detection.
• Conduct a thorough credible groundwater monitoring investigation that would
entail:
o Gathering grab samples from as deep as possible within Wells 86 and 103
to at least below the boulder zone at approximately 3,500 feet to detect
potential vertical movement of contaminants into these abandoned wells. ,
with no pumping (not in DEP sampling plan, only sinking a shallow well
next to Well 86 and doing nothing to monitor Well 103) Conduct a tracer
dye study between the horizontal Hughes well and the two nearby dry
bore holes (not in DEP sampling plan).
o Groundwater monitoring well depths should cover a variety of potentially
exposed aquifers including deep aquifers. DEP should install deep
monitoring wells below the defined Underground Source of Drinking Water
or at least 1,850 feet to detect any vertical migration of chemicals from
where the fracking-like activity took place towards public water supply (not
in DEP sampling plan). The very shallow monitoring wells that DEP
currently plans to use will not detect potential contamination from the
fracking-like activities until long after public water supplies are completely
contaminated.
o Allowing Collier County and independent consultant(s) to be present to
independently take water samples at the same time and location that DEP
collects samples.
o Disclosing DEP groundwater monitoring assessment plan and allow it to
be reviewed by independent consultants prior to well installation and
testing—to independently verify that the proper monitoring intervals,
locations and techniques are being used.
• Immediately conduct groundwater flow modeling to simulate fracking-like activity
undertaken (especially in the absence of actual measurements during the
procedure), to understand the potential extent to which geologic and hydrological
impacts may result.
• Obtain an operational plan from Dan A. Hughes, including pressures and
volumes of fluids used in the workover operation, to ensure that there is not
excessive dissolution of rock or forcing of fluids deeper than the targeted area.
• Publicly disclose the exact location of wastewater disposal, including the
pretreatment facility, as well as the ultimate disposal facility. It is vitally important
to assess this location in case the ultimate disposal facility is an injection well that
may present another potential source of contamination.
• Immediately conduct groundwater flow modeling and tracer-dye testing to
analyze the risk of potential migration down-gradient to existing private wells, the
Orangetree utility wells, East Golden Gate utility wells and the proposed
northeast Collier County Brackish Water wellfield.
• Disclose the total amount of water used and how that compares with their
consumptive use permit limit.
• Obtain from Hughes an interim spill prevention and clean-up plan, and assurance
that injected fluids will not migrate to other groundwater formations or aquifers.
• Include language in the consent order that requires Dan A. Hughes to pay any
and all remediation costs (not capped at any particular monetary value since total
costs are unknown), as well as to immediately post a bond for one million dollars
for costs associated only with the Hogan well (not for up to 10 wells as currently).
• Once is sampling completed, FDEP should properly plug and abandon (P&A)
wells 86 and 103 applying current regulations as a crucial step in protecting
underground sources of drinking water from potential future contamination,
especially if oil recovery activities are allowed to continue at the Collier Hogan
site.
What Collier County Can Do In Interim to Protect Its Drinking Water Supply
€ Sampling the County Golden Gate wellfield, private wells, and the City of Naples
for at a minimum:
o pH
o Alkalinity
o Hardness
o Specific Conductance
o Chloride
o Bromide
o Nitrate
o Nitrite
o Sulfate
o Barium
o Boron
o Sodium
o Strontium
o Arsenic
o Manganese
o VOCs
o Semi-volatile organics
o Benzene
o Carcinogens
o Hydrochloric Acid
Without knowing which chemicals were actually used in the Dan A. Hughes
Company operation, this would cover a suite of the most typical chemicals
utilized in such activities and provide a useful baseline as well. However, Collier
County should still insist on full disclosure of all chemicals used and check to
ensure key contaminant were not overlooked - testing those accordingly if so.
(Note: see attached map on opposite side)
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Patricia L. Morgan
From: Durham, Tim
Sent: Tuesday,June 24, 2014 4:06 PM
To: Patricia L. Morgan
Subject: Item 11D - Slide Presentation
Attachments: Advertising Policy.ppsx
Hi Trish.
This was the only exhibit/handout that the reporter did not get a hard copy.
Thanks,
CTun £ ? a/ 'am
Executive Manager of Corporate Business Operations
for Collier County, Florida
Website:www.colliergov.net
E-mail: timdurham @colliergov.net
Phone: (239)252-8383
Under Florida Law,e-mail addresses are public records.If you do not want your e-mail address released in response to a public records request.do not send
electronic mail to this entity.Instead,contact this office by telephone or in writing.
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